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Disinfection of potable water is one of the great public health victories of the twentieth century, responsible for the avoidance of millions of deaths due to waterborne illness. However, application of disinfectants, typically chemical oxidants, leads to formation of hundreds of trace contaminants, often carcinogens, and consumption of chlorinated water has been epidemiologically linked to bladder cancer and certain birth defects. Eleven of these compounds are federally regulated in drinking water, but certain non-regulated disinfection byproducts (DBPs) are orders of magnitude more toxic than currently regulated compounds. Two specific DBPs, chloropicrin and N-nitrosodimethylamine (NDMA), are especially genotoxic, and are associated with nitrogen input into drinking water supplies. Wastewater-impacted drinking water and recycled wastewater are enriched in the precursors of these compounds, and their formation during potable water treatment is likely to grow, as wastewater increasingly contributes to the water supply. This thesis focuses on applying the tools of environmental organic chemistry to identify the chemical precursors and formation mechanisms of these compounds, leading to strategies for their control during water treatment. In particular, ozonation of primary and secondary amine compounds, leading to formation of nitro compound intermediates, was found be responsible for chloropicrin formation during water treatment. Secondary N-methylamines and primary amines geminal to facile leaving groups were particularly potent precursors, forming chloropicrin at up to 50% yield when exposed to ozone followed by chlorine. Based on this predominant formation pathway, chloropicrin precursors may be oxidized upstream of ozone addition to prevent chloropicrin formation. Strategies for controlling NDMA formation, a major concern during wastewater recycling, were developed based on an understanding of the chemical composition of NDMA precursors, and chloramines, the primary disinfectant applied during wastewater reuse. Minor modifications to wastewater recycling operations, in particular switching from low-pressure to medium-pressure mercury lamps for ultraviolet light treatment, and minor adjustments in the application of chloramines, were shown to dramatically reduce NDMA concentrations in final effluent. Finally, the effluent from a new, all-anaerobic wastewater treatment system was demonstrated to more efficiently remove trace contaminants and DBP precursors than conventional aerobic treatment, suggesting that this energy-saving technology may also be more suitable for water reuse than conventional treatment. These findings facilitate reducing the chronic health risk associated with consumption of (intentionally or unintentionally) recycled wastewater.
Disinfection Byproducts in Drinking Water: Detection and Treatment presents cutting-edge research on how to understand the procedures, processes and considerations for detecting and treating disinfection by-products from drinking water, swimming pool water, and wastewater. The book begins with an overview of the different groups of Disinfection Byproducts (DBPs), such as: Trihalomethanes (THM), Halo acetic acids, and Haloacetonitrile (HAN). This coverage is quickly followed by a clear and rigorous exposition of the latest methods and technologies for the characterization, occurrence, formation, transformation and removal of DBPs in drinking water. Other chapters focus on ultraviolet-visible spectroscopy, electron spin resonance, and gas chromatography-mass spectrometry. Researchers will find a valuable resource to a breath of topics for DBP detection and treatment, including various recent techniques, such as microfiltration, nanofiltration membrane and nanotechnology. Explains the latest research in detection, treatment processes and remediation technologies Includes sampling, analytical and characterization methods and approaches Covers cutting-edge research, including membrane based technologies, nanotechnology treatment technologies and bioremediation treatment technologies Provides background information regarding contamination sources
Fundamentals and Applications of Fourier Transform Mass Spectrometry is the first book to delve into the underlying principles on the topic and their linkage to industrial applications. Drs. Schmitt-Kopplin and Kanawati have brought together a team of leading experts in their respective fields to present this technique from many different perspectives, describing, at length, the pros and cons of FT-ICR and Orbitrap. Numerous examples help researchers decide which instruments to use for their particular scientific problem and which data analysis methods should be applied to get the most out of their data. Covers FT-ICR-MS and Orbitrap’s fundamentals, enhancing researcher knowledge Includes details on ion sources, data processing, chemical analysis and imaging Provides examples across the wide spectrum of applications, including omics, environmental, chemical, pharmaceutical and food analysis
This book is a collection of chapters on the latest international research findings, including emerging issues and state-of-the-art studies, related to disinfection by-product formation and control in drinking waters and treated wastewaters.
There is a concern that disinfection byproducts (DBPs) produced in wastewater effluent may adversely impact the downstream aquatic system and drinking water resources. It is thus imperative to understand the occurrence, fate, transport, and removal of DBPs and DBP precursors to allow further wastewater reuse practices. This work contributed to this topic with the following efforts: 1) a nation-wide survey of the occurrences of many disinfection byproducts; 2) a comparison of the DBP formation potentials of effluent and natural organic matter, termed as dissolved organic carbon and nitrogen; 3) an evaluation of the effects of natural processes, i.e., hydrolysis, photolysis, biodegradation, volatilization, and adsorption, on reducing DBPs from surface waters; and 4) an assessment of conventional water treatment processes in removing DBP precursors. The results indicated the importance of wastewater effluent as a source of many DBPs, highlighted the role of organic nitrogen in forming nitrogenous DBPs, discovered the specificity of natural mechanisms in mitigating DBPs, and identified the deficiency of conventional treatment processes in respond to potential wastewater impact.
Provides an excellent balance between theory and applications in the ever-evolving field of water and wastewater treatment Completely updated and expanded, this is the most current and comprehensive textbook available for the areas of water and wastewater treatment, covering the broad spectrum of technologies used in practice today—ranging from commonly used standards to the latest state of the art innovations. The book begins with the fundamentals—applied water chemistry and applied microbiology—and then goes on to cover physical, chemical, and biological unit processes. Both theory and design concepts are developed systematically, combined in a unified way, and are fully supported by comprehensive, illustrative examples. Theory and Practice of Water and Wastewater Treatment, 2nd Edition: Addresses physical/chemical treatment, as well as biological treatment, of water and wastewater Includes a discussion of new technologies, such as membrane processes for water and wastewater treatment, fixed-film biotreatment, and advanced oxidation Provides detailed coverage of the fundamentals: basic applied water chemistry and applied microbiology Fully updates chapters on analysis and constituents in water; microbiology; and disinfection Develops theory and design concepts methodically and combines them in a cohesive manner Includes a new chapter on life cycle analysis (LCA) Theory and Practice of Water and Wastewater Treatment, 2nd Edition is an important text for undergraduate and graduate level courses in water and/or wastewater treatment in Civil, Environmental, and Chemical Engineering.
This book is written as a reference on organic substances in natural waters and as a supplementary text for graduate students in water chemistry. The chapters address five topics: amount, origin, nature, geochemistry, and characterization of organic carbon. Of these topics, the main themes are the amount and nature of dissolved organic carbon in natural waters (mainly fresh water, although seawater is briefly discussed). It is hoped that the reader is familiar with organic chemistry, but it is not necessary. The first part of the book is a general overview of the amount and general nature of dissolved organic carbon. Over the past 10 years there has been an exponential increase in knowledge on organic substances in water, which is the result of money directed toward the research of organic compounds, of new methods of analysis (such as gas chromatography and mass spectrometry), and most importantly, the result of more people working in this field. Because of this exponential increase in knowledge, there is a need to pull together and summarize the data that has accumulated from many disciplines over the last decade.