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Multiphase Flow in Polymer Processing focuses on dispersed and stratified multiphase flow in polymer processing. This book explores the rheological behavior of multiphase (or multicomponent) polymeric systems as they are involved in various fabrication operations. It also outlines the importance of the morphological states of multiphase polymeric systems to explain the systems, rheological behavior in the fluid state, and mechanical behavior in the solid state. This monograph consists of eight chapters divided into two parts. After discussing dispersed and stratified multiphase flow in polymer processing, it introduces the reader to the fundamentals of rheology. The following chapters focus on the rheological behavior of particulate-filled polymeric systems and heterogeneous polymeric systems; the phenomenon of droplet breakup in dispersed flow; and gas-charged polymeric systems. The role of the discrete phase (that is, solid particles, liquid droplets, gas bubbles) in determining the bulk rheological properties of the multiphase system is highlighted, along with some representative polymer processing operations (namely, fiber spinning and injection molding) of the multiphase (or multicomponent) polymeric systems. Coextrusion in cylindrical, rectangular, and annular dies is also considered. The final chapter is devoted to the phenomenon of interfacial instability in coextrusion. This text will be a useful resource for chemists, chemical engineers, and those in the polymer processing industry.
Crystallization in Multiphase Polymer Systems is the first book that explains in depth the crystallization behavior of multiphase polymer systems. Polymeric structures are more complex in nature than other material structures due to their significant structural disorder. Most of the polymers used today are semicrystalline, and the subject of crystallization is still one of the major issues relating to the performance of semicrystalline polymers in the modern polymer industry. The study of the crystallization processes, crystalline morphologies and other phase transitions is of great significance for the understanding the structure-property relationships of these systems. Crystallization in block copolymers, miscible blends, immiscible blends, and polymer composites and nanocomposites is thoroughly discussed and represents the core coverage of this book. The book critically analyzes the kinetics of nucleation and growth process of the crystalline phases in multi-component polymer systems in different length scales, from macro to nanoscale. Various experimental techniques used for the characterization of polymer crystallization process are discussed. Written by experts in the field of polymer crystallization, this book is a unique source and enables professionals and students to understand crystallization behavior in multiphase polymer systems such as block copolymers, polymer blends, composites and nanocomposites. - Covers crystallization of multiphase polymer systems, including copolymers, blends and nanocomposites - Features comprehensive, detailed information about the basic research, practical applications and new developments for these polymeric materials - Analyzes the kinetics of nucleation and growth process of the crystalline phases in multi-component polymer systems in different length scales, from macro to nanoscale
Thoroughly revised edition of the classic text on polymer processing The Second Edition brings the classic text on polymer processing thoroughly up to date with the latest fundamental developments in polymer processing, while retaining the critically acclaimed approach of the First Edition. Readers are provided with the complete panorama of polymer processing, starting with fundamental concepts through the latest current industry practices and future directions. All the chapters have been revised and updated, and four new chapters have been added to introduce the latest developments. Readers familiar with the First Edition will discover a host of new material, including: * Blend and alloy microstructuring * Twin screw-based melting and chaotic mixing mechanisms * Reactive processing * Devolatilization--theory, mechanisms, and industrial practice * Compounding--theory and industrial practice * The increasingly important role of computational fluid mechanics * A systematic approach to machine configuration design The Second Edition expands on the unique approach that distinguishes it from comparative texts. Rather than focus on specific processing methods, the authors assert that polymers have a similar experience in any processing machine and that these experiences can be described by a set of elementary processing steps that prepare the polymer for any of the shaping methods. On the other hand, the authors do emphasize the unique features of particular polymer processing methods and machines, including the particular elementary step and shaping mechanisms and geometrical solutions. Replete with problem sets and a solutions manual for instructors, this textbook is recommended for undergraduate and graduate students in chemical engineering and polymer and materials engineering and science. It will also prove invaluable for industry professionals as a fundamental polymer processing analysis and synthesis reference.
Fluid Dynamics is one of the most important topics of applied mathematics and physics. Together with complex flows and turbulence, multiphase flows remains one of the most challenging areas of computational mechanics, and even seemingly simple problems remain unsolved to date. Multiphase flows are found in all areas of technology, at all length scales and flow regimes. The fluids involved can be compressible or incompressible, linear or nonlinear. Because of the complexity of the problem, it is often essential to utilize advanced computational and experimental methods to solve the complex equations that describe them. Challenges in these simulations include nonlinear fluids, treating drop breakup and coalescence, characterizing phase structures, and many others.This volume brings together work presented at the Fourth International Conference on Computational and Experimental Methods in Multiphase and Complex Flows. Featured topics include: Suspensions; Bubble and Drop Dynamics; Flow in Porous Media; Interfaces; Turbulent Flow; Injectors and Nozzles; Particle Image Velocimetry; Macroscale Constitutive Models; Large Eddy Simulation; Finite Volumes; Interface Tracking Methods; Biological Flows; Environmental Multiphase Flow; Phase Changes and Stochastic Modelling.
Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued. The current list of Specialist Periodical Reports can be seen on the inside flap of this volume.
Polymerie materials have been replacing other conventional materials like metals, glass and wood in a number of applications. The use of various types of fillers incorporated into the polymer has become quite common as a means of reducing cost and to impart certain desirable mechanieal, thermal, electrieal and magnetic properties to the polymers. Oue to the energy crisis and high priees of petrochemieals, there has been a greater demand to use more and more fillers to cheapen the polymerie materials while maintaining and/or improving their properties. The advantages that filled polymer systems have to offer are normally offset to some extent by the increased complexity in the rheological behavior that is introduced by the inclusion of the fillers. Usually when the use of fillers is considered, a compromise has to be made between the improved mechanieal properties in the solid state, the increased difficulty in melt processing, the problem of achieving uniform dispersion of the filler in the polymer matrix and the economics of the process due to the added step of compounding. It has been recognized that addition of filler to the polymer brings a change in processing behavior. The presence of the filler increases the melt viscosity leading to increases in the pressure drop across the die but gives rise to less die swell due to decreased melt elasticity.
Biodegradable Polymer Blends and Composites from Renewable Resources provides a comprehensive, current overview of biopolymeric blends and composites and their applications in various industries. The book is organized according to the type of blend or composite. For each topic, the relationship between the structure of the blends/composites and their respective properties is explored, with particular focus on interface, compatibility, mechanical, and thermal properties. Real-life applications and potential markets are discussed. This is a premier reference for graduate students and researchers in polymer science, chemical and bio engineering, and materials science.
Discover the cutting-edge in multiphase flows used in the process industries In Multiphase Flows for Process Industries: Fundamentals and Applications, a team of accomplished chemical engineers delivers an insightful and complete treatment of the state-of-the-art in commonly encountered multiphase flows in the process industries. After discussing the theoretical background, experimental methods, and computational methods applicable to multiphase flows, the authors explore specific examples from the process industries. The book covers a wide range of multiphase flows, including gas-solid fluidized beds and flows with phase change. It also provides direction on how to use current advances in the field to realize efficient and optimized processes. Filling the gap between theory and practice, this unique reference also includes: A thorough introduction to multiphase flows and the process industry Practical discussions of flow regimes, lower order models and correlations, and the chronological development of mathematical models for multiphase flows Comprehensive explorations of experimental methods for characterizing multiphase flows, including flow imaging and visualization In-depth examinations of computational models for simulating multiphase flows Perfect for chemical and process engineers, Multiphase Flows for Process Industries: Fundamentals and Applications is required reading for graduate and doctoral students in the engineering sciences, as well as professionals in the chemical industry.
FROM THE PREFACE Almost all polymeric systems are subjected to a flow field at least once along the route between preparation and application. . . . There is also an increased interest in predictive models on phase behavior and suitable techniques for characterizing the structure of these systems when subjected to flow. Multiphase polymeric systems are particularly susceptible to flow, which may cause orientation of species, morphological changes, and phase transitions. All these events may, in turn, affect the end product properties, such as permeability, electrical conductivity, [and] mechanical properties. In processing, escalating needs have evolved for optimization and development of novel and more uniform product properties and increased productivity. In order to arrive at an understanding of processing polymeric systems under elastic flow conditions, it is convenient to analyze the basic physical mechanisms under conditions that enable development of predictive models in conjunction with controlled experimentation. . . . In recent years, the science of rheo-physics has evolved and now involves both advanced theories and experimental techniques. Rheo-physics means the rheological, morphological, and thermodynamic behavior of structured polymer systems during flow. . . . In this monograph, the rheo-optical techniques are . . . emphasized. The book gives an introduction to rheo-physics, including fundamentals of theories, and a representative selection of applications of rheo-optical techniques for analyzing multiphase systems. The chapters contain both practical advice for the new experimenter . . . as well as review material for the experienced scientist.
At the VIIth International Congress on Rheology, which was held in Goteborg in 1976, Proceedings were for the first time printed in advance and distributed to all participants at the time of the Congress. Although of course we Italians would be foolish to even try to emulate our Swedish friends as far as efficiency of organization is concerned, we decided at the very beginning that, as far as the Proceedings were concerned, the VIIIth International Congress on Rheology in Naples would follow the standards of time liness set by the Swedish Society of Rheology. This book is the result we have obtained. We wish to acknowledge the cooperation of Plenum Press in producing it within the very tight time schedule available. Every four years, the International Congress on Rheology represents the focal point where all rheologists meet, and the state of the art is brought up to date for everybody interested; the Proceedings represent the written record of these milestones of scientific progress in rheology. We have tried to make use of the traditions of having invited lectures, and of leaving to the organizing committee the freedom to choose the lecturers as they see fit, in order to collect a group of invited lectures which gives as broad as possible a landscape of the state of the art in every relevant area of rheology. The seventeen invited lectures are collected in the first volume of the proceedings.