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Considerable recent research has focused on the topic of chemical speciation in the environment. It is increasingly realised that the distribution, mobility and biological availability of chemical elements depend not simply on their concentrations but, critically, on the forms in which they occur in natural systems. Continuing developments in analytical chemistry have made speciation practicable even where analytes are present at trace levels (as is often the case in natural samples). In the second edition of this book, the expertise of scientists involved in chemical speciation in various fields have been brought together to provide an overview of the current status of speciation science and indicate how the field may develop in the future.
Proceedings of the NATO Advanced Study Institute on Metal Speciation in the Environmental held in Cesme, Turkey, October 9-20, 1989
This book presents new results on metal fluxes from society to the environment, on metal speciation in water, soil and sediment, and its mobility, biological uptake and toxicity. New approaches, like the Acid Volatile Sulphide (AVS) concept to predict metal bioavailability in sediments, and the Biotic Ligand Model to calculate the toxicity of metals to aquatic organisms, are critically evaluated, with a focus on copper, nickel, zinc, and, chromium.
The ongoing progress of science has shown that it is important for analytical scientists to determine not only the presence of particular elements, but also their species. There are many fields where this is applicable, and where there are a number of topics to be addressed. Developing separation and measurement systems for the many element species has tested the resourcefulness of analytical chemists over recent decades. A product of the EU sponsored Speciation 21 Network, this book presents a detailed review of the state-of-the-art of speciation issues in the occupational health, food and environment sectors, along with the main conclusions arising from discussions held during expert meetings. Topics covered include mercury and organotin compounds in the environment; factors affecting the health of workers; the importance of speciation of trace elements for health, and subsequent metabolism in the body; analytical methodologies; risk assessment; and legislation. Trace Element Speciation for Environment, Food and Health provides an insight into applied research in the speciation field and how it has become so important in all the fields represented. With its comprehensive coverage, it will be of particular interest to researchers in industry and academia, as well as government agencies and legislative bodies.
This publication deals with fundamental concepts and models, speciation measurements and field applications in metal speciation and bioavailability in aquatic environments. This volume provides a thorough review of current developments concerning the interactions between trace metals and aquatic organisms.
Volume 17, entitled Lead: Its Effects on Environment and Health of the series Metal Ions in Life Sciences centers on the interrelations between biosystems and lead. The book provides an up-to-date review of the bioinorganic chemistry of this metal and its ions; it covers the biogeochemistry of lead, its use (not only as gasoline additive) and anthropogenic release into the environment, its cycling and speciation in the atmosphere, in waters, soils, and sediments, and also in mammalian organs. The analytical tools to determine and to quantify this toxic element in blood, saliva, urine, hair, etc. are described. The properties of lead(II) complexes formed with amino acids, peptides, proteins (including metallothioneins), nucleobases, nucleotides, nucleic acids, and other ligands of biological relevance are summarized for the solid state and for aqueous solutions as well. All this is important for obtaining a coherent picture on the properties of lead, its effects on plants and toxic actions on mammalian organs. This and more is treated in an authoritative and timely manner in the 16 stimulating chapters of Volume 17, which are written by 36 internationally recognized experts from 13 nations. The impact of this recently again vibrant research area is manifested in nearly 2000 references, over 50 tables and more than 100 illustrations (half in color). Lead: Its Effects on Environment and Health is an essential resource for scientists working in the wide range from material sciences, inorganic biochemistry all the way through to medicine including the clinic ... not forgetting that it also provides excellent information for teaching.
Report, the editors replaced the term "speciation" wherever it occurred by "identification and quantification," or "description of abundance," or "reactivity," or "transformation" of a chemical species, according to whichever one of the four meanings the author had evidently meant to convey. In line with the Dahlem Workshop Model, this Report comprises the background papers written in advance of the meeting on the current status of problems in environmental research and on advanced analytical tech niques for the identification and quantification of chemical species, as well as the group reports summarizing the results of the discussions held during the meeting. Each group report was prepared during the meeting by one "rapporteur" with the help of members of that group and finalized by the rapporteur (listed as the first author of the group report) after the meeting, taking into account both verbal comments made during the presentation of the reports in the plenary session at the end of the workshop and written comments received afterwards.
"Heavy Metals: Problems and Solutions" is divided into three sections dealing with basic geochemical processes, remediation and case studies. The basic geochemical processes are discussed with respect to mobility in the environment and impact as well as methods to derive guidelines for heavy metals. Remediation focuses on currently available methods to treat contaminated sediments and soils. In addition, it considers the concept of geochemical engineering for remediation of large areas contaminated by metals. A number of case studies of polluted sediments and soils and their environmental impact highlight the principles discussed in the first two sections.
The aim of this volume is to describe the most recent advances in areas of analytical chemistry that relate to the trace determination of metals and inorganics, as well as their distribution and forms (species) present, sample dependent. Analytical approaches are described that encompass a number of separation methods, such as gas and high performance liquid chromatography, interfaced with selective and sensitive detection methods that become unique for metal species/forms present in various samples. Hyphenated techniques are emphasized, such as interfacing HPLC with plasma induced emission spectroscopy, electrochemistry, post-column reaction chemistry, etc. Each chapter describes the latest instrumental and methodology advances that utilize some form of chromatography together with element-specific detection or mass spectrometry to provide absolute identification of the specific species of a metal present in various samples. The book will be of value to those concerned with the determination of trace levels of individual metal species present or suspected present in any given sample and to those involved in trace metal toxicology, metabolism of metal-containing drugs or chemicals, environmental exposures to metals and chemical speciation of real world samples. Government regulatory laboratories striving to detect and determine absolute levels of a metal species in any regulated sample will be interested in this volume, as will academic institutes involved in environmental toxicology, environmental chemistry, metal-DNA/protein interactions and researchers working with metal species.