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Bulk metallic glasses are a new emerging field of materials with many desirable and unique properties. These amorphous materials have many diverse applications from structural applications to biomedical implants. This book provides a complete overview of bulk metallic glasses. It covers the principles of alloy design, glass formation, processing, atomistic modeling, computer simulations, mechanical properties and microstructures.
Reflecting the fast pace of research in the field, the Second Edition of Bulk Metallic Glasses has been thoroughly updated and remains essential reading on the subject. It incorporates major advances in glass forming ability, corrosion behavior, and mechanical properties. Several of the newly proposed criteria to predict the glass-forming ability of alloys have been discussed. All other areas covered in this book have been updated, with special emphasis on topics where significant advances have occurred. These include processing of hierarchical surface structures and synthesis of nanophase composites using the chemical behavior of bulk metallic glasses and the development of novel bulk metallic glasses with high-strength and high-ductility and superelastic behavior. New topics such as high-entropy bulk metallic glasses, nanoporous alloys, novel nanocrystalline alloys, and soft magnetic glassy alloys with high saturation magnetization have also been discussed. Novel applications, such as metallic glassy screw bolts, surface coatings, hyperthermia glasses, ultra-thin mirrors and pressure sensors, mobile phone casing, and degradable biomedical materials, are described. Authored by the world’s foremost experts on bulk metallic glasses, this new edition endures as an indispensable reference and continues to be a one-stop resource on all aspects of bulk metallic glasses.
Metallic glasses are multi-component metallic alloys with disordered atomic distribution unlike their crystalline counterparts with long range periodicity in arrangement of atoms. Metallic glasses of different compositions are being commercially used in bulk form and as coatings because of their excellent corrosion resistance. This book was written with the objective of providing a comprehensive understanding of the electrochemical and corrosion behavior of metallic glasses for a wide range of compositions. Corrosion in structural materials leads to rapid deterioration in the performance of critical components and serious economic implications including property damage and loss in human life. Discovery and development of metallic alloys with enhanced corrosion resistance will have a sizable impact in a number of areas including manufacturing, aerospace, oil and gas, nuclear industry, and load-bearing bioimplants. The corrosion resistance of many metallic glass systems is superior compared to conventionally used alloys in different environments. In this book, we discuss in detail the role of chemistry, processing conditions, environment, and surface state on the corrosion behavior of metallic glasses and compare their performance with conventional alloys. Several of these alloy systems consist of all biocompatible and non-allergenic elements making them attractive for bioimplants, stents, and surgical tools. To that end, critical insights are provided on the bio-corrosion response of some metallic glasses in simulated physiological environment.
This book is a printed edition of the Special Issue "Metallic Glasses" that was published in Metals
Metallic glasses are very promising engineering and functional materials due to their unique mechanical, chemical, and physical properties, attracting increasing attention from both scientific and industrial communities. However, their practical applications are greatly hindered due to three main problems: dimensional limit, poor tension plasticity, and difficulty in machining and shaping. Therefore, further investigation of these issues is urgently required. This book provides readers with recent achievements and developments in the properties and processing of metallic glasses, including mainly thermoplastic forming of metallic glasses (Chapter 2), atomic-level simulation of mechanical deformation of metallic glasses (Chapter 3), metallic glass matrix composites (Chapter 4), and tribo-electrochemical applications of metallic glasses (Chapters 5 and 6).
This book presents a comprehensive and holistic study of microstrucure evoution during solidification and additive manufacturin.g Bulk metallic glasses and their composites have attracted a lot of attention lately in the scientific community owing to their excellent mechanical properties (combination of hardness, strength, and high elastic strain limit). However, they still lack toughness and tensile ductility and exhibit catastrophic failure upon tension. This can be overcome by various means, of which in situ introduction of ductile crystalline precipitates/phases during solidification proved to be the best. Various studies have been carried out in the last two decades, which explain this phenomenon. However, there is a gap on how this can be achieved in modern additive manufacturing exploiting inherent nature of process. This book aims to bridge this gap. A comprehensive and holistic study is presented, documenting the step-by-step evolution of these materials since their inception till date, explaining the development of toughness in them by modeling and simulation of microstructure evolution during solidification and additive manufacturing.
Reflecting the fast pace of research in the field, the Second Edition of Bulk Metallic Glasses has been thoroughly updated and remains essential reading on the subject. It incorporates major advances in glass forming ability, corrosion behavior, and mechanical properties. Several of the newly proposed criteria to predict the glass-forming ability of alloys have been discussed. All other areas covered in this book have been updated, with special emphasis on topics where significant advances have occurred. These include processing of hierarchical surface structures and synthesis of nanophase composites using the chemical behavior of bulk metallic glasses and the development of novel bulk metallic glasses with high-strength and high-ductility and superelastic behavior. New topics such as high-entropy bulk metallic glasses, nanoporous alloys, novel nanocrystalline alloys, and soft magnetic glassy alloys with high saturation magnetization have also been discussed. Novel applications, such as metallic glassy screw bolts, surface coatings, hyperthermia glasses, ultra-thin mirrors and pressure sensors, mobile phone casing, and degradable biomedical materials, are described. Authored by the world’s foremost experts on bulk metallic glasses, this new edition endures as an indispensable reference and continues to be a one-stop resource on all aspects of bulk metallic glasses.
The Special Issue “Recent Advancements in Metallic Glasses” presents ten original papers, considering both scientific and application issues related to metallic glasses. The papers are devoted to general consideration of the formation and defects of the glassy structure, defect evolution due to heat treatment, deformation behavior upon compression and high-pressure torsion, amorphous-crystalline transformation, hydrogenation behavior, and biomedical applications.
The book provides a comprehensive state-of-the-art review on the topic of bulk metallic glass matrix composites and understanding of mechanisms of development of composite microstructure. It discusses mechanisms of formation and toughening both during conventional casting routes and additive manufacturing. The second edition encompasses new studies and highlights advancement in mechanical properties, characterization, processing and applications.
Metallic Glasses and Their Oxidation provides a comprehensive review of the structures, properties, preparations, processing and applications of metallic glasses. Special attention is paid to the oxidation behaviors and related mechanisms of metallic glasses that occur during their preparation, processing and application. The book's authors introduce basic knowledge of metallic glasses, including their structures, properties, processing techniques and applications. Then, the theories and techniques commonly used in oxidation investigation are highlighted, including thermal oxidation, native oxidation, stressed oxidation, powder oxidation and oxidation simulation. The book closes with the influence of oxidation on the structures and performances of metallic glasses, proposes measures to control oxidation, and discusses how to take advantage of oxidation to reinforce materials or create new materials. - Introduces the latest knowledge on the structures, properties, preparation, processing and application of metallic glasses - Reviews the fundamental concepts surrounding metal oxidation, including techniques, devices and methods frequently used in oxidation research - Discusses measures to control oxidation and the possibilities of using oxidation to reinforce metallic glasses or create new types of materials