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Oscillometry and Conductometry deals with oscillometry and conductometry and covers topics ranging from the conductivity and dielectric constant of a solution and their determination, to instruments used in carrying out conductometric and oscillometric measurements. Acid-base titrations and titrations based on precipitation, complex formation, and redox reactions are also discussed. A number of applications of conductometry and oscillometry are considered. This volume is comprised of 18 chapters and begins with an overview of the fundamentals of electrical conductivity, its theoretical interpretation, and how it is affected by temperature. The relation between ionic interaction and conductivity of solutions is also described, with emphasis on the Wien effect and the Debye effect. The theoretical fundamentals of the determination of conductivity using direct and alternating currents are then outlined. Subsequent chapters explore the principles and the devices used in determining dielectric constants; conductometric and oscillometric instruments; the titration of acids and bases; and acid-base titrations in aqueous and non-aqueous media. The final section is devoted to applications of conductometry and oscillometry, including kinetic studies and chromatographic analysis. This monograph will be of interest to analytical chemists.
Oscillometry and Conductometry deals with oscillometry and conductometry and covers topics ranging from the conductivity and dielectric constant of a solution and their determination, to instruments used in carrying out conductometric and oscillometric measurements. Acid-base titrations and titrations based on precipitation, complex formation, and redox reactions are also discussed. A number of applications of conductometry and oscillometry are considered. This volume is comprised of 18 chapters and begins with an overview of the fundamentals of electrical conductivity, its theoretical interpr...
A Practical Guide to Instrumental Analysis covers basic methods of instrumental analysis, including electroanalytical techniques, optical techniques, atomic spectroscopy, X-ray diffraction, thermoanalytical techniques, separation techniques, and flow analytical techniques. Each chapter provides a brief theoretical introduction followed by basic and special application experiments. This book is ideal for readers who need a knowledge of special techniques in order to use instrumental methods to conduct their own analytical tasks.
Electroanalysis as a representative of the wet-chemical methods has many advantages, such as: selectivity and sensitivity, nothwithstanding its inexpensive equipment; ample choice of possibilities and direct accessibility, especially to electronic and hence automatic control even at distance; automated data treatment; and simple insertion, if desirable, into a process-regulation loop. There may be circumstances in which an electroanalytical method, as a consequence of the additional chemicals required, has disadvantages in comparison with instrumental techniques of analysis; however the above-mentioned advantages often make electroanalysis the preferred approach for chemical control in industrial and environmental studies.This book provides the reader with a full understanding of what electroanalysis can do in these fields. It presents on the one hand a systematic treatment of the subject and its commonly used techniques on a more explanatory basis, and on the other it illustrates the practical applications of these techniques in chemical control in industry, health and environment. As such control today requires the increasing introduction of automation and computerization, electroanalysis with its direct input and/or output of electrical signals often has advantages over other techniques especially because recent progress in electronics and computerization have greatly stimulated new developments in the electroanalysis techniques themselves. Part A looks systematically at electroanalysis while more attention is paid in Part B to electroanalysis in non-aqueous media in view of its growing importance. The subject is rounded off in Part C by some insight into and examples of applications to automated chemical control.