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Corrosion due to water is one of the most significant and complex causes of damage to metallic products. Written from the viewpoint of physical chemistry, this authoritative and established text deals with the aqueous corrosion of metals. Available for the first time in English, Corrosion of Metal addressing engineers, metallurgists, physicists and chemists. This self-contained, valuable reference comprehensively organizes and makes readily accessible the accumulated wealth of fundamental and applied knowledge. The concentration is on the underlying essentials of corrosion and failure, and the material is consistently presented in relation to practical applications to corrosion protection. The first chapters introducing the physicochemical principles are ideal for students. The following chapters provide an overview of the state of research for those familiar with the fundamentals. An exhaustive bibliography and appendices conclude the volume.
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Understanding corrosion is essential for selecting and maintaining equipment and structural components that will withstand environmental and process conditions effectively. Fundamentals of Metallic Corrosion: Atmospheric and Media Corrosion of Metals focuses on the mechanisms of corrosion as well as the action of various corrodents on metals and th
The book is concerned with understanding the fundamental mechanisms of high temperature alloy oxidation. It uses this understanding to develop methods of predicting oxidation rates and the way they change with temperature, gas chemistry and alloy composition. The focus is on designing (or selecting) alloy compositions which provide optimal resistance to attack by corrosive gases. . Emphasises quantitative calculations for predicting reaction rates and the effects of temperature, oxidant activities and alloy compositions. . Uses phase diagrams and diffusion paths to analyse and interpret scale structures and internal precipitation distributions . Provides a detailed examination of corrosion in industrial gases (water vapour effects, carburisation and metal dusting, sulphidation) . Text is well supported by numerous micrographs, phase diagrams and tabulations of relevant thermodynamic and kinetic data . Combines physical chemistry and materials science methodologies.
Considerable progress has been made in the past 20 years toward understanding the basic mechanisms of corrosion, and the application of this knowledge to its control. From the very beginning, educational institutions and industrial research laboratories have contributed greatly toward determining and elucidating the fundamental principles of corrosion reactions. Some of the basic principles involved in cor rosion of metals can be credited to early investigators. Michael Faraday in 1830-1840 studied the relationship between the quantity of a metal dissolved and the electric current which was produced by this reaction. He also proposed that the passivation of iron was through the formation of a film and that the dissolution of a metal was electro chemical in nature. Sir Humphrey Davy in 1824 worked out the funda mentals of galvanic corrosion of ships' hulls and applied sacrificial zinc anodes to protect them from sea water corrosion. Richard Arlie in 1847 demonstrated that corrosion produced by oxygen at the surface of iron in a flowing stream generated a current. With the fundamental knowledge available to him from these early investigators, Willis Rodney Whitney developed and expressed, in its most useful form, one of the basic scientific principles which provides modern corrosion specialists with a fundamental basis of corrosion control. Dr. Whitney concluded that corrosion of iron is electrochemical, and that the rate is simply a function of the electromotive force and resistance of the circuit.
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Corrosion may be defined as an unintentional attack on a material through reaction with a surrounding medium. The term can refer to a process or to the damage caused by such a process. According to this general definition, materials other than metals, such as ceramics, plastics or concrete, may also be subject to corrosion (or corrode). When no particular reference is made to the material, however, it is normally understood that a metal is being attacked. It is entirely in this limited sense that the term is used in this book. There are good reasons for treating the corrosion of metals separately, apart from deterioration or decay of other materials. Since metals have a high electric conductivity, their corrosion is usually of an electrochemical nature. The chemical deterioration of electrically non-conducting ma terials, such as plastics and ceramics, is governed by other physico-chemical principles. It is necessary to devote more attention to metallic corrosion nowadays than earlier, due to 1. An increased use of metals within all fields of technology. 2. The use for special applications, e.g. within the atomic energy field, of rare and expensive metals, whose preservation requires particular precautions. 3. A more corrosive environment due to the increasing pollution of air and water. 4. The use of metallic constructions of more slender dimensions which do not tolerate corrosive attacks to the same extent as did the heavy constructions used in the old days.
This highly practical reference presents for the first time in a single volume all types of environmental degradation a metallic compound may undergo during its processing, storage, and service. Clarifying general and localized corrosion effects, Environmental Degradation of Metals describes the effects of atmospheric exposure, high-temperature gases, soil, water, weak and strong chemicals, liquid metals, and nuclear radiation. It determines whether corrosion can occur under a given set of conditions, shows how improvements in component design can reduce corrosion, and details the high- and low-temperature effects of oxidizing agents. The book also investigates the instantaneous and delayed failure of solid metal in contact with liquid metal, highlights the influence of hydrogen on metal, and profiles radiation effects on metal.
Covering the essential aspects of the corrosion behavior of metals in aqueous environments, this book is designed with the flexibility needed for use in courses for upper-level undergraduate and graduate students, for concentrated courses in industry, for individual study, and as a reference book.