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This book puts emphasis on developing the basic ideas behind the different approaches to non-equilibrium thermodynamics and on applying them to solids. After a survey about different approaches an introduction to their common fundamentals is given in the first part. In the second part the mechanical behavior of special materials such as viscoelasticity, viscoplasticity, viscoelastoplasticity, and thermoplasticity are discussed. The third part is devoted to extended thermodynamics. The basic ideas, phenomenological as well as microscopical, are reviewed and applied to thermo- and viscoelastic materials. Electromagnetic solids showing dielectric relaxation, such as ceramics, showing electromagneto-mechanical hysteresis and superconductivity are treated in the fourth part. In the last part stability with regard to constitutive equations is investigated. Especially stability of quasi-static processes and of elastic-plastic systems are discussed.
Maximum Dissipation: Non-Equilibrium Thermodynamics and its Geometric Structure explores the thermodynamics of non-equilibrium processes in materials. The book develops a general technique created in order to construct nonlinear evolution equations describing non-equilibrium processes, while also developing a geometric context for non-equilibrium thermodynamics. Solid materials are the main focus in this volume, but the construction is shown to also apply to fluids. This volume also: • Explains the theory behind thermodynamically-consistent construction of non-linear evolution equations for non-equilibrium processes • Provides a geometric setting for non-equilibrium thermodynamics through several standard models, which are defined as maximum dissipation processes • Emphasizes applications to the time-dependent modeling of soft biological tissue Maximum Dissipation: Non-Equilibrium Thermodynamics and its Geometric Structure will be valuable for researchers, engineers and graduate students in non-equilibrium thermodynamics and the mathematical modeling of material behavior.
Groundbreaking monograph by Nobel Prize winner for researchers and graduate students covers Liouville equation, anharmonic solids, Brownian motion, weakly coupled gases, scattering theory and short-range forces, general kinetic equations, more. 1962 edition.
Natural phenomena consist of simultaneously occurring transport processes and chemical reactions. These processes may interact with each other and may lead to self-organized structures, fluctuations, instabilities, and evolutionary systems. Nonequilibrium Thermodynamics, Third Edition emphasizes the unifying role of thermodynamics in analyzing the natural phenomena. This third edition updates and expands on the first and second editions by focusing on the general balance equations for coupled processes of physical, chemical, and biological systems. The new edition contains a new chapter on stochastic approaches to include the statistical thermodynamics, mesoscopic nonequilibrium thermodynamics, fluctuation theory, information theory, and modeling the coupled biochemical systems in thermodynamic analysis. This new addition also comes with more examples and practice problems. - Informs and updates on all the latest developments in the field - Contributions from leading authorities and industry experts - A useful text for seniors and graduate students from diverse engineering and science programs to analyze some nonequilibrium, coupled, evolutionary, stochastic, and dissipative processes - Highlights fundamentals of equilibrium thermodynamics, transport processes and chemical reactions - Expands the theory of nonequilibrium thermodynamics and its use in coupled transport processes and chemical reactions in physical, chemical, and biological systems - Presents a unified analysis for transport and rate processes in various time and space scales - Discusses stochastic approaches in thermodynamic analysis including fluctuation and information theories - Has 198 fully solved examples and 287 practice problems - An Instructor Resource containing the Solution Manual can be obtained from the author: [email protected]
This book provides the fundamental statistical theory of atomic transport in crystalline solids, that is the means by which processes occurring at the atomic level are related to macroscopic transport coefficients and other observable quantities. The cornerstones of the authors' treatment are (i) the physical concepts of lattice defects, (ii) the phenomenological description provided by non-equilibrium thermodynamics and (iii) the various methods of statistical mechanics used to link these (kinetic theory, random-walk theory, linear response theory etc.). The book is primarily concerned with transport in the body of crystal lattices and not with transport on surfaces, within grain boundaries or along dislocations, although much of the theory here presented can be applied to these low-dimensional structures when they are atomically well ordered and regular.
Modern Thermodynamics: From Heat Engines to Dissipative Structures, Second Edition presents a comprehensive introduction to 20th century thermodynamics that can be applied to both equilibrium and non-equilibrium systems, unifying what was traditionally divided into ‘thermodynamics’ and ‘kinetics’ into one theory of irreversible processes. This comprehensive text, suitable for introductory as well as advanced courses on thermodynamics, has been widely used by chemists, physicists, engineers and geologists. Fully revised and expanded, this new edition includes the following updates and features: Includes a completely new chapter on Principles of Statistical Thermodynamics. Presents new material on solar and wind energy flows and energy flows of interest to engineering. Covers new material on self-organization in non-equilibrium systems and the thermodynamics of small systems. Highlights a wide range of applications relevant to students across physical sciences and engineering courses. Introduces students to computational methods using updated Mathematica codes. Includes problem sets to help the reader understand and apply the principles introduced throughout the text. Solutions to exercises and supplementary lecture material provided online at http://sites.google.com/site/modernthermodynamics/. Modern Thermodynamics: From Heat Engines to Dissipative Structures, Second Edition is an essential resource for undergraduate and graduate students taking a course in thermodynamics.
This textbook on thermodynamics is intended primarily for honours and B. Sc students majoring in physical chemistry. However, students of physics, engineering and biochemistry will also find the book relevant to their studies.Its principal features are a much shorter presentation of the laws of thermodynamics than is customary, made possible by the definition of the thermodynamic scale of temperature using only one fixed point (the triple point of water) which immediately follows the Zeroth Law. The author's first exposure to thermodynamics revealed that its usefulness seemed to be mostly confined to the study of gases in equilibrium. Readers of this book will find that applications of thermodynamics to liquids and solids as well as gases are emphasized, and they will learn that thermodynamics can be applied to systems which are not in equilibrium.This book contains three learning aids. Fully worked out examples are included at appropriate places in the text, which also includes numerous exercises. These are designed to help the reader stop and think about what he or she has just read. Answers to the exercises are given at the end of each section and there are also problems at the end of each chapter which readers can work out on their own./a
This book deals with density, temperature, velocity and concentration fluctuations in fluids and fluid mixtures. The book first reviews thermal fluctuations in equilibrium fluids on the basis of fluctuating hydrodynamics. It then shows how the method of fluctuating hydrodynamics can be extended to deal with hydrodynamic fluctuations when the system is in a stationary nonequilibrium state. In contrast to equilibrium fluids where the fluctuations are generally short ranged unless the system is close to a critical point, fluctuations in nonequilibrium fluids are always long-ranged encompassing the entire system. The book provides the first comprehensive treatment of fluctuations in fluids and fluid mixtures brought out of equilibrium by the imposition of a temperature and concentration gradient but that are still in a macroscopically quiescent state. By incorporating appropriate boundary conditions in the case of fluid layers, it is shown how fluctuating hydrodynamics affects the fluctuations close to the onset of convection. Experimental techniques of light scattering and shadowgraphy for measuring nonequilibrium fluctuations are elucidated and the experimental results thus far reported in the literature are reviewed.· Systematic exposition of fluctuating hydrodynamics and its applications· First book on nonequilibrium fluctuations in fluids· Fluctuating Boussinesq equations and nonequilibrium fluids· Fluid layers and onset of convection· Rayleigh scattering and Brillouin scattering in fluids· Shadowgraph technique for measuring fluctuations· Fluctuations near hydrodynamic instabilities
Bridging a gap in the literature, Professor Ericksen has drawn on his experience in research on solids to devise a series of lectures for graduates that introduce and illustrate uses of various important ideas with analysis which can be done using elementary mathematics. Simple strategies are discussed for thermoelastic bars and an ideal gas-solid mixture. Illustrative examples of thermodynamic stability theory include rudimentary analysis of cold-drawing in polymers, martensitic transformations in plates, instabilities in rubber balloons and sheets, peeling tapes, breaking bars, buckling of beams and instabilities produced by electromagnetic fields in liquid crystals. Non-equilibrium theory is illustrated by head conduction in rigid and deformable bars, including a fairly common way of using the Clausius-Duhem inequality to obtain thermodynamic restrictions on constitutive equations. Also covered is some elementary one-dimensional theory of shock waves and slower-moving phase boundaries. Finally, drawing on all these experiences, the last chapter treats general ideas in a more abstract way.