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The problem of deriving irreversible thermodynamics from the re versible microscopic dynamics has been on the agenda of theoreti cal physics for a century and has produced more papers than can be digested by any single scientist. Why add to this too long list with yet another work? The goal is definitely not to give a gen eral review of previous work in this field. My ambition is rather to present an approach differing in some key aspects from the stan dard treatments, and to develop it as far as possible using rather simple mathematical tools (mainly inequalities of various kinds). However, in the course of this work I have used a large number of results and ideas from the existing literature, and the reference list contains contributions from many different lines of research. As a consequence the reader may find the arguments a bit difficult to follow without some previous exposure to this set of problems.
Statistical mechanics has been proven to be successful at describing physical systems at thermodynamic equilibrium. Since most natural phenomena occur in nonequilibrium conditions, the present challenge is to find suitable physical approaches for such conditions: this book provides a pedagogical pathway that explores various perspectives. The use of clear language, and explanatory figures and diagrams to describe models, simulations and experimental findings makes the book a valuable resource for undergraduate and graduate students, and also for lecturers organizing teaching at varying levels of experience in the field. Written in three parts, it covers basic and traditional concepts of nonequilibrium physics, modern aspects concerning nonequilibrium phase transitions, and application-orientated topics from a modern perspective. A broad range of topics is covered, including Langevin equations, Levy processes, directed percolation, kinetic roughening and pattern formation.
This book concentrates on the properties of the stationary states in chaotic systems of particles or fluids, leaving aside the theory of the way they can be reached. The stationary states of particles or of fluids (understood as probability distributions on microscopic configurations or on the fields describing continua) have received important new ideas and data from numerical simulations and reviews are needed. The starting point is to find out which time invariant distributions come into play in physics. A special feature of this book is the historical approach. To identify the problems the author analyzes the papers of the founding fathers Boltzmann, Clausius and Maxwell including translations of the relevant (parts of) historical documents. He also establishes a close link between treatment of irreversible phenomena in statistical mechanics and the theory of chaotic systems at and beyond the onset of turbulence as developed by Sinai, Ruelle, Bowen (SRB) and others: the author gives arguments intending to support strongly the viewpoint that stationary states in or out of equilibrium can be described in a unified way. In this book it is the "chaotic hypothesis", which can be seen as an extension of the classical ergodic hypothesis to non equilibrium phenomena, that plays the central role. It is shown that SRB - often considered as a kind of mathematical playground with no impact on physical reality - has indeed a sound physical interpretation; an observation which to many might be new and a very welcome insight. Following this, many consequences of the chaotic hypothesis are analyzed in chapter 3 - 4 and in chapter 5 a few applications are proposed. Chapter 6 is historical: carefully analyzing the old literature on the subject, especially ergodic theory and its relevance for statistical mechanics; an approach which gives the book a very personal touch. The book contains an extensive coverage of current research (partly from the authors and his coauthors publications) presented in enough detail so that advanced students may get the flavor of a direction of research in a field which is still very much alive and progressing. Proofs of theorems are usually limited to heuristic sketches privileging the presentation of the ideas and providing references that the reader can follow, so that in this way an overload of this text with technical details could be avoided.
Groundbreaking monograph by Nobel Prize winner for researchers and graduate students covers Liouville equation, anharmonic solids, Brownian motion, weakly coupled gases, scattering theory and short-range forces, general kinetic equations, more. 1962 edition.
A comprehensive and pedagogical text on nonequilibrium statistical physics, covering topics from random walks to pattern formation.
This text on the statistical theory of nonequilibrium phenomena grew out of lecture notes for courses on advanced statistical mechanics that were held more or less regularly at the Physics Department of the Technical University in Munich. My aim in these lectures was to incorporate various developments of many-body theory made during the last 20-30 years, in particular the correlation function approach, not just as an "extra" alongside the more "classical" results; I tried to use this approach as a unifying concept for the presentation of older as well as more recent results. I think that after so many excellent review articles and advanced treatments, correlation functions and memory kernels are as much a matter of course in nonequilibrium statistical physics as partition functions are in equilibrium theory, and should be used as such in regular courses and textbooks. The relations between correlation functions and earlier vehicles for the formulation of nonequilibrium theory such as kinetic equations, master equations, Onsager's theory, etc. , are discussed in detail in this volume. Since today there is growing interest in nonlinear phenomena I have included several chapters on related problems. There is some nonlinear response theory, some results on phenomenological nonlinear equations and some microscopic applications of the nonlinear response formalism. The main focus, however, is on the linear regime.
This book encompasses our current understanding of the ensemble approach to many-body physics, phase transitions and other thermal phenomena, as well as the quantum foundations of linear response theory, kinetic equations and stochastic processes. It is destined to be a standard text for graduate students, but it will also serve the specialist-researcher in this fascinating field; some more elementary topics have been included in order to make the book self-contained.The historical methods of J Willard Gibbs and Ludwig Boltzmann, applied to the quantum description rather than phase space, are featured. The tools for computations in the microcanonical, canonical and grand-canonical ensembles are carefully developed and then applied to a variety of classical and standard quantum situations. After the language of second quantization has been introduced, strongly interacting systems, such as quantum liquids, superfluids and superconductivity, are treated in detail. For the connoisseur, there is a section on diagrammatic methods and applications.In the second part dealing with non-equilibrium processes, the emphasis is on the quantum foundations of Markovian behaviour and irreversibility via the Pauli-Van Hove master equation. Justifiable linear response expressions and the quantum-Boltzmann approach are discussed and applied to various condensed matter problems. From this basis the Onsager-Casimir relations are derived, together with the mesoscopic master equation, the Langevin equation and the Fokker-Planck truncation procedure. Brownian motion and modern stochastic problems such as fluctuations in optical signals and radiation fields briefly make the round.
Alternative Mathematical Theory of Non-equilibrium Phenomena presents an entirely new theoretical approach to complex non-equilibrium phenomena, especially Gibbs/Falk thermodynamics and fluid mechanics. This innovative new theory allows for inclusion of all state variables and introduces a new vector-dissipation velocity-which leads to useful restatements of momentum, the Second Law, and tensors for the laws of motion, friction, and heat conduction. This application-oriented text is relatively self-contained and is an excellent guide-book for engineers with a strong interest in fundamentals, or for professionals using applied mathematics and physics in engineering applications. This book emphasizes macroscopic phenomena, focusing specifically on gaseous states, though relations to liquid and crystalline states are also considered. The author presents a new Alternative Continuum Theory of Compressible Fluids (AT) which providesa qualitative description of the subject in predominantly physical terms, minimizing the mathematical premises. The methodology discussed has applications in a wide range of fields outside of physics in areas including General System Theory, TheoreticalEconomics, and Biophysics and Medicine. Presents the first theory capable of handling non-equilibria phenomena Offers a unified theory of all branches of macroscopic physics Considers a consistent and uniform view of reality, supported by modern mathematics, leading to results different than those produced by classical theories Results in a change of paradigms in physics, engineering, and natural philosophy
Natural phenomena consist of simultaneously occurring transport processes and chemical reactions. These processes may interact with each other and may lead to self-organized structures, fluctuations, instabilities, and evolutionary systems. Nonequilibrium Thermodynamics, Third Edition emphasizes the unifying role of thermodynamics in analyzing the natural phenomena. This third edition updates and expands on the first and second editions by focusing on the general balance equations for coupled processes of physical, chemical, and biological systems. The new edition contains a new chapter on stochastic approaches to include the statistical thermodynamics, mesoscopic nonequilibrium thermodynamics, fluctuation theory, information theory, and modeling the coupled biochemical systems in thermodynamic analysis. This new addition also comes with more examples and practice problems. - Informs and updates on all the latest developments in the field - Contributions from leading authorities and industry experts - A useful text for seniors and graduate students from diverse engineering and science programs to analyze some nonequilibrium, coupled, evolutionary, stochastic, and dissipative processes - Highlights fundamentals of equilibrium thermodynamics, transport processes and chemical reactions - Expands the theory of nonequilibrium thermodynamics and its use in coupled transport processes and chemical reactions in physical, chemical, and biological systems - Presents a unified analysis for transport and rate processes in various time and space scales - Discusses stochastic approaches in thermodynamic analysis including fluctuation and information theories - Has 198 fully solved examples and 287 practice problems - An Instructor Resource containing the Solution Manual can be obtained from the author: [email protected]