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Global experts provide an authoritative source of information on the use of electrochemical fuel cells, and in particular discuss the use of nanomaterials to enhance the performance of existing energy systems. The book covers the state of the art in the design, preparation, and engineering of nanoscale functional materials as effective catalysts for fuel cell chemistry, highlights recent progress in electrocatalysis at both fuel cell anode and cathode, and details perspectives and challenges in future research.
Nanotechnology in Fuel Cells focuses on the use of nanotechnology in macroscopic and nanosized fuel cells to enhance their performance and lifespan. The book covers the fundamental design concepts and promising applications of nanotechnology-enhanced fuel cells and their advantages over traditional fuel cells in portable devices, including longer shelf life and lower cost. In the case of proton-exchange membrane fuel cells (PEMFCs), nano-membranes could provide 100 times higher conductivity of hydrogen ions in low humidity conditions than traditional membranes. For hydrogen fuel cell, nanocatalysts (Pt hybrid nanoparticles) could provide 12 times higher catalytic activity. This is an important reference source for materials scientists and engineers who are looking to understand how nanotechnology is being used to create more efficient macro- and nanosized fuel cells. - Outlines how fuel cells can be nanoengineered to enhance their performance and lifespan - Covers a variety of fuel cell types, including proton-exchange membrane fuel cells and hydrogen-based fuel cells - Assesses the major challenges of nanoengineering fuel cells at an industrial scale
Nanomaterials for Direct Alcohol Fuel Cells explains nanomaterials and nanocomposites as well as the characterization, manufacturing, and design of alcohol fuel cell applications. The advantages of direct alcohol fuel cells (DAFCs) are significant for reliable and long-lasting portable power sources used in devices such as mobile phones and computers. Even though substantial improvements have been made in DAFC systems over the last decade, more effort is needed to commercialize DAFCs by producing durable, low-cost, and smaller-sized devices. Nanomaterials have an important role to play in achieving this aim. The use of nanotechnology in DAFCs is vital due to their role in the synthesis of nanocatalysts within the manufacturing process. Lately, nanocatalysts containing carbon such as graphene, carbon nanotubes, and carbon nanocoils have also attracted much attention. When compared to traditional materials, carbon-based materials have unique advantages, such as high corrosion resistance, better electrical conductivity, and less catalyst poisoning. This book also covers different aspects of nanocomposites fabrication, including their preparation, design, and characterization techniques for their fuel cell applications. This book is an important reference source for materials scientists, engineers, energy scientists, and electrochemists who are seeking to improve their understanding of how nanomaterials are being used to enhance the efficiency and lower the cost of DAFCs. Shows how nanomaterials are being used for the design and manufacture of DAFCs Explores how nanotechnology is being used to enhance the synthesis and catalysis processes to create the next generation of fuel cells Assesses the major challenges of producing nanomaterial-based DAFCs on an industrial scale
This book is a comprehensive, theoretical, practical, and thorough guide to XAFS spectroscopy. The book addresses XAFS fundamentals such as experiments, theory and data analysis, advanced XAFS methods such as operando XAFS, time-resolved XAFS, spatially resolved XAFS, total-reflection XAFS, high energy resolution XAFS, and practical applications to a variety of catalysts, nanomaterials and surfaces. This book is accessible to a broad audience in academia and industry, and will be a useful guide for researchers entering the subject and graduate students in a wide variety of disciplines.
Provides a comprehensive introduction to the field of nanocarbon electrochemistry The discoveries of new carbon materials such as fullerene, graphene, carbon nanotubes, graphene nanoribbon, carbon dots, and graphdiyne have triggered numerous research advances in the field of electrochemistry. This book brings together up-to-date accounts of the recent progress, developments, and achievements in the electrochemistry of different carbon materials, focusing on their unique properties and various applications. Nanocarbon Electrochemistry begins by looking at the studies of heterogeneous electron transfer at various carbon electrodes when redox-active molecules are reversibly and specifically adsorbed on the carbon electrode surface. It then covers electrochemical energy storage applications of various carbon materials, particularly the construction and performance of supercapacitors and batteries by use of graphene and related materials. Next, it concentrates on electrochemical energy conversion applications where electrocatalysis at 0D, 1D, 2D, and 3D carbon materials nanocarbon materials is highlighted. The book finishes with an examination of the contents of electrogenerated chemiluminescence and photoelectrochemical pollutant degradation by use of diamond and related carbon materials. Covers the fundamental properties of different carbon materials and their applications across a wide range of areas Provides sufficient background regarding different applications, which contributes to the understanding of specialists and non-specialists Examines nanoelectrochemistry of adsorption-coupled electron transfer at carbon electrodes; graphene and graphene related materials; diamond electrodes for the electrogenerated chemiluminescence; and more Features contributions from an international team of distinguished researchers Nanocarbon Electrochemistry is an ideal book for students, researchers, and industrial partners working on many diverse fields of electrochemistry, whether they already make frequent use of carbon electrodes in one form of another or are looking at electrodes for new applications.
Metal Oxide-Based Nanostructured Electrocatalysts for Fuel Cells, Electrolyzers, and Metal-Air Batteries is a comprehensive book summarizing the recent overview of these new materials developed to date. The book is motivated by research that focuses on the reduction of noble metal content in catalysts to reduce the cost associated to the entire system. Metal oxides gained significant interest in heterogeneous catalysis for basic research and industrial deployment. Metal Oxide-Based Nanostructured Electrocatalysts for Fuel Cells, Electrolyzers, and Metal-Air Batteries puts these opportunities and challenges into a broad context, discusses the recent researches and technological advances, and finally provides several pathways and guidelines that could inspire the development of ground-breaking electrochemical devices for energy production or storage. Its primary focus is how materials development is an important approach to produce electricity for key applications such as automotive and industrial. The book is appropriate for those working in academia and R&D in the disciplines of materials science, chemistry, electrochemistry, and engineering. - Includes key aspects of materials design to improve the performance of electrode materials for energy conversion and storage device applications - Reviews emerging metal oxide materials for hydrogen production, hydrogen oxidation, oxygen reduction and oxygen evolution - Discusses metal oxide electrocatalysts for water-splitting, metal-air batteries, electrolyzer, and fuel cell applications
Nanocatalysis is a topical area of research that has huge potential. It attempts to merge the advantages of heterogeneous and homogeneous catalysis. The collection of articles in this book treats the topics of specificity, activity, reusability, and stability of the catalyst and presents a compilation of articles that focuses on different aspects of these issues.
PEM Fuel Cells: Fundamentals, Advanced Technologies, and Practical Application provides a comprehensive introduction to the principles of PEM fuel cell, their working condition and application, and the latest breakthroughs and challenges for fuel cell technology. Each chapter follows a systematic and consistent structure with clear illustrations and diagrams for easy understanding. The opening chapters address the basics of PEM technology; stacking and membrane electrode assembly for PEM, degradation mechanisms of electrocatalysts, platinum dissolution and redeposition, carbon-support corrosion, bipolar plates and carbon nanotubes for the PEM, and gas diffusion layers. Thermodynamics, operating conditions, and electrochemistry address fuel cell efficiency and the fundamental workings of the PEM. Instruments and techniques for testing and diagnosis are then presented alongside practical tests. Dedicated chapters explain how to use MATLAB and COMSOL to conduct simulation and modeling of catalysts, gas diffusion layers, assembly, and membrane. Degradation and failure modes are discussed in detail, providing strategies and protocols for mitigation. High-temperature PEMs are also examined, as are the fundamentals of EIS. Critically, the environmental impact and life cycle of the production and storage of hydrogen are addressed, as are the risk and durability issues of PEMFC technology. Dedicated chapters are presented on the economics and commercialization of PEMFCs, including discussion of installation costs, initial capital costs, and the regulatory frameworks; apart from this, there is a separate chapter on their application to the automotive industry. Finally, future challenges and applications are considered. PEM Fuel Cells: Fundamentals, Advanced Technologies, and Practical Application provides an in-depth and comprehensive reference on every aspect of PEM fuel cells fundamentals, ideal for researchers, graduates, and students. - Presents the fundamentals of PEM fuel cell technology, electrolytes, membranes, modeling, conductivity, recent trends, and future applications - Addresses commercialization, public policy, and the environmental impacts of PEMFC in dedicated chapters - Presents state-of-the-art PEMFC research alongside the underlying concepts
Nanotechnology has the potential to play an important role in increasing the sustainability of a wide range of industrial sectors. Nanomaterials could contribute to more sustainable manufacturing through cleaner, less wasteful production processes and can substitute conventional materials, leading to savings in raw materials and energy. Nanotechnology for Sustainable Manufacturing discusses recent progress in the areas of energy and materials efficiency related to resource savings and conservation of raw materials, which are drivers for the application of nanotechnology in the industrial setting. Written by leading experts from Europe, North America, Asia, and Australia, the book provides an innovative perspective by establishing connections between the subject areas associated with nanotechnology and by bridging the academic and industrial research gap. The topics covered include electronics, agrifood, aerospace, pulp and paper manufacturing, batteries, catalysts, solar energy, fuel cells, drinking water, and construction materials. The chapters offer insights into the diverse industries that are currently or likely to be impacted by developments in nanotechnology and nanomaterials. They cover applications such as nanotechnology for alternative energy generation, improving water quality, and novel uses in agriculture and forest products. The book also addresses the use of life-cycle analysis for assessing the sustainability of nanotechnology-based products and processes.
A fuel cell is an electrochemical device that converts the chemical energy of a reaction (between fuel and oxidant) directly into electricity. Given their efficiency and low emissions, fuel cells provide an important alternative to power produced from fossil fuels. A major challenge in their use is the need for better materials to make fuel cells cost-effective and more durable. This important book reviews developments in materials to fulfil the potential of fuel cells as a major power source.After introductory chapters on the key issues in fuel cell materials research, the book reviews the major types of fuel cell. These include alkaline fuel cells, polymer electrolyte fuel cells, direct methanol fuel cells, phosphoric acid fuel cells, molten carbonate fuel cells, solid oxide fuel cells and regenerative fuel cells. The book concludes with reviews of novel fuel cell materials, ways of analysing performance and issues affecting recyclability and life cycle assessment.With its distinguished editor and international team of contributors, Materials for fuel cells is a valuable reference for all those researching, manufacturing and using fuel cells in such areas as automotive engineering. - Examines the key issues in fuel cell materials research - Reviews the major types of fuel cells such as direct methanol and regenerative fuel cells - Further chapters explore ways of analysing performance and issues affecting recyclability and life cycle assessment