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Hybrid materials have currently a great impact on numerous future developments including nanotechnology. This book presents an overview about the different types of materials, clearly structured into synthesis, characterization and applications. A perfect starting point for everyone interested in the field, but also for the specialist as a source of high quality information.
The combination of supramolecular chemistry, inorganic solids, and nanotechnology has already led to significant advances in many areas such as sensing, controlled motion, and delivery. By making possible an unprecedented tunability of the properties of nanomaterials, these techniques open up whole new areas of application for future supramolecular concepts. The Supramolecular Chemistry of Organic–Inorganic Hybrid Materials gathers current knowledge on the subject and provides an overview of the present state and upcoming challenges in this rapidly growing, highly cross- or interdisciplinary research field. The book details how these designed materials can improve existing materials or generate novel functional features such as chemical amplification, cooperative binding and signal enhancement that are difficult or not at all achievable by classical organic supramolecular chemistry. It also discusses issues related to nanofabrication or nanotechnology such as the directed and controlled assembly or disassembly, biomimetic functions and strategies, and the gating and switching of surface functions or morphology.
This book deals with one of the most attractive fields in material science and technology research. In fact, the concept of organic–inorganic hybrid materials is applied to a wide variety of approaches that include materials with inorganic and/or organic nature with respect to their matrices and/or dispersed phase. The present book compiles one editorial and eleven approaches to the topic, and intends to provide a transversal idea about what the field of the so-called organic–inorganic hybrid materials means in actual scientific scenarios. In any case, the role is pointed out of the interphase between the components as the critical aspect to consider, as a way to enhance and understand these components in order to design materials with "tailor-made" organized structures considering the increasing nano-, meso-, micro- and macro-scales.
This book reports the basics of hybrid phosphor materials, their synthesis routes and their special properties and characterization techniques. It gives the reader information about the natural origins and development of hybrid materials, which are developed by combining inorganic and organic species in one material interface-determined materials. The book provides a general classification of hybrid materials, wherein inorganic materials modified by organic moieties are distinguished from organic materials or matrices modified by inorganic constituents. It gives a focus to the functionalization of organic materials by inorganic additives. The application areas covered include optoelectronic field, sensor applications, biological and environmental applications.
Metal–organic frameworks (MOFs) are crystalline porous materials constructed from metal ions/clusters and organic linkers, combining the merits of both organic and inorganic components. Due to high porosity, rich functionalities, well-defined open channels and diverse structures, MOFs show great potentials in field such as gas storage and separation, catalysis, and sensing. Combining them with polymers tunes their chemical, mechanical, electrical and optical properties, and endows MOFs with processability. Covalent organic frameworks (COFs) are crystalline porous materials built from organic molecular units with diverse structures and applications. Hybrid materials with intriguing properties can be achieved by appropriate preparation methods and careful selection of MOFs/COFs and polymers, broadening their potential applications. This book documents the latest research progress in MOF/COF-polymer hybrid materials and reviews and summarises hybridization strategies to achieve MOF/COF polymeric composites. It also introduces various applications and potential applicable scenarios of hybrid MOF/COF polymers. Hybrid Metal–Organic Framework and Covalent Organic Framework Polymers offers an overview to readers who are new to this field, and will appeal to graduate students and researchers working on porous materials, polymers, hybrid materials, and supramolecular chemistry.
Showcases the highly beneficial features arising from the presence of main group elements in organic materials, for the development of more sophisticated, yet simple advanced functional materials Functional organic materials are already a huge area of academic and industrial interest for a host of electronic applications such as Organic Light-Emitting Diodes (OLEDs), Organic Photovoltaics (OPVs), Organic Field-Effect Transistors (OFETs), and more recently Organic Batteries. They are also relevant to a plethora of functional sensory applications. This book provides an in-depth overview of the expanding field of functional hybrid materials, highlighting the incredibly positive aspects of main group centers and strategies that are furthering the creation of better functional materials. Main Group Strategies towards Functional Hybrid Materials features contributions from top specialists in the field, discussing the molecular, supramolecular and polymeric materials and applications of boron, silicon, phosphorus, sulfur, and their higher homologues. Hypervalent materials based on the heavier main group elements are also covered. The structure of the book allows the reader to compare differences and similarities between related strategies for several groups of elements, and to draw crosslinks between different sections. The incorporation of main group elements into functional organic materials has emerged as an efficient strategy for tuning materials properties for a wide range of practical applications Covers molecular, supramolecular and polymeric materials featuring boron, silicon, phosphorus, sulfur, and their higher homologues Edited by internationally leading researchers in the field, with contributions from top specialists Main Group Strategies towards Functional Hybrid Materials is an essential reference for organo-main group chemists pursuing new advanced functional materials, and for researchers and graduate students working in the fields of organic materials, hybrid materials, main group chemistry, and polymer chemistry.
Hybrid organic-inorganic perovskites (HOIPs) have attracted substantial interest due to their chemical variability, structural diversity and favorable physical properties the past decade. This materials class encompasses other important families such as formates, azides, dicyanamides, cyanides and dicyanometallates. The book summarizes the chemical variability and structural diversity of all known hybrid organic-inorganic perovskites subclasses including halides, azides, formates, dicyanamides, cyanides and dicyanometallates. It also presents a comprehensive account of their intriguing physical properties, including photovoltaic, optoelectronic, dielectric, magnetic, ferroelectric, ferroelastic and multiferroic properties. Moreover, the current challenges and future opportunities in this exciting field are also been discussed. This timely book shows the readers a complete landscape of hybrid organic-inorganic pervoskites and associated multifuctionalities.
The contributors to this book discuss inorganic synthesis reactions, dealing with inorganic synthesis and preparative chemistry under specific conditions. They go on to describe the synthesis, preparation and assembly of six important categories of compounds with wide coverage of distinct synthetic chemistry systems
Hybrid Composite Perovskite Materials: Design to Applications discusses the manufacturing, design and characterization of organic-inorganic perovskite composite materials. The book goes beyond the basics of characterization and discusses physical properties, surface morphology and environmental stability. Users will find extensive examples of real-world products that are suitable for the needs of the market. Following a logical order, the book begins with mathematical background and then covers innovative approaches to physical modeling, analysis and design techniques. Numerous examples illustrate the proposed methods and results, making this book a sound resource on the modern research application of perovskite composites with real commercial value.
This book provides an overview of polymer nanocomposites and hybrid materials with polyhedral oligomeric silsesquioxanes (POSS). Among inorganic nanoparticles, functionalized POSS are unique nano-building blocks that can be used to create a wide variety of hybrid and composite materials, where precise control of nanostructures and properties is required. This book describes the influence of incorporation of POSS moieties into (organic) polymer matrices on the mechanical, thermal and flammability behavior of composites and hybrid organic-inorganic materials. Importantly, POSS-containing materials can be bio-functionalized by linking e.g. peptides and growth factors through appropriate surface modification in order to enhance the haemo-compatibility of cardiovascular devices made of these materials. This volume includes descriptions of synthesis routes of POSS and POSS-containing polymeric materials (e.g. based on polyolefines, epoxy resins and polyurethanes), presentation of POSS’ role as flame retardants and as biocompatible linker, as well as the depiction of decomposition and ageing processes.