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The collection of the six contributions of the 7th International Seminar on Modern Synthetic Methods, written by leading experts in their fields, gives an overview on the state of the art, trends, and new accomplishments in solvent effects on chemical transformations, in reactions on surfaces, in the synthesis of oligosaccharides and nucleid acid analogues, and in antibody catalyis. This volume is an invaluable companion to both the active research chemists and the advanced students, fascinated by the world of biologically important compounds and by the creativity in synthetic techniques directed towards their preparation.
Sponsored and organized by the Association of Swiss Chemists
This paperback is the conference documentation of the fifth Seminar on MODERN SYNTHETIC METHODS 1989. It is the aim of these triennial Interlaken-Seminars to provide a proper, concine and "ready for use" acceos to important and rapidly developing areas of synthetic organic chemistry. Usefu.l synthetic methods have to combine economic and ecological aspects. The search for such methods is a continuous scientific challenge. It implies a solid knowledge a~d updated information on current prospects in biochemistry, organic as well as inorganic chemiotry. The main themes of the 1989-Seminar are "Biotransformations in Organic Synthesis", "Enantioselective Catalyois with Metal Complexes" and "Aluminosilicates in Organic Synthesis". These topics have been chosen, since they reflect the enormous progress in experience and understanding of catalysis in organic syntheGis. This book if' the compilation of the contributions provided by the lecturers of the Seminar. The reviews are written by leading experts and describe not only the basic concepts, their application in oynthesis but also contain representative experimental procedures. The purpose of this volume is twofold. It should aid participants and students in followi~g the lectures. The main reason, however, is to serve ao an updated guide for chemists interested in catalyois applied to organic synthesis.
Authored by one of the world?s leading synthetic chemists in the field, this reference presents modern enolate chemistry with an emphasis on metal O-enolates in asymmetric synthesis. While great care is taken to cover novel, successful concepts, such classical methods as the famous Evans enolates are equally highlighted. Throughout the book representative reaction procedures are presented, thus helping readers to find the best solution for their own synthetic problem. Of high interest to synthetic chemists in academia, as well as the pharmaceuticals, agrochemicals and fine chemicals industries.
Rapid advances in chromatographic procedures, spectroscopic techniques and pharmacological assay methods have resulted in the discovery of an increasing number of new and interesting natural products from terrestrial and marine sources. The present volume contains comprehensive reviews on some of the major advances in this field which have taken place in recent years. The reviews include those on: novel metabolites from marine gastropods; the chemistry of marine natural products of the Halenaquinol family; secondary metabolites from Echinoderms and Bryozoans; triterpenoids and aromatic compounds from medicinal plants; chemistry and activity of sesquiterpenes from the genus Lactarius; the chemistry of bile alcohols; antifungal sesquiterpene dialdehydes; annonaceous acetogenins; nargenicin macrolides; and lignans and diarylheptanoids. Tropane alkaloids and phenolides formed by root cultures are also reviewed. Articles on natural Diels-Alder type adducts, the use of computer aided overlay for modelling the substrate binding domain of HLADH, applications of 170 NMR spectroscopy to natural product chemistry and the role of biological raw materials in synthesis are included. Volume 17 provides material of interest to natural products chemists.
The fields of glycochemistry and glycoscience are rich and varied and where much can be learned from Nature. As Nature is not always able to produce carbohydrates in quantities useful for not only in research but also as therapeutic agents, new ways need to be found to optimize the yield. This book presents an overview of the latest developments in the field of carbohydrates, ranging from de-novo approaches via cyclodextrin chemistry to the synthesis of such highly complex glycoconjugates as glycosphingolipids and GPI anchors. The main emphasis remains on the synthetic aspects making the book an excellent source of information for those already involved in carbohydrate chemistry, as well as for those organic chemists who are beginners in this field. Equally of interest to synthetic chemists, as well as medicinal chemists and biochemists.
These two volumes collect forty-four selected papers from the scientific contributions presented at the Third European Workshop on Quantum Systems in Chemistry and Physics, held in Granada (Spain), April 19–22, 1998. Ninety-nine scientists from Bulgaria, Columbia, Cuba, Denmark, Finland, France, Germany, Hungary, Israel, Italy, Mexico, Netherlands, Norway, Poland, Russia, Slovakia, Spain, Sweden, United Ki- dom, Uruguay and Venezuela attended the workshop, discussing the state of the art, new trends, and future evolution of the methods and applications. The workshop took place at the ‘Los Alixares’ Hotel, where 45 lectures were given by prominent members of the scientific community; in addition, 49 posters were presented in two very animated sessions. The success of this workshop is due, without doubt, to the excellent tradition initiated at the previous workshops, organised by Prof. R. McWeeny in San Miniato, Pisa (Italy), 1996, and by Prof. S. Wilson in Oxford (United Kingdom), 1997. These workshops create occasions for meetings and disc- sions on the current state of the art, emerging methods and applications and new trends in this area of science. The three meetings were sponsored and partially supported by the European Union (EU) in the frame of the Cooperation in Science and Technology (COST) chemistry actions.
This annual volume in the series contains 28 checked and edited procedures on stereochemical selection. Eight procedures illustrate the impressive advances in the areas of enantioselective (asymmetric) synthesis, four cover, highly stereospecific syntheses of useful optically active products. Procedures are given for two specific compounds - cyclopropanone ethyl hemiketal and hexafluoroacetone, and the rest treat a wide range of synthetic methodology.
Stereochemistry of Organic Compounds The first fully referenced, comprehensive book on this subject in more than thirty years, Stereochemistry of Organic Compounds contains up-to-date coverage and insightful exposition of all important new concepts, developments, and tools in the rapidly advancing field of stereochemistry, including: * Asymmetric and diastereoselective synthesis * Conformational analysis * Properties of enantiomers and racemates * Separation and analysis of enantiomers and diastereoisomers * Developments in spectroscopy (including NMR), chromatography, and molecular mechanics as applied to stereochemistry * Prostereoisomerism * Conceptual foundations of stereochemistry, including terminology and symmetry concepts * Chiroptical properties Written by the leading authorities in the field, the text includes more than 4,000 references, 1,000 illustrations, and a glossary of stereochemical terms.
Volume 8.