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Negative ions formed by electron resonance capture in alkali halide vapors were investigated mass spectrometrically. Ions detected were: M( - ), X( - ), MX( - ), and M2X( - ) (M = Li, Na, K, Rb, Cs; X = F, Cl, Br, I). From measured appearance potentials and known dissociated energies, lower limits are given for the electron affinities of the alkali metals and the alkali halides.
Emphasises on contemporary applications and an intuitive problem-solving approach that helps students discover the exciting potential of chemical science. This book incorporates fresh applications from the three major areas of modern research: materials, environmental chemistry, and biological science.
For beginners and specialists in other fields: the Nobel Laureate's introduction to atomic spectra and their relationship to atomic structures, stressing basics in a physical, rather than mathematical, treatment. 80 illustrations.
Alkali Halide Vapors: Structure, Spectra, and Reaction Dynamics highlights the various studies done in the subject area of alkali halide chemistry. These studies have resulted to providing many relevant insights and paving the way for the study of more complex chemical systems. This book ultimately reviews and summarizes the said studies. This text is divided into two categories: structural and spectral properties of the alkali halide molecules and dynamics of various alkali atom-halogen reactions. The first category is discussed in Chapters 1, 3-5, and 15, while the second category is presented in Chapters 6-14. Chapter 2 however belongs to neither of the said categories as it describes the techniques and considerations related to alkali halogen experiments. Numerous quantitative data in table format are presented all of the discussions in this book. An index of these tables has been compiled and can be found in the last part of the book. This book will be a valuable material to students, scientists, and researchers in the scientific field of chemistry, physics, and applied science.
The development of excimer laser systems marked a significant turning point in the development of coherent sources. The progress of the last few years has been largely predicated upon the combined knowledge of several disciplines including atomic and molecular physics, optical technology, and pulsed power technology, the latter mainly associated with electron beam devices. The purpose of this volume is to provide a comprehensive view of this marvelously exciting field that will be of value to both active researchers and neophytes alike. Since a clear understanding of both theory and experiment is necessary to achieve this goal, these issues are presented as an integrated whole. The preparation of this work involved the dedicated cooperation of many authors dispersed both geographically and intellectually. Naturally, the editor has the responsibility to integrate and balance a diverse range of opinions to the satisfaction of all, a job not always readily accomplished. We hope that this has been performed to the satisfaction of the reader. The editor wishes to express his gratitude to the many persons whose efforts made this book possible. Most important are the authors whose work constitutes the backbone and substance of this volume and whose normal professional lives are very busy ones, indeed. I can say that they worked diligently and with good humor in the preparation of their contributions.