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This book provides a comprehensive account of the modern theory for the dynamical properties of polymer solutions. The theory has undergone dramatic evolution over the last two decades due to the introduction of new methods and concepts that have extended the frontier of theory from dilute solutions in which polymers move independently to concentrated solutions where many polymers converge. Among the properties examined are viscoelasticity, diffusion, dynamic light scattering, and electric birefringence. Nonlinear viscoelasticity is discussed in detail on the basis of molecular dynamical models. The book bridges the gap between classical theory and new developments, creating a consistent picture of polymer solution dynamics over the entire concentration range.
Schäfer gives a concise overview of the static equilibrium properties of polymer solutions. In the first part diagrammatic perturbation theory is derived from scratch. The second part illustrates the basic ideas of the renormalization group (RG). The crucial role of dilation invariance is stressed. The more efficient method of dimensional regularization and minimal subtractions is worked out in part three. The fourth part contains a unified evaluation of the theory to the one loop level. All the important experimental quantities are discussed in detail, and the results are compared extensively to experiment. Empirical methods of data analysis are critically discussed. The final (fifth) part is devoted to extensions of theory. The first three parts of this book may serve as the basis of a course. Parts four and five are hoped to be useful for detailed quantitative evaluations of experiments.
This book is a concise and clearly written introduction to the modern theory of polymer physics. The book describes basic concepts and methods of investigating the statistical properties of the assembly of chain-like molecules. The topics discussed include scaling theory, concentration fluctuation, gels, and reptation. Both graduate students and researchers in physics, physical chemistry, chemical engineering, and materials science will find this an extremely useful textbook and reference work.
Polymer Solutions: An Introduction to Physical Properties offers a fresh, inclusive approach to teaching the fundamentals of physical polymer science. Students, instructors, and professionals in polymer chemistry, analytical chemistry, organic chemistry, engineering, materials, and textiles will find Iwao Teraoka’s text at once accessible and highly detailed in its treatment of the properties of polymers in the solution phase. Teraoka’s purpose in writing Polymer Solutions is twofold: to familiarize the advanced undergraduate and beginning graduate student with basic concepts, theories, models, and experimental techniques for polymer solutions; and to provide a reference for researchers working in the area of polymer solutions as well as those in charge of chromatographic characterization of polymers. The author’s incorporation of recent advances in the instrumentation of size-exclusion chromatography, the method by which polymers are analyzed, renders the text particularly topical. Subjects discussed include: Real, ideal, Gaussian, semirigid, and branched polymer chains Polymer solutions and thermodynamics Static light scattering of a polymer solution Dynamic light scattering and diffusion of polymers Dynamics of dilute and semidilute polymer solutions Study questions at the end of each chapter not only provide students with the opportunity to test their understanding, but also introduce topics relevant to polymer solutions not included in the main text. With over 250 geometrical model diagrams, Polymer Solutions is a necessary reference for students and for scientists pursuing a broader understanding of polymers.
From the reviews: "...This book is a very useful addition to polymer literature, and it is a pleasure to recommend it to the polymer community." (J.E. Mark, University of Cincinnati, POLYMER NEWS)
Presents the methods used for characterization of polymers. In addition to theory and basic principles, the instrumentation and apparatus necessary for methods used to study the kinetic and thermodynamic interactions of a polymer with its environment are covered in detail. Some of the methods examined include polymer separations and characterization by size exclusion and high performance chromatography, inverse gas chromatography, osmometry, viscometry, ultracentrifugation, light scattering and spectroscopy.
Our brutal century of atom bombs and spaceships can also be called the century ofpolymers. In any case, the broad spreading ofsynthetic polymer materials is one of thesigns of our time. A look at the various aspects of our life is enough to convince us that polymeric materials (textiles, pl- tics, rubbers) are as widely spread and important in our life as are other materials (metals and non-metals) derived from small molecules. Polymers have entered the life of the twentieth century as irreplaceable construction materials. Polymers differ from other substances by the size of their molecules which, appropriately enough, are referred to as macromolecules, since they consist of thousands or tens of thousands of atoms (molecular weight up to -4 6 10 ormore) andhave a macroscopic rectilinear length (upto 10 cm). The atoms ofa macromolecule are firmly held together by valence bonds, fo- ing a single entity. In polymeric substances, the weaker van der Waals forces have an effect on the components of the macromolecules which form the system. The structure of polymeric systems is more complicated than that oflow-molecular solids or liquids, but there are some common features: the atoms within a given macromolecule are ordered, but the centres ofmass of the individual macromolecules and parts of them are distributed randomly. Remarkably, the mechanical response of polymeric systems combines the elasticity of a solid with the fluidity of a liquid.
This book is concerned with the configuration of polymers at the interfacial zone between two other phases or immiscible components. In recent years, developments in technology combined with increased attention from specialists in a wide range of fields have resulted in a considerable increase in our understanding of the behavior of polymers at interfaces. Inevitably these advances have generated a wealth of literature and although there have been numerous reviews, a critical treatment with adequate descriptions of both theory and experiment, including detailed analysis of the two, has been missing. This text hopes to fill this gap, providing a timely and comprehensive account of the field as it stands today. This long needed work will be invaluable to experts as well as newcomers in the broad field of polymers, interfaces and colloids, both in industry and academia. Whilst industrial laboratories involved in this field will find it indispensable, it will be equally important to anyone with an interest in interfacial polymer or colloidal research.
Remarkable progress has been made in the last two decades in the study of concentrated polymer solutions leading to many new concepts, theories, and techniques in the field of polymer science. Any description of the theory of polymer solutions is now insufficient unless both concentrated and dilute solutions are given equal attention. This book reviews recent developments in the study of dilute and concentrated polymer solutions, emphasizing mainly the typical equilibrium and steady-state dynamic properties of linear homopolymers. The author strives to clarify the gap which still remains open between current theories and well-documented experimental results, thereby stimulating further efforts toward a more accurate understanding of polymer solutions.The book contains a collection of typical experimental data and their comparison with current theories, molecular or phenomenological, a summary of recent advances in the physics of concentrated polymer solutions and melts, and an elementary account of the renormalization group theory as applied to dilute solutions. Polymer Solutions should prove invaluable as a reference work for graduate students and specialists in this field.