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Filling a gap in the literature and all set to become the standard in this field, this monograph begins with a look at computational viscoelastic fluid mechanics and studies of turbulent flows of dilute polymer solutions. It then goes on discuss simulations of nanocomposites, polymerization kinetics, computational approaches for polymers and modeling polyelectrolytes. Further sections deal with tire optimization, irreversible phenomena in polymers, the hydrodynamics of artificial and bacterial flagella as well as modeling and simulation in liquid crystals. The result is invaluable reading for polymer and theoretical chemists, chemists in industry, materials scientists and plastics technologists.
Polymers are substances made of macromolecules formed by thousands of atoms organized in one (homopolymers) or more (copolymers) groups that repeat themselves to form linear or branched chains, or lattice structures. The concept of polymer traces back to the years 1920's and is one of the most significant ideas of last century. It has given great impulse to indus try but also to fundamental research, including life sciences. Macromolecules are made of sm all molecules known as monomers. The process that brings monomers into polymers is known as polymerization. A fundamental contri bution to the industrial production of polymers, particularly polypropylene and polyethylene, is due to the Nobel prize winners Giulio Natta and Karl Ziegler. The ideas of Ziegler and Natta date back to 1954, and the process has been improved continuously over the years, particularly concerning the design and shaping of the catalysts. Chapter 1 (due to A. Fasano ) is devoted to a review of some results concerning the modelling of the Ziegler- Natta polymerization. The specific ex am pie is the production of polypropilene. The process is extremely complex and all studies with relevant mathematical contents are fairly recent, and several problems are still open.
Exploring the chemistry of synthesis, mechanisms of polymerization, reaction engineering of step-growth and chain-growth polymerization, polymer characterization, thermodynamics and structural, mechanical, thermal and transport behavior of polymers as melts, solutions and solids, Fundamentals of Polymer Engineering, Third Edition covers essential concepts and breakthroughs in reactor design and polymer production and processing. It contains modern theories and real-world examples for a clear understanding of polymer function and development. This fully updated edition addresses new materials, applications, processing techniques, and interpretations of data in the field of polymer science. It discusses the conversion of biomass and coal to plastics and fuels, the use of porous polymers and membranes for water purification, and the use of polymeric membranes in fuel cells. Recent developments are brought to light in detail, and there are new sections on the improvement of barrier properties of polymers, constitutive equations for polymer melts, additive manufacturing and polymer recycling. This textbook is aimed at senior undergraduate students and first year graduate students in polymer engineering and science courses, as well as professional engineers, scientists, and chemists. Examples and problems are included at the end of each chapter for concept reinforcement.
Recent years have witnessed the sheer growth of macromolecular concepts and nanotechnology-based innovations in polymer science. Processing and Characterization of Multicomponent Polymer Systems is a collection of contributions from materials science experts across the globe. The fabrication and characterization of polymeric systems are still important in the study of materials science, and the quality measurements of newly designed polymeric stuffs demand systematic and new characterization protocols. The volume highlights some of the latest innovations and principles of nanostructured polymeric materials and polymer nanocomposites. It is devoted to novel architectures at the nano-level with an emphasis on new synthesis and characterization methods. Organized into several sections, the chapters cover a selection of topics on: Biocomposites and nanocomposites Interpenetrating polymeric networks and nanostructured materials Theoretical protocols for polymers and clusters Special topics in polymer processing and polymer coating. This survey will be an important resource for those involved in the field of polymer materials design for advanced technologies, including scientists, engineers, and budding researchers working in the area of polymer science and nanotechnology.
Advances in Modeling and Simulation in Textile Engineering: New Concepts, Methods, and Applications explains the advanced principles and techniques that can be used to solve textile engineering problems using numerical modeling and simulation. The book draws on innovative research and industry practice to explain methods for the modeling of all of these processes, helping readers apply computational power to more areas of textile engineering. Experimental results are presented and linked closely to processes and methods of implementation. Diverse concepts such as heat transfer, fluid dynamics, three-dimensional motion, and multi-phase flow are addressed. Finally, tools, theoretical principles, and numerical models are extensively covered. Textile engineering involves complex processes which are not easily expressed numerically or simulated, such as fiber motion simulation, yarn to fiber formation, melt spinning technology, optimization of yarn production, textile machinery design and optimization, and modeling of textile/fabric reinforcements. - Provides new approaches and techniques to simulate a wide range of textile processes from geometry to manufacturing - Includes coverage of detailed mathematical methods for textiles, including neural networks, genetic algorithms, and the finite element method - Addresses modeling techniques for many different phenomena, including heat transfer, fluid dynamics and multi-phase flow
Rapid Solidification Processing of molten metals and alloys has proved to be a reliable route for producing new and advanced materials. The Chill-Block Melt Spin (CBMS) technique is important because its simplicity, flexibility and perfection. High quality materials can be produced with lower costs, as compared to other routes, by refining the microstructure and trapping the nucleated (new) metastable phases. Melt-spun ribbons subsequently produced can then be consolidated to produce billets and sheets that can be used in many industries especially high-tech industries such as aerospace and racing automobiles. This book contains several perspectives about CBMS technology and should be a useful review for undergraduate and post-graduate metallurgy students.
Most of the shaping in the manufacture of polymeric objects is carried out in the melt state, as it is a substantial part of the physical property development. Melt processing involves an interplay between fluid mechanics and heat transfer in rheologically complex liquids, and taken as a whole it is a nice example of the importance of coupled transport processes. This book is on the underlying foundations of polymer melt processing, which can be derived from relatively straightforward ideas in fluid mechanics and heat transfer; the level is that of an advanced undergraduate or beginning graduate course, and the material can serve as the text for a course in polymer processing or for a second course in transport processes.
This book introduces anisotropic innovations in liquid crystalline polymers as well as new nanocomposite materials and testing techniques. The authors detail the newest discoveries of material properties, material types and phases, and material characterization. This interdisciplinary work creates valuable links that strengthen the approach to the evolving field of liquid crystalline polymers/ materials.
Polymer Processing Instabilities: Control and Understanding offers a practical understanding of the various flows that occur during the processing of polymer melts. The book pays particular attention to flow instabilities that affect the rate of production and the methods used to prevent and eliminate flow instabilities in order to increase product