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* Physical chemists will find this book comprehensive. Topical reviews on all aspects of colloidal ordering and related phase transitions will be covered. It provides a good blend of experimental and theoretical investigations. * Useful to materials scientists and chemical engineers, the book includes a discussion of stability, important from the point of view of applications of colloidal crystals. * Physicists will be interested in the book, because it highlights the controversy over effective interparticle interaction in charged colloids.
The first five articles in this issue emphasize equilibrium phases and structures. The hard sphere properties of sterically stabilized particle suspensions are examined in the article by van Megan, Pusey and Bartlett, a colloidal compound is discussed by Hachisu and attractive interactions are shown to produce a full complement of phase transitions including a liquid/gas transition by Emmett and Vincent. Recent theoretical interest in the nature of melting in two dimensions has led to the investigation of the melting transition in colloidal systems where the particles are constrained to a single layer. Murray, Van Winkle and Wenk present experimental results supporting the view that two dimensional melting is mediated by two second order transitions, while Tang, Armstrong, Mockler and O'Sullivan present results suggesting a first order process in a similar colloidal monolayer.
This monograph represents an extension of the author''s original PhD thesis and includes a more thorough discussion on the concepts and mathematics behind his research works on the foam model, as applied to studying issues of phase stability and elasticity for various non-closed packed structures found in fuzzy and colloidal crystals, as well as on a renormalization-group analysis regarding the critical behavior of loop polymers upon which topological constraints are imposed. The common thread behind these two research works is their demonstration of the importance and effectiveness of utilizing geometrical and topological concepts for modeling and understanding soft systems undergoing phase transitions.
Volume IV (2005) covers preparation, characterization of colloids, stability and interaction between pairs of particles, and in concentrated systems, their rheology and dynamics. This volume contains two chapters written, or co-authored by J. Lyklema and edited contributions by A.P.Philipse, H.P. van Leeuwen, M. Minor, A. Vrij, R.Tuinier and T. van Vliet. The volume is logically followed by Vol V, but is equally valuable as a stand alone reference.* Combined with part V, this volume completes the prestigious series Fundamentals of Interface and Colloid Science* Together with volume V this book provides a general physical chemical background to colloid science* Covers all aspects of particle colloids
The Physics of Phase Transitions occupies an important place at the crossroads of several fields central to materials sciences. This second edition incorporates new developments in the states of matter physics, in particular in the domain of nanomaterials and atomic Bose-Einstein condensates where progress is accelerating. New information and application examples are included. This work deals with all classes of phase transitions in fluids and solids, containing chapters on evaporation, melting, solidification, magnetic transitions, critical phenomena, superconductivity, and more. End-of-chapter problems and complete answers are included.
This book is designed to critically review experimental findings on ionic polymers and colloidal particles and to prove a theoretical framework based on the Poisson-Boltzmann approach. Structure formation in ionic polymer solutions has attracted attention since the days of H. Staudinger and J. D. Bernal. An independent study on ionic colloidal dispersions with microscopy provided a compelling evidence of structure formation. Recent technical developments have made it possible to accumulate relevant information for both ionic polymers and colloidal particles in dilute systems. The outstanding phenomenon experimentally found is microscopic inhomogeneity in the solute distribution in macroscopically homogeneous systems.To account for the observation, the present authors have invoked the existence of the counterion-mediated attraction between similarly charged solute species, in addition to the widely accepted electrostatic repulsion.
The Encyclopedia of Physical Chemistry and Chemical Physics introduces possibly unfamiliar areas, explains important experimental and computational techniques, and describes modern endeavors. The encyclopedia quickly provides the basics, defines the scope of each subdiscipline, and indicates where to go for a more complete and detailed explanation. Particular attention has been paid to symbols and abbreviations to make this a user-friendly encyclopedia. Care has been taken to ensure that the reading level is suitable for the trained chemist or physicist. The encyclopedia is divided in three major sections: FUNDAMENTALS: the mechanics of atoms and molecules and their interactions, the macroscopic and statistical description of systems at equilibrium, and the basic ways of treating reacting systems. The contributions in this section assume a somewhat less sophisticated audience than the two subsequent sections. At least a portion of each article inevitably covers material that might also be found in a modern, undergraduate physical chemistry text. METHODS: the instrumentation and fundamental theory employed in the major spectroscopic techniques, the experimental means for characterizing materials, the instrumentation and basic theory employed in the study of chemical kinetics, and the computational techniques used to predict the static and dynamic properties of materials. APPLICATIONS: specific topics of current interest and intensive research. For the practicing physicist or chemist, this encyclopedia is the place to start when confronted with a new problem or when the techniques of an unfamiliar area might be exploited. For a graduate student in chemistry or physics, the encyclopedia gives a synopsis of the basics and an overview of the range of activities in which physical principles are applied to chemical problems. It will lead any of these groups to the salient points of a new field as rapidly as possible and gives pointers as to where to read about the topic in more detail.
This book is the third volume of review papers on advanced problems of phase transitions and critical phenomena, following the success of the first two volumes in 2004 and in 2007. Broadly, the book aims to demonstrate that the phase transition theory, which experienced its ‘golden age’ during the 70s and 80s, is far from over and there is still a good deal of work to be done, both at the fundamental level and in respect of applications.This volume presents a broad spectrum of problems connected with criticality. It covers its theoretical backgrounds, analytical approaches and numerical simulations to describe criticality in specific systems (ionic fluids, diluted magnets, polymers), as well as phase transitions on complex networks and in the minority game model. As the first two volumes, this book is based on the review lectures that were given in Lviv (Ukraine) at the “Ising lectures” — a traditional annual workshop on phase transitions and critical phenomena which brings together scientists working in the field with university students and those who are interested in the subject.
Reviews the most interesting materials on the market concerning self-ordering, including macroporous silicon, porous alumina, MCM41 and photonic bandgap.
Patterns and their formations appear throughout nature, and are studied to analyze different problems in science and make predictions across a wide range of disciplines including biology, physics, mathematics, chemistry, material science, and nanoscience. With the emergence of nanoscience and the ability for researchers and scientists to study living systems at the biological level, pattern formation research has become even more essential. This book is an accessible first of its kind guide for scientists, researchers, engineers, and students who require a general introduction to this research area, in order to gain a deeper analytical understanding of the most recent observations and experiments by top researchers in physics. Pattern Formations describes the most up-to-date status of this developing field and analyzes the physical phenomena behind a wide range of interesting topics commonly known in the scientific community. The study of pattern formations as a research field will continue to grow as scientists expand their understanding of naturally occurring patterns and mimic nature to help solve complex problems. This research area is becoming more highly recognized due to its contributions to signal processing, computer analysis, image processing, complex networks development, advancements in optics and photonics, crystallography, metallurgy, drug delivery (chemotherapy) and the further understanding of gene regulation. - The only introductory reference book which places special emphasis on the theoretical analyses of experiments in this rapidly growing field of pattern formation - A wide range of physical applications make this book highly interdisciplinary - Explanations of observations and experiments deepen the readers understanding of this developing research field