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Over the past several decades, analyses of solute migration in aquifers have widely adopted the classical advection-dispersion equation. However, misunderstandings over advection-dispersion concepts, their relationship with the scales of heterogeneity, our observation and interest, and their ensemble mean nature have created furious debates about the concepts' validity. This book provides a unified and comprehensive overview and lucid explanations of the stochastic nature of solute transport processes at different scales. It also presents tools for analyzing solute transport and its uncertainty to meet our needs at different scales. Easy-to-understand physical explanations without complex mathematics make this book an invaluable resource for students, researchers, and professionals performing groundwater quality evaluations, management, and remediation.
This monograph considers engineering systems with random parame ters. Its context, format, and timing are correlated with the intention of accelerating the evolution of the challenging field of Stochastic Finite Elements. The random system parameters are modeled as second order stochastic processes defined by their mean and covari ance functions. Relying on the spectral properties of the covariance function, the Karhunen-Loeve expansion is used' to represent these processes in terms of a countable set of un correlated random vari ables. Thus, the problem is cast in a finite dimensional setting. Then, various spectral approximations for the stochastic response of the system are obtained based on different criteria. Implementing the concept of Generalized Inverse as defined by the Neumann Ex pansion, leads to an explicit expression for the response process as a multivariate polynomial functional of a set of un correlated random variables. Alternatively, the solution process is treated as an element in the Hilbert space of random functions, in which a spectral repre sentation in terms of the Polynomial Chaoses is identified. In this context, the solution process is approximated by its projection onto a finite subspace spanned by these polynomials.
GeoENV96, the First European Conference on Geostatistics for Environmental Applications held in Lisbon, was conceived to bring together researchers, mostly from, but not limited to Europe, working on environmental issues approached by geostatistical methods. Papers were attracted from fields as diverse as hydrogeology. biology, soil sciences, air pollution or ecology. It is clear that there is a lot of activity on geostatistics for environmental applications as the collection of papers in this book reveals. GeoENV96 was successful in the number and quality of the papers presented which surpassed the initial expectations. There is still a large dispersion on the level of application of geostatistics in the different areas. To help in spreading the most novel applications of geostatistics across disciplines and to discuss the specific problems related to the application of geostatistics to environmental applications, geoENV96 is intended to set the pace and to be the first of a series of biennial meetings. The pace is set, now let us wait for geoENV98. Lisbon, November 1996 The Executive Committee: Jaime Gomez-Hernandez Roland Froidevaux Amflcar Soares TABLE OF CONTENTS Foreword .................................................. Vll Hydrology, Groundwater, Groundwater Contaminantion Equivalent Transmissivities in Heterogeneous Porous Media under Radially Convergent Flow X. Sanchez-Vila, c.L. Axness and J. Carrera .......................... .
Effective measurement of the composition and properties of petroleum is essential for its exploration, production, and refining; however, new technologies and methodologies are not adequately documented in much of the current literature. Analytical Methods in Petroleum Upstream Applications explores advances in the analytical methods and instrumentation that allow more accurate determination of the components, classes of compounds, properties, and features of petroleum and its fractions. Recognized experts explore a host of topics, including: A petroleum molecular composition continuity model as a context for other analytical measurements A modern modular sampling system for use in the lab or the process area to collect and control samples for subsequent analysis The importance of oil-in-water measurements and monitoring The chemical and physical properties of heavy oils, their fractions, and products from their upgrading Analytical measurements using gas chromatography and nuclear magnetic resonance (NMR) applications Asphaltene and heavy ends analysis Chemometrics and modeling approaches for understanding petroleum composition and properties to improve upstream, midstream, and downstream operations Due to the renaissance of gas and oil production in North America, interest has grown in analytical methods for a wide range of applications. The understanding provided in this text is designed to help chemists, geologists, and chemical and petroleum engineers make more accurate estimates of the crude value to specific refinery configurations, providing insight into optimum development and extraction schemes.
Impacts of developed tools of heterogenous characterization on the hydrodynamics of flow and the transport mechanisms are illustrated in this text through a series of extensive numerical simulations consisting of single and multiple-realizations (Monte Carlo method).
Open system behavior is predicated on a fundamental relationship between the timescale over which mass is transported and the timescale over which it is chemically transformed. This relationship describes the basis for the multidisciplinary field of reactive transport (RT). In the 20 years since publication of Review in Mineralogy and Geochemistry volume 34: Reactive Transport in Porous Media, RT principles have expanded beyond early applications largely based in contaminant hydrology to become broadly utilized throughout the Earth Sciences. RT is now employed to address a wide variety of natural and engineered systems across diverse spatial and temporal scales, in tandem with advances in computational capability, quantitative imaging and reactive interface characterization techniques. The present volume reviews the diversity of reactive transport applications developed over the past 20 years, ranging from the understanding of basic processes at the nano- to micrometer scale to the prediction of Earth global cycling processes at the watershed scale. Key areas of RT development are highlighted to continue advancing our capabilities to predict mass and energy transfer in natural and engineered systems.
Vadose Zone Processes provides a unified, up-to-date treatment on the movement of water through unsaturated media. In addition to covering the basic equations governing the flow and fate of water in unsaturated media, the text covers the biogeochemistry of vadose environments and the statistical description of vadose processes. The authors emphasize maintaining an intuitive understanding of how the results are derived and how they are appropriately applied. This comprehensive and important book will be useful not only to those in traditional fields such as civil engineering, geology, crop science, chemical engineering, agricultural engineering, and hydrology but also in the newer environmental engineering fields including containment transport, pollution remediation, and waste disposal.