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This volume and its companion Volume 1 chronicle the proceed ings of the International Symposium on Micellization, Solubiliza tion, and tficroemulsions held under the auspices of the Northeast Regional Meeting of the American Chemical Society in Albany, New York, August 8-11, 1976. The technical program consisted of 48 papers by 91 authors from twelve countries. The program was divided into six sessions, and Dr. Hartley delivered the Concluding Remarks. Subsequently, six more papers were contributed for the proceedings volumes with the result that these volumes contain Sl papers (three papers are not included for certain reasons) and are divided into seven parts. The first three parts are embodied in Volume I and the remaining four parts constitute Volume 2; each part is followed by a Discussion Section. Dr. Hartley's Concluding Remarks are in cluded in both volumes. When the idea of arranging a symposium on micelles was broached to me, I accepted it without an iota of hesitation. I had two op tions: either to make it a one- or two-sessions symposium, or bring together the global community actively carrying out research in this area. I opted for the latter as the subject was very timely and I knew that it would elicit very enthusiastic response. In order to broaden the scope of the symposium, I suggested that the theme of the symposium should be Micellizationy Solubilization and Microemulsions.
Guide to Protein Purification , designed to serve the needs of the student, experienced researcher and newcomer to the field, is a comprehensive manual that provides all the up-to-date procedures necessary for purifying, characterizing, and handling proteins and enzymes in one source. Key Features* Detailed procedures newly written for this volume* Extensive practical information* Rationale and strategies for protein and enzyme purification* Personal perspectives on enzyme purification by eminent researchersAmong the Topics Covered* General methods for handling proteins and enzymes * Extraction, subcellular fractionation, and solubilization procedures * Comprehensive purification techniques * Specialized purification procedures * Protein characterization * Immunological procedures * Computer analysis of protein structure.
This book describes the microemulsion phenomenon in a systematic manner and not only provides an up-to-date introduction to this topic but aslo serves as the basis for further development in the area.The progress of microemulsion research has taken place in well-defined stages. The introduction period was founded on Schulman‘s original discovery and was, as expected, focused on the interfacial free energy. Because Schulman obtained his microemulsions from a macroemulsion by the addition of a cosurfactant.The present stage is characterized by an extensively enhanced knowledge about structure and dynamics in these systems. This has led to the realization that the structure of the microemulsions is related both to solutions with critical behaviour and long range order structures, the lyotropic liquid crystals. These two aspects have been elucidated independently by the French groups and by the Lund Spectroscopy group.
This book describes the microemulsion phenomenon in a systematic manner and not only provides an up-to-date introduction to this topic but aslo serves as the basis for further development in the area.The progress of microemulsion research has taken place in well-defined stages. The introduction period was founded on Schulman‘s original discovery and was, as expected, focused on the interfacial free energy. Because Schulman obtained his microemulsions from a macroemulsion by the addition of a cosurfactant.The present stage is characterized by an extensively enhanced knowledge about structure and dynamics in these systems. This has led to the realization that the structure of the microemulsions is related both to solutions with critical behaviour and long range order structures, the lyotropic liquid crystals. These two aspects have been elucidated independently by the French groups and by the Lund Spectroscopy group.
Demonstrating methods for overcoming stability issues in paints, wax dispersions, cosmetics, food products, and other industrial applications, this reference probes theoretical and practical issues surrounding microemulsion science and technology. Featuring the work of 51 international experts and containing almost 1000 instructive tables, equations, and illustrations, this book reviews the performance of, and prospects for, experimental methods such as X-ray diffraction, transmission electron microscopy (TEM), light scattering, small angle neutron scattering, viscosimetry, and nuclear magnetic resonance (NMR) to characterize various aspects of the dispersed phase of microemulsions.
During the last decade there has been a renewed interest in research on supramolecular assemblies in solutions, such as micelles and microemulsions, not only because of their extensive applications in industries dealing with catalysts, detergency, biotechnology, and enhanced oil recovery, but also due to the development of new and more powerful experimental and theoretical tools for probing the microscopic behavior of these systems. Prominent among the array of the newly available experimental techniques are photon correlation spectroscopy, small-angle neutron and X-ray scattering, and neutron spin-echo and nuclear magnetic resonance spectroscopies. On the theoretical side, the traditionally emphasized thermodynamic approach to the study of the phase behavior of self-assembled systems in solutions is gradually being replaced by statistical mechanical studies of semi-micro scopic and microscopic models of the assemblies. Since the statistical mechanical approach demands as its starting point the microscopic struc tural information of the self-assembled system, the experimental determina tion of the structures of micelles and microemulsions becomes of paramount interest. In this regard the scattering techniques mentioned above have played an important role in recent years and will continue to do so in the future. In applying the scattering techniques to the supramolecular species in solution, one cannot often regard the solution to be ideal. This is because the inter-aggregate interaction is often long-ranged since it is coulombic in nature and the interparticle correlations are thus appreciable.
Surfactant research explores the forces responsible for surfactant assembly and the critical industrial, medical, and personal applications, including viscosity control, microelectronics, drug stabilization, drug delivery, cosmetics, enhanced oil recovery, and foods. Surfactant Science and Technology: Retrospects and Prospects, "a Festschrift in ho
Beginning with P.A. Winsor's fundamental hypothesis on a natural interfacial curvature depending on the values of the formulation variables, this unique book shows scientists how to understand the intrinsic structure of these complex systems and their corresponding physical properties... predict how a change in one formulation variable (surfactant structure, oil structure, aqueous phase composition, temperature, etc.) will modify the microemulsion... and systematically formulate microemulsions for individual applications.This book provides a thermodynamic analysis supporting the existence of natural interfacial curvature... compares the behavior of commercial surfactant mixtures and pure isomeric surfactant molecules in order to point out differences and similarities highly significant for various uses... explains how micelles can evolve smoothly and continuously toward solutions containing large quantities of oil and water... gives procedures for fixing quantitative relationships among formulation variables... plus much more.Illustrated with more than 200 diagrams, tables, and photographs, and completely referenced, this superb volume is essential reading for surfactant, colloid, and physical chemists in both academe and industry, as well as chemical engineers, biotechnologists, and petroleum engineers.Contents: 1. The R-Ratio. 2. Aqueous solutions containing amphiphiles. 3. Nonpolar solutions containing amphiphiles. 4. The phase behavior and properties of solutions containing amphiphiles, organic liquids, and water: micellar solutions. 5. Methods for promoting phase changes. 6. Compensating changes between formulation variables. 7. Solubilization. 8. Thermodynamics of solubilized systems.