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Electrolytes for Lithium and Lithium-ion Batteries provides a comprehensive overview of the scientific understanding and technological development of electrolyte materials in the last several years. This book covers key electrolytes such as LiPF6 salt in mixed-carbonate solvents with additives for the state-of-the-art Li-ion batteries as well as new electrolyte materials developed recently that lay the foundation for future advances. This book also reviews the characterization of electrolyte materials for their transport properties, structures, phase relationships, stabilities, and impurities. The book discusses in-depth the electrode-electrolyte interactions and interphasial chemistries that are key for the successful use of the electrolyte in practical devices. The Quantum Mechanical and Molecular Dynamical calculations that has proved to be so powerful in understanding and predicating behavior and properties of materials is also reviewed in this book. Electrolytes for Lithium and Lithium-ion Batteries is ideal for electrochemists, engineers, researchers interested in energy science and technology, material scientists, and physicists working on energy.
The electrolyte plays a vital role for the performance of rechargeable lithium batteries with a Li metal anode as well as Li-ion batteries. A better understanding of the elementary processes involved in the formation of the electrolyte/electrode interface and charge transfer kinetics in relation to solvent, salt, additive, and electrode material is crucial to the further optimization of Li and Li-ion batteries. This issue will focus on both the fundamental and applied aspects of the electrolyte for Li and Li-ion batteries. Topics include theoretical and experimental studies of structure/property relationships of electrolytes; development of new salts, solvents and additives; development of electrolytes for 5 V Li and Li-ion batteries; studies and approaches leading to the understanding of electrode/electrolyte interfacial phenomena and the charge transfer processes; electrolytes with enhanced non-flammability; electrolytes for wide temperature range operations; and cell performance improvement with respect to that of electrolyte materials.
Synthesis, Technology and Applications of Carbon Nanomaterials explores the chemical properties of different classes of carbon nanomaterials and their major applications. As carbon nanomaterials are used for a variety of applications due to their versatile properties and characteristics, this book discusses recent advances in synthesis methods, characterization, and applications of 0D -3D dimensional carbon nanomaterials. It is an essential resource for readers focusing on carbon nanomaterials research. - Explores the chemical properties of different classes of carbon nanomaterials and their major applications - Discusses recent advances in synthesis methods, characterization, and applications of 0D -3D dimensional carbon nanomaterials
The handbook focuses on a complete outline of lithium-ion batteries. Just before starting with an exposition of the fundamentals of this system, the book gives a short explanation of the newest cell generation. The most important elements are described as negative / positive electrode materials, electrolytes, seals and separators. The battery disconnect unit and the battery management system are important parts of modern lithium-ion batteries. An economical, faultless and efficient battery production is a must today and is represented with one chapter in the handbook. Cross-cutting issues like electrical, chemical, functional safety are further topics. Last but not least standards and transportation themes are the final chapters of the handbook. The different topics of the handbook provide a good knowledge base not only for those working daily on electrochemical energy storage, but also to scientists, engineers and students concerned in modern battery systems.
Battery technology is constantly changing, and the concepts and applications of these changes are rapidly becoming increasingly more important as more and more industries and individuals continue to make “greener” choices in their energy sources. As global dependence on fossil fuels slowly wanes, there is a heavier and heavier importance placed on cleaner power sources and methods for storing and transporting that power. Battery technology is a huge part of this global energy revolution. Zinc batteries are an advantageous choice over lithium-based batteries, which have dominated the market for years in multiple areas, most specifically in electric vehicles and other battery-powered devices. Zinc is the fourth most abundant metal in the world, which is influential in its lower cost, making it a very attractive material for use in batteries. Zinc-based batteries have been around since the 1930s, but only now are they taking center stage in the energy, automotive, and other industries. Zinc Batteries: Basics, Developments, and Applicationsis intended as a discussion of the different zinc batteries for energy storage applications. It also provides an in-depth description of various energy storage materials for Zinc (Zn) batteries. This book is an invaluable reference guide for electrochemists, chemical engineers, students, faculty, and R&D professionals in energy storage science, material science, and renewable energy.
This invaluable book focuses on the mechanisms of formation of a solid-electrolyte interphase (SEI) on the electrode surfaces of lithium-ion batteries. The SEI film is due to electromechanical reduction of species present in the electrolyte. It is widely recognized that the presence of the film plays an essential role in the battery performance, and its very nature can determine an extended (or shorter) life for the battery. In spite of the numerous related research efforts, details on the stability of the SEI composition and its influence on the battery capacity are still controversial. This book carefully analyzes and discusses the most recent findings and advances on this topic.
An excellent resource for all graduate students and researchers using electrochemical techniques. After introducing the reader to the fundamentals, the book focuses on the latest developments in the techniques and applications in this field. This second edition contains new material on environmentally-friendly solvents, such as room-temperature ionic liquids.
Electricity from renewable sources of energy is plagued by fluctuations (due to variations in wind strength or the intensity of insolation) resulting in a lack of stability if the energy supplied from such sources is used in 'real time'. An important solution to this problem is to store the energy electrochemically (in a secondary battery or in hydrogen and its derivatives) and to make use of it in a controlled fashion at some time after it has been initially gathered and stored. Electrochemical battery storage systems are the major technologies for decentralized storage systems and hydrogen is the only solution for long-term storage systems to provide energy during extended periods of low wind speeds or solar insolation. Future electricity grid design has to include storage systems as a major component for grid stability and for security of supply. The technology of systems designed to achieve this regulation of the supply of renewable energy, and a survey of the markets that they will serve, is the subject of this book. It includes economic aspects to guide the development of technology in the right direction. - Provides state-of-the-art information on all of the storage systems together with an assessment of competing technologies - Features detailed technical, economic and environmental impact information of different storage systems - Contains information about the challenges that must be faced for batteries and hydrogen-storage to be used in conjunction with a fluctuating (renewable energy) power supply
Includes details of the fundamental phenomenological theories of solar cells, Li ion/ Li-air/Li-S batteries, fuel cells and their energy storage mechanisms. Discusses properties of various energy materials in addition to their device operation and evaluation. - Includes details of the fundamental phenomenological theories of solar cells, Li ion/ Li-air/Li-S batteries, fuel cells and their energy storage mechanisms - Discusses properties of various energy materials in addition to their device operation and evaluation
The 21 chapters in this book presents a comprehensive overview of flexible supercapacitors using engineering nanoarchitectures mediated by functional nanomaterials and polymers as electrodes, electrolytes, and separators, etc. for advanced energy applications. The various aspects of flexible supercapacitors, including capacitor electrochemistry, evaluating parameters, operating conditions, characterization techniques, different types of electrodes, electrolytes, and flexible substrates are covered. This is probably the first book of its type which systematically describes the recent developments and progress in flexible supercapacitor technology, and will be very helpful for generating new and innovative ideas in the field of energy storage material for wearable/flexible industry applications.