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The mechanical behavior of graphene oxide is length scale dependent: orders of magnitude different between the bulk forms and monolayer counterparts. Understanding the underlying mechanisms plays a significant role in their versatile application. A systematic multiscale mechanical study from monolayer to multilayer, including the interactions between layers of GO, can provide fundamental support for material engineering. In this thesis, an experimental coupled with simulation approach was used to study the multiscale mechanics of graphene oxide (GO) and the methods developed for GO study are proved to be applicable also to mechanical study of graphene based composites. GO is a layered nanomaterial comprised of hierarchical units whose characteristic dimension lies between monolayer GO (0.7 nm â 1.2 nm) and bulk GO papers (1 um). Mechanical behaviors of monolayer GO and GO nanosheets (10 nm- 100 nm) were comprehensively studied this work. Monolayer GO was measured to have an average strength of 24.7 GPa,, orders of magnitude higher than previously reported values for GO paper and approximately 50% of the 2D intrinsic strength of pristine graphene. The huge discrepancy between the strength of monolayer GO and that of bulk GO paper motivated the study of GO at the intermediate length scale (GO nanosheets). Experimental results showed that GO nanosheets possess high strength in the gigapascal range. Molecular Dynamic simulations showed that the transition in the failure behavior from interplanar fracture to intraplanar fracture was responsible for the huge strength discrepancy between nanometer scale GO and bulk GO papers. Additionally, the interfacial shear strength between GO layers was found to be a key contributing factor to the distinct mechanical behavior among hierarchical units of GO. The understanding of the multiscale mechanics of GO is transferrable in heterogeneous layered nanomaterials, such as graphene-metal oxide based anode materials in Li-ion batteries. The novel methods developed in this work to study GO multilayered structures were also applied to study the mechanics of graphene-TiO2 composites. It was found that a critical thickness range of TiO2 deposition on graphene is required for the observed stiffness enhancement effect of graphene to influence the mechanical behavior of the composite.
A monograph that locates graphene within the carbon chemistry alternatives available to materials engineers and explains how it is incorporated into polymer-matrix, as well as ceramic - and metal-matrix composite materials. It also investigates emerging uses of graphene in films, coatings and colloidal suspensions.
The fourth volume in a series of handbooks on graphene research and applications The Handbook of Graphene, Volume 4: Composites looks at composite materials exclusively. Topics covered include graphene composites and graphene-reinforced advanced composite materials. The following graphene-based subjects are discussed: ceramic composites; composite nanostructures; composites with shape memory effect; and scroll structures. Chapters also address: the fabrication and properties of copper graphene composites; graphene metal oxide composite as an anode material in li-ion batteries; supramolecular graphene-based systems for drug delivery; and other graphene-related areas of interest to scientists and researchers.
Innovations in Graphene-Based Polymer Composites reviews recent developments in this important field of research. The book's chapters focus on processing methods, functionalization, mechanical, electrical and thermal properties, applications and life cycle assessment. Leading researchers from industry, academia and government research institutions from across the globe have contributed to the book, making it a valuable reference resource for materials scientists, academic researchers and industrial engineers working on recent developments in the area of graphene-based materials, graphene-based polymer blends and composites. Readers will gain insights into what has been explored to-date, along with associated benefits and challenges for the future. Presents a strong emphasis on synthesis methods, functionalization, processing and properties Includes chapters on characterization, electrical conductivity and modeling and simulation Provides recent advances in applications, including drawbacks and future scope
Explore the Practical Applications and Promising Developments of GrapheneThe Graphene Science Handbook is a six-volume set that describes graphene's special structural, electrical, and chemical properties. The book considers how these properties can be used in different applications (including the development of batteries, fuel cells, photovoltaic
Composite materials have aroused a great interest over the last few decades, as proven by the huge number of scientific papers and industrial progress. The increase in the use of composite structures in different engineering practices justify the present international meeting where researches from every part of the globe can share and discuss the recent advancements regarding the use of structural components within advanced applications such as buckling, vibrations, repair, reinforcements, concrete, composite laminated materials and more recent metamaterials. Studies about composite structures are truly multidisciplinary and the given contributions can help other researches and professional engineers in their own field. This Conference is suitable as a reference for engineers and scientists working in the professional field, in the industry and the academia and it gives the possibility to share recent advancements in different engineering practices to the outside world. This book aims to collect selected plenary and key-note lectures of this International Conference. For this reason, the establishment of this 20th edition of International Conference on Composite Structures has appeared appropriate to continue what has been begun during the previous editions. ICCS wants to be an occasion for many researchers from each part of the globe to meet and discuss about the recent advancements regarding the use of composite structures, sandwich panels, nanotechnology, bio-composites, delamination and fracture, experimental methods, manufacturing and other countless topics that have filled many sessions during this conference. As a proof of this event, which has taken place in Paris (France), selected plenary and key-note lectures have been collected in the present book.
Graphene is the strongest material ever studied and can be an efficient substitute for silicon. This six-volume handbook focuses on fabrication methods, nanostructure and atomic arrangement, electrical and optical properties, mechanical and chemical properties, size-dependent properties, and applications and industrialization. There is no other major reference work of this scope on the topic of graphene, which is one of the most researched materials of the twenty-first century. The set includes contributions from top researchers in the field and a foreword written by two Nobel laureates in physics. Volumes in the set: K20503 Graphene Science Handbook: Mechanical and Chemical Properties (ISBN: 9781466591233) K20505 Graphene Science Handbook: Fabrication Methods (ISBN: 9781466591271) K20507 Graphene Science Handbook: Electrical and Optical Properties (ISBN: 9781466591318) K20508 Graphene Science Handbook: Applications and Industrialization (ISBN: 9781466591332) K20509 Graphene Science Handbook: Size-Dependent Properties (ISBN: 9781466591356) K20510 Graphene Science Handbook: Nanostructure and Atomic Arrangement (ISBN: 9781466591370)
The eighth volume in a series of handbooks on graphene research and applications The Handbook of Graphene, Volume 8: Technology and Innovations discusses the role of graphene-based applications in technological advancements. Topics include graphene materials used in circuit board repairs; RFID antenna and sensor fabrication; and wearable healthcare electronics. Chapters present detailed information on: modeling methods used in graphene research; applications of graphene-on-silicon photonic integrated circuits; the development of graphene for engineering applications; and other graphene subjects of interest to scientists, chemists and physicists.
Tribology of Graphene: Simulation Methods, Preparation Methods, and Their Applications provides an exhaustive reference guide on the tribology of graphene-based materials. The book begins with a discussion on the selection of the proper graphene-based material and then segues into how to choose a deposition method, how to control of its structure and properties, and the most effective working conditions and applications. The latest developments in theoretical simulations of graphene friction, preparation methods, and effective applications are all reviewed, as are the ways various graphene coatings can be successfully employed to decrease friction and wear in nano-, micro- and macro-mechanical applications. - Synthesizes the broad current research in tribological applications of graphene all in one place - Covers theoretical simulations and preparation methods, including insights on how to put them into practice, allowing for quicker and more effective selection of graphene-based material - Provides a broader perspective by discussing both graphene-based composites and additives