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Metal-Organic Frameworks for Chemical Reactions: From Organic Transformations to Energy Applications brings together the latest information on MOFs materials, covering recent technology in the field of manufacturing and design. The book covers different aspects of reactions from energy storage and catalysts, including preparation, design and characterization techniques of MOFs material and applications. This comprehensive resource is ideal for researchers and advanced students studying metal-organic frameworks in academia and industry. Metal-organic frameworks (MOFs) are nanoporous polymers made up of inorganic metal focuses connected by natural ligands. These entities have become a hot area of research because of their exceptional physical and chemical properties that make them useful in di?erent ?elds, including medicine, energy and the environment. Since combination conditions strongly a?ect the properties of these compounds, it is especially important to choose an appropriate synthetic technique that produces a product with homogenous morphology, small size dispersion, and high thermal stability. Covers the synthetic advantages and versatile applications of metal-organic frameworks (MOFs) due to their organic-inorganic hybrid nature and unique porous structure Includes energy applications such as batteries, fuel storage, fuel cells, hydrogen evaluation reactions and super capacitors Features information on using MOFs as a replacement to conventional engineering materials because they are lightweight, less costly, environmentally-friendly and sustainable
Because of their nanoporous structures and ultra-high surface areas Metal-Organic Framework Composites (MOFs) are very interesting materials. The book focusses on the following applications: gas capture and storage, especially molecular hydrogen storage; performance enhancement of Li-ion batteries; gas separation, nano-filtration, ionic sieving, water treatment, and catalysis; sustainable renewable energy resources, electrochemical capacitors, including supercapacitors, asymmetric supercapacitors and hybrid supercapacitors; biomedical disciplines including drug delivery, theranostics; biological detection and imaging; nanoparticle photosensitizers for photodynamic therapy (PDT) and photothermal therapy (PTT). Keywords: MOF Materials, Hydrogen Storage, Renewable Energy Applications, Lithium Batteries, MOF-Quantum Dots, Clean Energy, Nanoporous MOFs, Supercapacitors, Therapeutic Applications, Biosensing, Bioimaging, Phototherapy of Cancer, Gas Separation, Nano-filtration, Ionic Sieving, Water Treatment, Drug Delivery, Theranostics; Nanoparticle Photosensitizers, Photodynamic Therapy (PDT), Photothermal Therapy (PTT).
Metal-organic frameworks represent a new class of materials that may solve the hydrogen storage problem associated with hydrogen-fueled vehicles. In this first definitive guide to metal-organic framework chemistry, author L. MacGillivray addresses state-of-art developments in this promising technology for alternative fuels. Providing professors, graduate and undergraduate students, structural chemists, physical chemists, and chemical engineers with a historical perspective, as well as the most up-to-date developments by leading experts, Metal-Organic Frameworks examines structure, symmetry, supramolecular chemistry, surface engineering, metal-organometallic frameworks, properties, and reactions.
Metal–organic frameworks are among the most promising novel materials. The concept of MOFs was first introduced in 1990. They were actually initially used in catalysis, gas separation, membranes, electrochemical sensors. Later on, they were introduced as SPE sorbents for PAHs (Polycyclic Aromatic Hydrocarbons) in environmental water samples, then the range expanded to the field of analytical chemistry, both in chromatographic separation and sample preparation, with great success in, e.g., SPE and SPME (Solid Phase Mico-extraction). Since then, the number of analytical applications implementing MOFs as sorbents in sorptive sample preparation approaches is increasing. Τhis is reinforced by the fact that, at least theoretically, an infinite number of structures can be designed and synthesized, thus making tuneability one of the most unique characteristics of MOF materials. Moreover, they have been designed in various shapes, such as columns, fibers, and films, so that they can meet more analytical challenges with improved analytical features.Their exceptional properties attracted the interest of analytical chemists who have taken advantage of the unique structures and properties and have already introduced them in several sample pretreatment techniques, such as solid phase extraction, dispersive SPE, magnetic solid phase extraction, solid phase microextraction, stir bar sorptive extraction, etc.
Metal-Organic Frameworks for Biomedical Applications is a comprehensive, authoritative reference that offers a substantial and complete treatment of published results that have yet to be critically reviewed. It offers a summary of current research and provides in-depth understanding of the role of metal-organic frameworks in biomedical engineering. The title consists of twenty-two chapters presented by leading international researchers in the field. Chapters are arranged by target-application in biomedical engineering, allowing medical and pharmaceutic specialists to translate current materials and engineering science on metal-organic frameworks into their work.
Composites based on Metal-organic frameworks (MOFs) have exceptional physical and chemical properties and offer a great number of advanced applications in such fields as energy storage, energy conversion by catalysis, sensors for environmental applications, environment safety and industrial wastewater treatments. They also have interesting medical applications, such as encapsulation of enzymes. The present book covers design, synthesis and preparation of various MOFs, as well as the resulting product characteristics: homogenous morphology, small size dispersion, high thermal stability and desired surface area.
Metal–organic frameworks (MOFs) are porous crystalline polymers con­structed by metal sites and organic building blocks. Since the discovery of MOFs in the 1990s, they have received tremendous research attention for various applications due to their high surface area, controllable mor­phology, tunable chemical properties, and multifunctionalities, including MOFs as precursors and self-sacrificing templates for synthesizing metal oxides, heteroatom-doped carbons, metal-atoms encapsulated carbons, and others. Thus, awareness and knowledge about MOFs and their derived nanomaterials with conceptual understanding are essential for the advanced material community. This breakthrough new volume aims to explore down-to-earth applications in fields such as bio­medical, environmental, energy, and electronics. This book provides an overview of the structural and fundamental properties, synthesis strate­gies, and versatile applications of MOFs and their derived nanomaterials. It gives an updated and comprehensive account of the research in the field of MOFs and their derived nanomaterials. Whether as a reference for industry professionals and nanotechnologists or for use in the classroom for graduate and postgraduate students, faculty members, and research and development specialists working in the area of inorganic chemistry, materials science, and chemical engineering, this is a must-have for any library.
Metal-Organic Frameworks for Environmental Applications examines this important topic, looking at potential materials and methods for the remediation of pressing pollution issues, such as heavy-metal contaminants in water streams, radioactive waste disposal, marine oil-spillage, the treatment of textile and dye industry effluents, the clean-up of trace amounts of explosives in land and water, and many other topics. This survey of the cutting-edge research and technology of MOFs is an invaluable resource for researchers working in inorganic chemistry and materials science, but it is also ideal for graduate students studying MOFs and their applications. - Examines the applications of metal-organic frameworks for the remediation of environmental pollutants - Features leading experts who research the applications of MOFs from around the world, including contributions from the United States, India and China - Explores possible solutions to some of today's most pressing environmental challenges, such as heavy-metal contamination in bodies of water, oil spills and clean-up of explosives hidden in land and water - Provides an excellent reference for researchers and graduate students studying in the areas of inorganic chemistry, materials chemistry and environmental science
Metal Oxides in Supercapacitors addresses the fundamentals of metal oxide-based supercapacitors and provides an overview of recent advancements in this area. Metal oxides attract most of the materials scientists use due to their excellent physico-chemical properties and stability in electrochemical systems. This justification for the usage of metal oxides as electrode materials in supercapacitors is their potential to attain high capacitance at low cost. After providing the principles, the heart of the book discusses recent advances, including: binary metal oxides-based supercapacitors, nanotechnology, ternary metal oxides, polyoxometalates and hybrids. Moreover, the factors affecting the charge storage mechanism of metal oxides are explored in detail. The electrolytes, which are the soul of supercapacitors and a mostly ignored character of investigations, are also exposed in depth, as is the fabrication and design of supercapacitors and their merits and demerits. Lastly, the market status of supercapacitors and a discussion pointing out the future scope and directions of next generation metal oxides based supercapacitors is explored, making this a comprehensive book on the latest, cutting-edge research in the field. - Explores the most recent advances made in metal oxides in supercapacitors - Discusses cutting-edge nanotechnology for supercapacitors - Includes fundamental properties of metal oxides in supercapacitors that can be used to guide and promote technology development - Contains contributions from leading international scientists active in supercapacitor research and manufacturing
Biocatalysis has become an essential tool in the chemical industry and is the core of industrial biotechnology, also known as white biotechnology, making use of biocatalysts in terms of enzymes or whole cells in chemical processes as an alternative to chemical catalysts. This shift can be seen in the many areas of daily life where biocatalysts-with