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With contributions by numerous experts
With contributions by numerous experts
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In spite of the vast number of patents and publications mainly issued duringthelastdecade, acomprehensivereviewthatcoversthescienti?caswell as the patent literature has been missing until now. In this volume we try to review the available literature by two independent approaches to Nd and Ln-catalyzed diene polymerizations. In the?rst part of thevolume, whichisentitled"Neodymium-Based Ziegler/NattaCatalystsand their Application in Diene Polymerization", a polymer chemist's view is given with strong emphasis on Nd-based catalyst systems. Also technological and industrialaspectsofNd-catalyzeddienepolymerizationsareaddressed. Inthe secondpartofthevolume, whichisentitled"Rare-EarthMetalsandAluminum Getting Close in Ziegler-type Organometallics", a more organometallic p- spective isgivenandLn-based catalystsystems areaddressed
1 V.O. Aseyev, H. Tenhu, F. Winnik: Temperature Dependence of the Colloidal Stability of Neutral Amphiphilic Polymers in Water.- 2 V.I. Lozinsky: Approaches to Chemical Synthesis of Protein-Like Copolymers.- 3 S.I. Kuchanov, A.R. Khokhlov: Role of Physical Factors in the Processes of Obtaining of Copolymers.- 4 A.Y. Grosberg, A.R. Khokhlov: "After-Action" of the Ideas of O.M. Lifshitz in Polymer and Biopolymer Physics.-
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This book presents these important facts: a) The mechanism of anionic polymerization, a more than 50-year challenge in polymer chemistry, has now become better understood; b) Precise synthesis of many polymers with novel architectures (triblock, multi-block, graft, exact graft, comb, cyclic, many armed stars with multi-components, dendrimer-like hyper-branched, and their structural mixed (co)polymers, etc.) have been advanced significantly; c) Based on such polymers, new morphological and self-organizing nano-objects and supra molecular assemblies have been created and widely studied and are considered nanodevices in the fields of nano science and technology; d) New high-tech and industrial applications for polymeric materials synthesized by anionic polymerization have been proposed. These remarkable developments have taken place in the last 15 years. Anionic polymerization continues to be the only truly living polymerization system (100 % termination free under appropriate conditions) and consequently the only one with unique capabilities in the synthesis of well-defined (i.e., precisely controlled molecular weight, nearly mono-disperse molecular weight distribution, structural and compositional homogeneity) complex macromolecular architectures. This book, with contributions from the world’s leading specialists, will be useful for all researchers, including students, working in universities, in research organizations, and in industry.
Biomaterials have had a major impact on the practice of contemporary medicine and patient care. Growing into a major interdisciplinary effort involving chemists, biologists, engineers, and physicians, biomaterials development has enabled the creation of high-quality devices, implants, and drug carriers with greater biocompatibility and biofunctiona