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Nanoporous Materials IV contains the invited lectures and peer-reviewed oral and poster contributions to be presented at the 4th International Symposium on Nanoporous Materials, which will be hosted in Niagara Falls, Ontario, Canada, June 7-10, 2005. This volume covers complementary approaches to and recent advances in the field of nanostructured materials with pore sizes larger than 1nm, such as periodic mesoporous molecular sieves (e.g., MCM-41 and SBA-15) and related materials including clays, ordered mesoporous carbons, colloidal crystal templated materials, porous polymers and sol gels. The broad range of topics covered in relation to the synthesis and characterization of ordered mesoporous materials are of great importance for advanced adsorption, catalytic, separation and environmental processes as well as for the development of nanotechnology. This volume contains over 120 contributions related to the synthesis of ordered mesoporous silicas, organosilicas, nonsiliceous inorganic materials, carbons, polymers and related materials, their characterization and applications in adsorption, catalysis and environmental clean up.* Unique contributions brings readers up-to-date on new research and application developments* Figures and tables supplement comprehensive topics * Extensive author and subject index
Atoms and molecules in all states of matter are subject to continuous irregular movement. This process, referred to as diffusion, is among the most general and basic phenomena in nature and determines the performance of many technological processes. This book provides an introduction to the fascinating world of diffusion in microporous solids. Jointly written by three well-known researchers in this field, it presents a coherent treatise, rather than a compilation of separate review articles, covering the theoretical fundamentals, molecular modeling, experimental observation and technical applications. Based on the book Diffusion in Zeolites and other Microporous Solids, originally published in 1992, it illustrates the remarkable speed with which this field has developed since that time. Specific topics include: new families of nanoporous materials, micro-imaging and single-particle tracking, direct monitoring of transient profiles by interference microscopy, single-file diffusion and new approaches to molecular modeling.
Nanoporous Materials III contains the invited lectures and peer-reviewed oral and poster contributions to be presented at the 3rd Conference on Nanoporous Materials, which will be hosted in Ottawa, Canada, June 2002. The work covers complementary approaches to and recent advances in the field of nanostructured materials with pore sizes larger than 1nm, such as periodic mesoporous molecular sieves M41S and FSM16 and related materials including clays, carbon molecular sieves, colloidal crystal templated organic and inorganic materials, porous polymers and sol gels. The broad range of topics covered in relation to the synthesis and characterization of ordered mesoporous materials are of great importance for advanced adsorption, catalytic and separation processes as well as the development of nanotechnology. The contents of this title are based on topics to be discussed by invited lecturers, which deal with periodic mesoporous organosilicas, stability and catalytic activity of aluminosilicate mesostructures, electron microscopy studies of ordered materials, imprinted polymers and highly porous metal-organic frameworks. The other contributions deal with tailoring the surface and structural properties of nanoporous materials, giving a detailed characterization as well as demonstrating their usefulness for advanced adsorption and catalytic applications.
This proceedings volume contains selected and peer-reviewed original oral and poster contributions to be presented at the 5th International Symposium on Nanoporous Materials, Vancouver, Canada, May 25OCo28, 2008. It presents recent scientific advances in the area of nanoporous materials, especially those with ordered pores of sizes between 1 and 50 nm, their synthesis, characterization and applications in adsorption, catalysis, bio-related processes, environmental cleanup and nanotechnology. A unique feature of this volume is the wide variety of nanoporous materials covered, ranging from ordered silica nanostructures, silicas with incorporated organic and inorganic species, ordered nanoporous carbons and polymers, metal organic frameworks, nanostructured catalysts to nanoporous films, membranes and monoliths. This proceedings volume reflects the current trends and advances in the field of nanomaterials, which will certainly continue to attract the attention of materials scientists around the globe. It will therefore be a valuable reference for materials scientists, chemists and physicists working in academia, national and industrial laboratories. Sample Chapter(s). Chapter 1: New Routes for Improving Hydrothermal Stability of Ordered Mesoporous Materials and Synthesis of Mesoporous Zeolites (497 KB). Contents: Mesoporous Silicas; Si-Containing Mesoporous Inorganic Frameworks; Mesoporous Zeolites; Mesoporous Organosilicas; Non-siliceous Inorganic Nanomaterials; Porous Polymers and Polymer/Inorganic Nanocomposites; Mesoporous Carbons; Nanoparticles Assembly; Adsorption on Nanostructured Materials; Nanostructured Catalysts; Catalytic Applications of Nanoporous Materials; Environmental Applications of Nanoporous Materials; Bio-related Applications of Mesoporous Materials. Readership: Graduate students, academics and researchers in the field of nanoporous materials."
This proceedings volume contains selected and peer-reviewed original oral and poster contributions to be presented at the 5th International Symposium on Nanoporous Materials, Vancouver, Canada, May 25-28, 2008. It presents recent scientific advances in the area of nanoporous materials, especially those with ordered pores of sizes between 1 and 50 nm, their synthesis, characterization and applications in adsorption, catalysis, bio-related processes, environmental cleanup and nanotechnology. A unique feature of this volume is the wide variety of nanoporous materials covered, ranging from ordered silica nanostructures, silicas with incorporated organic and inorganic species, ordered nanoporous carbons and polymers, metal organic frameworks, nanostructured catalysts to nanoporous films, membranes and monoliths. This proceedings volume reflects the current trends and advances in the field of nanomaterials, which will certainly continue to attract the attention of materials scientists around the globe. It will therefore be a valuable reference for materials scientists, chemists and physicists working in academia, national and industrial laboratories.
Nanoporous materials consist of a regular organic or inorganic framework supporting a porous structure. Nanoporous materials are separated into three subtypes: microporous materials, mesoporous materials and macroporous materials. In recent years, nanoporous materials have been recognized as promising candidates for the multifunctional applications such as catalysis, ion-exchange, gas storage low density magnetic storage, etc. In addition, nanoporous materials are also of scientific and technological importance because of their ability to absorb and co-operate with atoms, ions and molecules on their sizeable interior surfaces and pore space. This book proposes and reviews advances being made in the field of nanoporous materials.
This NATO ASI involved teachings and perspectives of the state-of-the-art in experimental and theoretical understandings of transport in nanoporous solids. This workshop brought together the top scientists and engineers in each area to discuss the similarities and differences in each technique and theory. The lectures truly bridge the gaps between these related areas and approaches. The applications in future separations, catalysis, the environment and energy needs are obvious. The solids comprised the newly developing molecular sieves, biological systems and polymeric solids. Transport in single particles, in membranes and in commercial applications were reviewed and analyzed, placing each in context. Techniques such as uptake, Chromatographic, Frequency Response, NMR, Neutron Scattering and Infrared spectroscopies are discussed for mixtures as well as for single components. Theoretical approaches such as Density Functional Theory, Statistical Mechanics, Molecular Dynamics and Maxwell-Stefan Theory are employed to analyze the diffusional transport in confined environments, spanning from sub-nanometers to centimetre scales. In all cases the theories are related to the experiments. These lectures present a uniquq opportunity to learn the various theoretical and experimental approaches to analyze and understand transport in nanoporous materials.
Having successfully replaced elements used in traditional, pollution-prone, energy-consuming separation processes, nanoporous materials play an important role in chemical processing. Although their unique structural or surface physicochemical properties can, to an extent, be tailored to meet specific process-related requirements, the task of charac
This series of books, which is published at the rate of about one per year, addresses fundamental problems in materials science. The contents cover a broad range of topics from small clusters of atoms to engineering materials and involve chemistry, physics, and engineering, with length scales ranging from Ångstromsup to millimeters. The emphasis is on basic science rather than on applications. Each book focuses on a single area ofcurrent interest and brings together leading experts to give an up-to-date discussion of their work and the work ofothers. Each article contains enough references that the interested reader can accesstherelevant literature. Thanks aregiven to the Center forFundamental Materials Research atMichigan State University forsupportingthis series. M.F. Thorpe, Series Editor E-mail: [email protected] EastLansing,Michigan, September, 1995 PREFACE This book records selected papers given at an interdisciplinary Symposium on Access in Nanoporous Materials held in Lansing, Michigan, on June 7-9, 1995. Broad interest in the synthesis of ordered materials with pore sizes in the 1.0-10 nm range was clearly manifested in the 64 invited and contributed papers presented by workers in the formal fields of chemistry, physics, and engineering. The intent of the symposium was to bring together a small number ofleading researchers within complementary disciplines to share in the diversity of approaches to nanoporous materials synthesis and characterization.
Offering a materials science point of view, the author covers the theory and practice of adsorption and diffusion applied to gases in microporous crystalline, mesoporous ordered, and micro/mesoporous amorphous materials. Examples used include microporous and mesoporous molecular sieves, amorphous silica, and alumina and active carbons, akaganeites, prussian blue analogues, metal organic frameworks and covalent organic frameworks. The use of single component adsorption, diffusion in the characterization of the adsorbent surface, pore volume, pore size distribution, and the study of the parameters characterizing single component transport processes in porous materials are detailed.