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Filling the gap for a reference dedicated to the characterization of polymer blends and their micro and nano morphologies, this book provides comprehensive, systematic coverage in a one-stop, two-volume resource for all those working in the field. Leading researchers from industry and academia, as well as from government and private research institutions around the world summarize recent technical advances in chapters devoted to their individual contributions. In so doing, they examine a wide range of modern characterization techniques, from microscopy and spectroscopy to diffraction, thermal analysis, rheology, mechanical measurements and chromatography. These methods are compared with each other to assist in determining the best solution for both fundamental and applied problems, paying attention to the characterization of nanoscale miscibility and interfaces, both in blends involving copolymers and in immiscible blends. The thermodynamics, miscibility, phase separation, morphology and interfaces in polymer blends are also discussed in light of new insights involving the nanoscopic scale. Finally, the authors detail the processing-morphology-property relationships of polymer blends, as well as the influence of processing on the generation of micro and nano morphologies, and the dependence of these morphologies on the properties of blends. Hot topics such as compatibilization through nanoparticles, miscibility of new biopolymers and nanoscale investigations of interfaces in blends are also addressed. With its application-oriented approach, handpicked selection of topics and expert contributors, this is an outstanding survey for anyone involved in the field of polymer blends for advanced technologies.
Block copolymers represent an important class of multi-phase material, which have received very widespread attention, particularly since their successful commercial development in the mid-1960s. Much of the interest in these polymers has arisen because of their rather remarkable micro phase morphology and, hence, they have been the subject of extensive microstructural examination. In many respects, the quest for a comprehensive interpretation of their structure, both theoretically and experimentally, has not been generally matched by a corresponding enthusiasm for developing structure/property relationships in the context of their commercial application. Indeed, it has been left largely to the industrial companies involved in the development and utilization of these materials to fulfil this latter role. While it is generally disappointing that a much greater synergism does not exist between science and technology, it is especially sad in the case of block copolymers. Thus these materials offer an almost unique opportunity for the application of fundamental structural and property data to the interpretation of the properties of generally processed artefacts. Accordingly, in this book, the editor has drawn together an eminent group of research workers, with the specific intention of highlighting some of those aspects of the science and technology of block copolymers that are potentially important if further advances are to be made either in material formulation or utilization. For example, special consideration is given to the relationship between the flow properties of block copo lymers and their microstructure.
Elastomer Blends and Composites: Principles, Characterization, Advances, and Applications presents the latest developments in natural rubber and synthetic rubber-based blends and nanocomposites, with a focus on current trends, future directions and state-of-the-art applications. The book introduces the fundamentals of natural rubber and synthetic rubbers, outlining synthesis, structure, properties, challenges and potential applications. This is followed by detailed coverage of compounding and formulations, manufacturing methods, and preparation of elastomer-based blends, composites, and nanocomposites. The next section of the book focuses on properties and characterization, examining elasticity, spectroscopy, barrier properties, and rheological, morphological, mechanical, thermal, and viscoelastic behavior, and more. This is a highly valuable resource for researchers and advanced students in rubber (or elastomer) science, polymer blends, composites, polymer science, and materials science and engineering, as well as engineers, technologists, and scientists working with rubber-based materials for advanced applications. - Guides the reader through the manufacturing, properties, characterization and latest innovations in elastomer blends and composites - Addresses aging and degradation behavior, lifecycle analysis, and recycling of rubber-based materials - Explores novel applications of rubber blends and composites in areas such as automotive, aerospace, medicine and engineering
With their broad range of properties, polymer blends are widely used in adhesion, colloidal stability, the design of composite and biocompatible materials, and other areas. As the science and technology of polymer blends advances, an increasing number of polymer blend systems and applications continue to be developed. Functional Polymer Blends: Syn
This book explores the recent advances in the field of shape memory polymers, whose ease of manufacturing and wide range of potential applications have spurred interest in the field. The book presents details about the synthesis, processing, characterization, and applications of shape memory polymers, their blends and composites. It provides a correlation of physical properties of shape memory polymers with macro, micro and nano structures. The contents of this book will be of interest to researchers across academia and industry.
Block copolymers represent an important class of multi-phase material, which have received very widespread attention, particularly since their successful commercial development in the mid-1960s. Much of the interest in these polymers has arisen because of their rather remarkable micro phase morphology and, hence, they have been the subject of extensive microstructural examination. In many respects, the quest for a comprehensive interpretation of their structure, both theoretically and experimentally, has not been generally matched by a corresponding enthusiasm for developing structure/property relationships in the context of their commercial application. Indeed, it has been left largely to the industrial companies involved in the development and utilization of these materials to fulfil this latter role. While it is generally disappointing that a much greater synergism does not exist between science and technology, it is especially sad in the case of block copolymers. Thus these materials offer an almost unique opportunity for the application of fundamental structural and property data to the interpretation of the properties of generally processed artefacts. Accordingly, in this book, the editor has drawn together an eminent group of research workers, with the specific intention of highlighting some of those aspects of the science and technology of block copolymers that are potentially important if further advances are to be made either in material formulation or utilization. For example, special consideration is given to the relationship between the flow properties of block copo lymers and their microstructure.
Brydson's Plastics Materials, Eighth Edition, provides a comprehensive overview of the commercially available plastics materials that bridge the gap between theory and practice. The book enables scientists to understand the commercial implications of their work and provides engineers with essential theory. Since the previous edition, many developments have taken place in plastics materials, such as the growth in the commercial use of sustainable bioplastics, so this book brings the user fully up-to-date with the latest materials, references, units, and figures that have all been thoroughly updated. The book remains the authoritiative resource for engineers, suppliers, researchers, materials scientists, and academics in the field of polymers, including current best practice, processing, and material selection information and health and safety guidance, along with discussions of sustainability and the commercial importance of various plastics and additives, including nanofillers and graphene as property modifiers. With a 50 year history as the principal reference in the field of plastics material, and fully updated by an expert team of polymer scientists and engineers, this book is essential reading for researchers and practitioners in this field. - Presents a one-stop-shop for easily accessible information on plastics materials, now updated to include the latest biopolymers, high temperature engineering plastics, thermoplastic elastomers, and more - Includes thoroughly revised and reorganised material as contributed by an expert team who make the book relevant to all plastics engineers, materials scientists, and students of polymers - Includes the latest guidance on health, safety, and sustainability, including materials safety data sheets, local regulations, and a discussion of recycling issues