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Clay minerals are layer silicates with a large propensity for adsorbing and intercalating simple and polymeric organic molecules. Because of their fine particle size, extensive surface area, layer structure, and peculiar charge characteristics, clay minerals can also act as efficient solid acid catalysts and catalyst carriers/supports. Besides being easy to separate from the reaction mixture and recyclable, clay minerals are abundant, inexpensive, and nonpolluting. Moreover, layer silicates offer a reduced dimensionality of reaction space in which introduced organic species can meet and collide. This book provides an insight into the relationship between the surface properties of clay minerals and their catalytic activity. Organized into eight comprehensive chapters, the volume describes and discusses the ability of clay minerals to serve as solid acid catalysts for a large range and variety of organic conversions and transformations. This book is a valuable reference for research scientists and industrial chemists who use, or contemplate using, clay minerals as catalysts for targeted organic reactions and syntheses. The present text will also be of interest to environmental and soil chemists as well as teachers and postgraduate students of organic geochemistry and solid acid catalysis. Book jacket.
Given the recent expansion in materials chemistry, this book addresses several of the vigorous areas of research in this field, where inorganic materials are central to the research. Each chapter provides an introduction to the subject under discussion and then develops the field to provide a sensible overview, with certain topics being expanded. Written by an international group of researchers the nine chapters cover such important areas as inorganic superconductors, magnetic materials, biogenic inorganic materials, polymeric co-ordination compounds, liquid crystals and precursors for electronic materials.
Proceedings of the NATO Advanced Research Workshop on the Application of Natural Microporous Materials for Environmental Technology, Smolenice Castle, Slovakia, 26-30 October 1998
Bringing together information widely distributed throughout scientific and industrial journals, here is an overview of the chemical consititution and properties of clay minerals and the environmental conditions that lead to their formation. Provides a detailed picture of the chemical consititution of the eight main groups of clay minerals containing silica and of the non-siliceous oxide clays. The central section of the book deals with the properties of clays: their colloidal behavior, cation exchange, interaction with water, reactions on heating, catalytic properties, and reactions with organic compounds. Also discusses the chemical conditions that favor the formation of clays and their evolution or decomposition into other materials.
Surface and Interface Chemistry of Clay Minerals, Volume 9, delivers a fundamental understanding of the surface and interface chemistry of clay minerals, thus serving as a valuable resource for researchers active in the fields of materials chemistry and sustainable chemistry. Clay minerals, with surfaces ranging from hydrophilic, to hydrophobic, are widely studied and used as adsorbents. Adsorption can occur at the edges and surfaces of clay mineral layers and particles, and in the interlayer region. This diversity in properties and the possibility to tune the surface properties of clay minerals to match the properties of adsorbed molecules is the basis for study. This book requires a fundamental understanding of the surface and interface chemistry of clay minerals, and of the interaction between adsorbate and adsorbent. It is an essential resource for clay scientists, geologists, chemists, physicists, material scientists, researchers, and students. - Presents scientists and engineers with a resource they can rely on for their own research and work involving clay minerals - Includes an in-depth look at ion exchange, adsorption of inorganic and organic molecules, including polymers and proteins, and catalysis occurring at the surfaces of clay minerals - Includes materials chemistry of clay minerals with chiral clay minerals, optical materials and functional films
Since 1997, scientists of different disciplines sharing a deep interest in concepts and knowledge related to evolutionary biology have held the annual Evolutionary Biology Meetings in Marseille in order to discuss their research and promote collaboration. Lately scientists especially focusing on applications have also joined the group. This book starts with the report of the "12th Evolutionary Biology Meeting", which gives a general idea of the meeting’s epistemological stance. This is followed by 22 chapters, a selection of the most representative contributions, which are grouped under the following four themes: Part I Concepts and Knowledge - Part II Modelization - Part III Applied Evolutionary Biology - Part IV Applications in Other Fields -Part IV transcends the field of biology, presenting applications of evolutionary biology in economics and astronomy.
As the human population grows from seven billion toward an inevitable nine or 10 billion, the demands on the limited supply of soils will grow and intensify. Soils are essential for the sustenance of almost all plants and animals, including humans, but soils are virtually infinitely variable. Clays are the most reactive and interactive inorganic compounds in soils. Clays in soils often differ from pure clay minerals of geological origin. They provide a template for most of the reactive organic matter in soils. They directly affect plant nutrients, soil temperature and pH, aggregate sizes and strength, porosity and water-holding capacities. This book aims to help improve predictions of important properties of soils through a modern understanding of their highly reactive clay minerals as they are formed and occur in soils worldwide. It examines how clays occur in soils and the role of soil clays in disparate applications including plant nutrition, soil structure, and water-holding capacity, soil quality, soil shrinkage and swelling, carbon sequestration, pollution control and remediation, medicine, forensic investigation, and deciphering human and environmental histories. Features: Provides information on the conditions that lead to the formation of clay minerals in soils Distinguishes soil clays and types of clay minerals Describes clay mineral structures and their origins Describes occurrences and associations of clays in soil Details roles of clays in applications of soils Heavily illustrated with photos, diagrams, and electron micrographs Includes user-friendly description of a new method of identification To know soil clays is to enable their use toward achieving improvements in the management of soils for enhancing their performance in one or more of their three main functions of enabling plant growth, regulating water flow to plants, and buffering environmental changes. This book provides an easily-read and extensively-illustrated description of the nature, formation, identification, occurrence and associations, measurement, reactivities, and applications of clays in soils.
The book provides insight into the working of clays and clay minerals in speeding up a variety of organic reactions. Clay minerals are known to have a large propensity for taking up organic molecules and can catalyse numerous organic reactions due to fine particle size, extensive surface area, layer structure, and peculiar charge characteristics. They can be used as heterogeneous catalysts and catalyst carriers of organic reactions because they are non-corrosive, easy to separate from the reaction mixture, and reusable. Clays and clay minerals have an advantage over other solid acids as they are abundant, inexpensive, and non-polluting.