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An international conference. titled Nonlinear Phenomena in Chemical Dynamics was held in Bordeaux on September 7-11, 1981. The present volume contains the text of lectures and abstracts of posters presented during the meeting. This conference is part of a series of scientific multidisciplinary meetings in which chemistry is involved at various levels. Amongst the most recent ones let us mention Aachen 1979, Bielefeld 1979, New York 1979, Elmau 1981. In addition, this meeting is a direct extension of the first one that took place in Bordeaux in 1978 on the topic "Far from equilibrium: instabilities and structures," at the conclusions of which we could write (cf. Far fram Equilibrium, Springer Series in Synergetics, Vol. 3): "The three key words, far fram equilibriUm, instabilities and structuPes, best illustrate the new concepts which emerge from the description of the dynamics of various systems relevant to many different research areas. " The present proceedings show how much these remarks have remained true, even though substantial progress has been achieved during the three last years. To get a ,deeper experimental knowledge of open reacting systems, to model and simulate reaction-diffusion systems, to develop the mathematical theory of dynamical sys tems, these are the main direction~ in current investigations.
Just a few decades ago, chemical oscillations were thought to be exotic reactions of only theoretical interest. Now known to govern an array of physical and biological processes, including the regulation of the heart, these oscillations are being studied by a diverse group across the sciences. This book is the first introduction to nonlinear chemical dynamics written specifically for chemists. It covers oscillating reactions, chaos, and chemical pattern formation, and includes numerous practical suggestions on reactor design, data analysis, and computer simulations. Assuming only an undergraduate knowledge of chemistry, the book is an ideal starting point for research in the field. The book begins with a brief history of nonlinear chemical dynamics and a review of the basic mathematics and chemistry. The authors then provide an extensive overview of nonlinear dynamics, starting with the flow reactor and moving on to a detailed discussion of chemical oscillators. Throughout the authors emphasize the chemical mechanistic basis for self-organization. The overview is followed by a series of chapters on more advanced topics, including complex oscillations, biological systems, polymers, interactions between fields and waves, and Turing patterns. Underscoring the hands-on nature of the material, the book concludes with a series of classroom-tested demonstrations and experiments appropriate for an undergraduate laboratory.
This textbook is aimed at newcomers to nonlinear dynamics and chaos, especially students taking a first course in the subject. The presentation stresses analytical methods, concrete examples, and geometric intuition. The theory is developed systematically, starting with first-order differential equations and their bifurcations, followed by phase plane analysis, limit cycles and their bifurcations, and culminating with the Lorenz equations, chaos, iterated maps, period doubling, renormalization, fractals, and strange attractors.
The Advanced Study Institute (ASI) on Nonlinear Phenomena-in Physics and Biology was held at the Banff Centre, Banff, Alberta, Canada, from 17 - 29 August, 1980. The Institute was made possible through funding by the North Atlantic Treaty Organization (who sup plied the major portion of the financial aid), the National Research and Engineering Council of Canada, and Simon Fraser University. The availability of the Banff Centre was made possible through the co sponsorship (with NATO) of the ASI by the Canadian Association of Physicists. 12 invited lecturers and 82 other participants attended the Institute. Except for two lectures on nonlinear waves by Norman Zabusky, which were omitted because it was felt that they already had been exhaustively treated in the available literature, this volume contains the entire text of the invited lectures. In addition, short reports on some of the contributed talks have also been included. The rationale for the ASI and this resulting volume was that many of the hardest problems and most interesting phenomena being studied by scientists today ar.e nonlinear in nature. The nonlinear models involved often span several different disciplines, °a simple example being the Volterra-type model in population dynamics which has its analogue in nonlinear optics and plasma physics (the 3-wave problem), in the discussion of the social behavior of animals, and in biological competition and selection at the molecular level.
FolJowing the formulation of the laws of mechanics by Newton, Lagrange sought to clarify and emphasize their geometrical character. Poincare and Liapunov successfuIJy developed analytical mechanics further along these lines. In this approach, one represents the evolution of all possible states (positions and momenta) by the flow in phase space, or more efficiently, by mappings on manifolds with a symplectic geometry, and tries to understand qualitative features of this problem, rather than solving it explicitly. One important outcome of this line of inquiry is the discovery that vastly different physical systems can actually be abstracted to a few universal forms, like Mandelbrot's fractal and Smale's horse-shoe map, even though the underlying processes are not completely understood. This, of course, implies that much of the observed diversity is only apparent and arises from different ways of looking at the same system. Thus, modern nonlinear dynamics 1 is very much akin to classical thermodynamics in that the ideas and results appear to be applicable to vastly different physical systems. Chaos theory, which occupies a central place in modem nonlinear dynamics, refers to a deterministic development with chaotic outcome. Computers have contributed considerably to progress in chaos theory via impressive complex graphics. However, this approach lacks organization and therefore does not afford complete insight into the underlying complex dynamical behavior. This dynamical behavior mandates concepts and methods from such areas of mathematics and physics as nonlinear differential equations, bifurcation theory, Hamiltonian dynamics, number theory, topology, fractals, and others.
Nonlinear Systems and Methods For Mechanical, Electrical and Biosystems presents topics observed at the 3rd Conference on Nonlinear Science and Complexity(NSC), focusing on energy transfer and synchronization in hybrid nonlinear systems. The studies focus on fundamental theories and principles,analytical and symbolic approaches, computational techniques in nonlinear physical science and mathematics. Broken into three parts, the text covers: Parametrical excited pendulum, nonlinear dynamics in hybrid systems, dynamical system synchronization and (N+1) body dynamics as well as new views different from the existing results in nonlinear dynamics, mathematical methods for dynamical systems including conservation laws, dynamical symmetry in nonlinear differential equations and invex energies and nonlinear phenomena in physical problems such as solutions, complex flows, chemical kinetics, Toda lattices and parallel manipulator. This book is useful to scholars, researchers and advanced technical members of industrial laboratory facilities developing new tools and products.
Scientists in many fields are now expressing considerable interest in non-linearity and the ideas of oscillations and chaos. Chemical reactions provide perfect examples of these phenomena, as oscillating reactions, explosions, ignition, travelling waves, patterns, quasiperiodicity, and chaosare all features of chemical kinetics.Now available in paperback, this book introduces non-linear phenomena in chemical kinetics using simple model schemes. These models involve chemical feedback, such as chain branching, autocatalysis, and self-heating. The emphasis is on physical and pictorial representation, and on identifying thosegross features which are essential. The experimental conditions under which such behaviour will occur can be predicted using simple mathematical recipes, and these are also included.The first part of the book begins with a discussion of long-lived oscillations for autocatalytic or exothermic reactions in closed vessels. Stationary states, bistability, and oscillations in continuous flow reactors and diffusion cells are then considered. This is followed by chemical wavepropagation and by pattern selection and oscillations. Complex oscillations, quasiperiodicity, and chemical chaos, either forced or spontaneous, are introduced. Part 2 deals with real experimental systems, describing observed experimental behaviour and its interpretation in terms of the underlyingchemical mechanisms or simplified models. The Belousov-Zhabotinskii reactions is discussed in some detail as the most extensively studied system, and the behaviour of important gas phase reactions is presented.
This book starts with a discussion of nonlinear ordinary differential equations, bifurcation theory and Hamiltonian dynamics. It then embarks on a systematic discussion of the traditional topics of modern nonlinear dynamics -- integrable systems, Poincaré maps, chaos, fractals and strange attractors. The Baker’s transformation, the logistic map and Lorenz system are discussed in detail in view of their central place in the subject. There is a detailed discussion of solitons centered around the Korteweg-deVries equation in view of its central place in integrable systems. Then, there is a discussion of the Painlevé property of nonlinear differential equations which seems to provide a test of integrability. Finally, there is a detailed discussion of the application of fractals and multi-fractals to fully-developed turbulence -- a problem whose understanding has been considerably enriched by the application of the concepts and methods of modern nonlinear dynamics. On the application side, there is a special emphasis on some aspects of fluid dynamics and plasma physics reflecting the author’s involvement in these areas of physics. A few exercises have been provided that range from simple applications to occasional considerable extension of the theory. Finally, the list of references given at the end of the book contains primarily books and papers used in developing the lecture material this volume is based on. This book has grown out of the author’s lecture notes for an interdisciplinary graduate-level course on nonlinear dynamics. The basic concepts, language and results of nonlinear dynamical systems are described in a clear and coherent way. In order to allow for an interdisciplinary readership, an informal style has been adopted and the mathematical formalism has been kept to a minimum. This book is addressed to first-year graduate students in applied mathematics, physics, and engineering, and is useful also to any theoretically inclined researcher in the physical sciences and engineering. This second edition constitutes an extensive rewrite of the text involving refinement and enhancement of the clarity and precision, updating and amplification of several sections, addition of new material like theory of nonlinear differential equations, solitons, Lagrangian chaos in fluids, and critical phenomena perspectives on the fluid turbulence problem and many new exercises.