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The dramatic evolution of catalytic converters in the last thirty years was a result of a need worldwide to reduce pollution created by the exhaust gases of internal combustion engines. Environmental concerns have led American, Japanese and European Union (EU) legislation to pose continuously stricter emission limits for petrol engines in the last decades. The catalytic converter has become the most important means of exhaust treatment to achieve the desired emission limits. The international legislation has also created a need for a regular assessment of the efficiency of the catalytic converter in order to detect a deterioration of its conversion efficiency as soon as this deterioration takes place. The assessment of conversion efficiency of a catalytic converter can take place during normal driving of a vehicle (on-board diagnosis or OBD) or in a workshop by specialized technicians. The most important methods nowadays are the OBD methods. The evolution of methods concerned with OBD and non-OBD monitoring and diagnosing of efficiency of catalytic converters of internal combustion engines is described based on patents and published patent applications. Non-patent references are also used. The basic principles of modern catalytic converters are described in an extensive Introduction, where the importance of monitoring and diagnosing the efficiency of catalytic converters is demonstrated. The book is divided into four parts. The first part describes methods involving the use of oxygen or air/fuel exhaust gas sensors to determine the oxygen storage capacity of a catalytic converter. The second part describes methods involving the use of temperature sensors to determine the exothermic reaction capacity of a catalytic converter. The third part describes all other methods existing in patent literature that monitor and diagnose the efficiency of catalytic converters. The great majority of the methods of the third part involves exhaust gas concentration measurements. The fourth part comprises a general discussion of all methods described. In the beginning of each part, a short introduction is given to explain the problem that the methods attempt to solve. The methods in each part are presented in chronological order per patent applicant. This helps to evaluate how the patent applicant has improved his methods over time. A patent number index with information about the patent applicants, inventors, priorities and patent-families, an inventor index, a company index and a subject index can be found at the end of the book.
This book is divided in five main parts (production technology, system production, machinery, design and materials) and tries to show emerging solutions in automotive industry fields related to OEMs and no-OEMs sectors in order to show the vitality of this leading industry for worldwide economies and related important impacts on other industrial sectors and their environmental sub-products.
This book covers the most important topics concerning cationic Ziegler-Natta and ring-opening metathesis polymerization of cycloolefins. The work describes the major pathways that cycloolefins can follow under the action of specific catalytic systems, essentially vinyl and ring-opening polymerization, both reaction types allowing the manufacture of distinct products with wide applicability in modern technologies. The comprehensive data available on this subject are logically and systematically selected and reviewed throughout 18 chapters, according to the basic catalytic processes involved, types of monomers and catalysts employed, reaction conditions and application fields. The modern trends in design of chiral metallocene catalysts, well-defined living metathesis catalysts, catalysts tolerant toward functionalities and water systems are highlighted. The book discusses in detail the relevant aspects of these processes including reaction thermodynamics, kinetics, mechanisms and stereochemistry and correlates the structure of produced polymers with their chemical and physical-mechanical properties. Related important topics include Ziegler-Natta polymerization of olefins and dienes, atom transfer radical polymerization of vinyl compounds, metathesis of olefins and acetylenes, acyclic diene metathesis reaction, carbonyl olefination reaction, metathesis polymerization of acetylenes, metathesis degradation of polymers and ring-opening polymerization of heterocycles. Special emphasis is laid upon the manufacture of commerical products, new polymers and copolymers of potential interest for industry and design and synthesis of speciality polymers with particular structures and architectures and desired properties. The book critically evaluates the most recent achievements reported in this field and outlines the modern trends on the research and application of the catalytic processes for cycloolefin polymerization. For the first time, comprehensive information about the published data on the subject up to now is provided for both academic and industrial researchers working in the areas of polymer chemistry, organic and organometallic chemistry, surface science and catalysis, petrochemistry and chemical engineering. This stimulating book offers an enlightening introduction and a quick documentation on the subject as well as a solid background in this field. Moreover, the work offers a wealth of useful information for specialists applying polymers in various scientific and industrial areas.
Catalyst production for the transformation of crudes into gasoline and other fuel products is a billion dollar/year business and fluid cracking catalysts (FCCs) represent almost half of the refinery catalyst market. During the cracking reactions, the FCC surface is contaminated by metals (Ni, V, Fe, Cu, Na) and by coke deposition. As a result, the catalyst activity and product selectivity is reduced to unacceptable levels thus forcing refiners to replace part of the recirculating equilibrium FCC inventory with fresh FCC to compensate for losses in catalyst performance. About 1,100 tons/day of FCC are used worldwide in over 200 fluid cracking catalyst units (FCCUs). It is for these reasons that refiners' interest in FCC research has remained high through the years almost independantly, of crude oil prices. However, recent oil company mergers and the dissolution of research laboratories, have drastically decreased the number of researchers involved in petroleum refining research projects; as a result the emphasis of research has shifted from new materials to process improvements and this trend is clearly reflected in the type of papers contained in this volume. Modern spectroscopic techniques continue to be essential in the understanding of catalyst performance and several chapters in the book describe the use of 27Al, 29Si and 13C NMR to study variation in FCC acidity during aging and coke deposition. In addition several chapters have been dedicated to the modeling of FCC deactivation, and to the understanding of contact times on FCC performance. Refiners efforts to conform with environmental regulations are reflected in chapters dealing with sulfur removal, metals contaminants and olefin generation.
This volume looks at the recent progress of this technology as reported in the 21 papers presented during the 219th National Meeting of the ACS in New York, September 5-11, 2003.In addition, the volume focuses on the use of modern spectroscopic techniques for the generation of detailed structural analysis required for the advancement of the science of FCC design.Other chapters look at the use and importance of solid state nuclear magnetic resonance (NMR), microcalorimetry and atomic force microscopy (AFM) to the study of FCCs and discussing strategies to control pollutant emissions from a refinery FCCU and looking at advances in FCC preparation.
The science of catalytic reaction engineering studies the catalyst and the catalytic process in the laboratory in order to predict how they will perform in production-scale reactors. Surprises are to be avoided in the scaleup of industrial processes. The laboratory results must account for flow, heat and mass transfer influences on reaction rate to be useful for scaleup. Calculated performance based on these results must also be useful to maximization of profit and safety and minimization of pollution. To this end, information on products as well as byproducts and heat produced must be generated. If a sufficiently large database of knowledge is produced, optimization studies will be possible later if economic conditions change.The field of reaction engineering required new tools. For kinetic and catalyst testing, the most successful of these tools was the internal recycle reactor. Studies in recycle reactors can be made under well-defined conditions of flow and associated transfer processes, and close to commercial operation. The recycle reactor eliminates or minimizes the effect of transfer process, and allows the remaining ones to be known.Features of this book:• Provides insight into a field that is neither well understood nor properly appreciated.• Gives a deeper understanding of reaction engineering practice.• Helps avoid frustration and disappointment in industrial research. This book is short and clear enough to assist all members of the R&D and Engineering team, whether reaction engineers, or specialists in other fields. This is critical in this new age of computation and communication, when team members must each know at least something of their colleagues' fields. Additionally, many scientists in more exploratory or fundamental fields can use recycle reactors to study basic phenomena free of transfer interactions.
This proceedings contains the papers presented at the 9th International Symposium on Catalyst Deactivation, held in Lexington, KY, USA, on 7-10 October 2001.
The proceedings of the VIIth International Symposium on the Scientific Bases for the Preparation of Heterogeneous Catalysts, are in line with the general scope of this series of events. Emphasis in all Symposia has been on the scientific aspects of the preparation of new and industrial catalysts, or on new methods of preparation, rather than on the catalytic reactions in which such solids are ultimately used. In the present context, the catalytic event itself has only been considered as another, though often decisive, method of catalyst characterization.
This authoritative new book focuses on recent developments in the instrumentation for sending voltages and currents. It covers new trends and challenges in the field, such as measurements of biocurrents, the increased speed of the components for data taking, testing of computers and integrated circuits where the measurement of rapid voltage and current variations on a very small geometrical scale is necessary. The first chapter concentrates on recent methods to sense voltages and currents, while the rest of the book investigates the applied side, covering for instance electrical power and energy measurements. The main purpose of this volume is to illustrate commonly employed techniques rather than track the scientific evolution and merits and therefore mainly covers patent literature aimed at industrial applications. It is an exciting addition, justifying the series' claim to cover state-of-the-art developments in both the applied and theoretical fields of sensors and actuators. The measurement of voltages and currents is a common task in the field of electricity and electronics. From a technical point of view it is useful to identify schematically different steps of such a measurement. In a first step a voltage or a current is sensed, intermediate steps such as amplification, transmission and further treatment may follow to yield the result in the final step. Today in most cases microprocessors perform the final steps of such measurements. Analog-to digital converters digitise a voltage that is proportional to the value to be measured and a processor performs further computations and handles the storage and the display of the results. The prerequisite for such measurements are sensors or transducers that respond in a known way to the voltage or current to be measured. The emphasis of this book is put on recent developments of the instrumentation for sensing voltages and currents. Aside from the general trend towards smaller, cheaper and more reliable instrumentation, new demands have arisen. New applications, like measurements of biocurrents, ask for higher sensitivities. Computers and integrated circuits pose new challenges. To exploit the increased speed of the components for data taking, suitable sensors are required. The accuracy that can be achieved depends more than ever on the first step, the acquisition of the raw data. The influence of the measurement process on the results becomes more crucial. Testing of integrated circuits themselves is a completely new application. For such tests one has to measure rapid voltage and current variations on very small geometrical scales. Here, as well as in the traditional high voltage applications, contactless measurements play an important role. The organisation of this book is as follows: In the first chapter different methods to sense voltages and currents are described. For the sake of completeness most commonly used methods are mentioned, we concentrate, however, on those developed recently. The chapters address the subject from the side of different applications in which voltages and currents are sensed. Since the main purpose of this publication is to illustrate commonly employed techniques rather than to track the scientific evolution and merits in particular fields, in general those publications that illustrate a particular measurement principle best have been cited. The citation of a particular reference does therefore not imply that this is the first or most pertinent publication in the respective field.
This volume of Studies in Surface Science and Catalysis contains the Proceedings of the 9th International Symposium on the Scientific Bases for the Preparation of Heterogeneous Catalysts, held on the campus of the "Universit catholique de Louvain" (UCL) in Louvain-la-Neuve, Belgium, on September 10-14, 2006. This series of symposia was initiated in 1975 on a regular 4-year interval basis. The Symposium covered the following topics: key aspects in catalysts preparation, micro- and mesoporous supports, supported metal catalysts, structured catalysts, tailored zeolites, catalysis by bases, and catalysts for fuel production. These topics served as guidelines for the sessions both in the programs of oral communications (41 contributions including 7 keynote communications – one for each topic) and poster presentations (101 contributions). In addition, the opening invited lecture addressed the question of scaling-up high-throughput experimental approaches.* Contains a collection of the papers presented at the workshop