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Research on metal-containing polymers began in the early 1960's when several workers found that vinyl ferrocene and other vinylic transition metal u -com plexes would undergo polymerization under the same conditions as conventional organic monomers to form high polymers which incorporated a potentially reactive metal as an integral part of the polymer structures. Some of these materials could act as semi-conducters and pos sessed one or two dimensional conductivity. Thus appli cations in electronics could be visualized immediately. Other workers found that reactions used to make simple metal chelates could be used to prepare polymers if the ligands were designed properly. As interest in homo geneous catalysts developed in the late 60's and early 70's, several investigators began binding homogeneous catalysts onto polymers, where the advantage of homo geneous catalysis - known reaction mechanisms and the advantage of heterogeneous catalysis - simplicity and ease of recovery of catalysts could both be obtained. Indeed the polymer matrix itself often enhanced the selectivity of the catalyst.
Self-Healing Polymer-Based Systems presents all aspects of self-healing polymeric materials, offering detailed information on fundamentals, preparation methods, technology, and applications, and drawing on the latest state-of-the-art research. The book begins by introducing self-healing polymeric systems, with a thorough explanation of underlying concepts, challenges, mechanisms, kinetic and thermodynamics, and types of chemistry involved. The second part of the book studies the main categories of self-healing polymeric material, examining elastomer-based, thermoplastic-based, and thermoset-based materials in turn. This is followed by a series of chapters that examine the very latest advances, including nanoparticles, coatings, shape memory, self-healing biomaterials, ionomers, supramolecular polymers, photoinduced and thermally induced self-healing, healing efficiency, life cycle analysis, and characterization. Finally, novel applications are presented and explained. This book serves as an essential resource for academic researchers, scientists, and graduate students in the areas of polymer properties, self-healing materials, polymer science, polymer chemistry, and materials science. In industry, this book contains highly valuable information for R&D professionals, designers, and engineers, who are looking to incorporate self-healing properties in their materials, products, or components. - Provides comprehensive coverage of self-healing polymeric materials, covering principles, techniques, and applications - Includes the very latest developments in the field, such as the role of nanofillers in healing, life cycle analysis of materials, and shape memory assisted healing - Enables the reader to unlock the potential of self-healing polymeric materials for a range of advanced applications
Research on applications of polymers for biomedical applications has increased dramatically to find improved medical plastics for this rapidly evolving field. This book brings together various aspects of recent research and developments within academia and industry related to polymers for biomedical applications.
The vast array of libraries in the world bear mute witness to the truth of the 3000-year-old observation of King Solomon who stated " ... of making many books there is no end, and much study is a weariness of the flesh." Yet books are an essential written record of our lives and the progress of science and humanity. Here is another book to add to this huge collection, but, hopefully, not just another collection of pages, but rather a book with a specific purpose to aid in alleviating the "weariness of the flesh" that could arise from much studying of other journals and books in order to obtain the basic information contained herein. This book is about polymeric materials and biological activity, as the title notes. Polymeric materials, in the broad view taken here, would include not only synthetic polymers (e.g., polyethylene, polyvinyl chloride, polyesters, polyamides, etc.), but also the natural macromolecules (e.g., proteins, nucleic acids, polysaccharides) which compose natural tissues in humans, animals and plants. In the broad sense used here, biological activity is any type of such action whether it be in medication, pest control, plant-growth regu lation, and so on. In short, this book attempts to consider, briefly, the use of any type of polymeric material system with essentially any kind of biological activity.
This book overviews methods for the synthesis of metal-containing monomers with various types of metal bonds to the organic moiety of the molecule, such as ionic, covalent, donor-acceptor, and others. Published data on homopolymerization, copolymerization, and graft polymerization of these monomers are generalized. Synthesis and Polymerization of Metal-Containing Monomers discusses features typical of the molecular and structural organization of the resulting metal-containing polymers, their properties and the associated major applications, such as catalytical and biological activity, electrophysical characteristics, and thermal resistance.
A detailed, up-to-date review of transition metal-containing polymers Promising advances in the electrical, optical, magnetic, biological, and catalytic properties that metal-containing polymers possess have led to notable expansion in the field of transition metal-containing polymers. Frontiers in Transition Metal-Containing Polymers provides a comprehensive, up-to-date review of the synthesis, properties, and applications of transition metal-containing polymers, including an overview of the historical development of these types of polymers. Written by the leading researchers in the field, this thorough volume covers the routes to organometallic and coordination polymers, as well as characterization and applications of transition metal-containing monomers and polymers. Other topics discussed include: Metallo-supramolecular coordination polymers based on nitrogen ligands Coordination polymers based on phosphorus ligands Polypeptide-based metallobiopolymers and DNA-based metallopolymers Metallodendrimers Self-assembly of metal-containing block copolymers Applications including drug delivery, optics, molecular devices, sensors, conductive materials, and more
Phase morphology in multicomponent polymer-based systems represents the main physical characteristic that allows for control of the material design and implicitly the development of new plastics. Emphasizing properties of these promising new materials in both solution and solid phase, this book describes the preparation, processing, properties, and practical implications of advanced multiphase systems from macro to nanoscales. It covers a wide range of systems including copolymers, polymer blends, polymer composites, gels, interpenetrating polymers, and layered polymer/metal structures, describing aspects of polymer science, engineering, and technology. The book analyzes experimental and theoretical aspects regarding the thermal and electrical transport phenomena and magnetic properties of crucial importance in advanced technologies. It reviews the most recent advances concerning morphological, rheological, interfacial, physical, fire-resistant, thermophysical, and biomedical properties of multiphase polymer systems. Concomitantly the book deals with basic investigation techniques that are sensitive in elucidating the features of each phase. It also discusses the latest research trends that offer new solutions for advanced bio- and nanotechnologies. Introduces an overview of recent studies in the area of multiphase polymer systems, their micro- and nanostructural evolutions in advanced technologies, and provides future outlooks, new challenges and opportunities. Discusses multicomponent structures that offer enhanced physical, mechanical, thermal, electrical, magnetic, and optical properties adapted to current requirements of modern technologies. Covers a wide range of materials, such as composites, blends, alloys, gels and interpenetrating polymer networks. Presents new strategies for controlling the micro- and nanomorphology and the mechanical properties of multiphase polymeric materials. Describes different applications of multiphase polymeric materials in various fields, including automotive, aeronautics and space industry, displays, and medicine.
Provides complete and undiluted knowledge on making inorganic polymers functional. This comprehensive book reflects the state of the art in the field of inorganic polymers, based on research conducted by a number of internationally leading research groups working in this area. It covers the synthesis aspects of synthetic inorganic polymers and looks at multiple inorganic monomers as building blocks, which exhibit unprecedented electronic, redox, photo-emissive, magnetic, self-healing and catalytic properties. It also looks at the applications of inorganic polymers in areas such as optoelectronics, energy storage, industrial chemistry, and biology. Beginning with an overview of the use of smart inorganic polymers in daily life, Smart Inorganic Polymers: Synthesis, Properties and Emerging Applications in Materials and Life Sciences goes on to study the synthesis, properties, and applications of polymers incorporating different heteroelements such as boron, phosphorus, silicon, germanium, and tin. The book also examines inorganic polymers in flame-retardants, as functional materials, and in biology. An excellent addition to the polymer scientists' and synthetic chemists' toolbox Summarizes the state of the art on how to make and use functional inorganic polymers, from synthesis to applications Edited by the coordinator of a highly funded European community research program (COST action) that focuses specifically on the exploration of inorganic polymers Features contributions from top experts in the field Aimed at academics and industrial researchers in this field, Smart Inorganic Polymers: Synthesis, Properties and Emerging Applications in Materials and Life Sciences will also benefit scientists who want to get a better overview on the state-of-the-art of this rapidly advancing area.
This first book on this important and emerging topic presents an overview of the very latest results obtained in single-chain polymer nanoparticles obtained by folding synthetic single polymer chains, painting a complete picture from synthesis via characterization to everyday applications. The initial chapters describe the synthetics methods as well as the molecular simulation of these nanoparticles, while subsequent chapters discuss the analytical techniques that are applied to characterize them, including size and structural characterization as well as scattering techniques. The final chapters are then devoted to the practical applications in nanomedicine, sensing, catalysis and several other uses, concluding with a look at the future for such nanoparticles. Essential reading for polymer and materials scientists, materials engineers, biochemists as well as environmental chemists.
Research on metal-containing polymers began in the early 1960's when several workers found that vinyl ferrocene and other vinylic transition metal TI -complexes would undergo polymerization under the same conditions as conventional organic monomers to form high polymers which incorporated a potentially reactive metal as an integral part of the polymer structures. Some of these materials could act as semi conductors and possessed one or two dimensional conductivity. Thus applications in electronics could be visualized immediately. Other workers found that reactions used to make simple metal chelates could be used to prepare polymers if the ligands were designed properly. As interest in homogeneous catalysts developed in the late 60's and early 70's, several investigators began binding homogeneous catalysts onto polymers, where the advantage of homogeneous catalysis - known reaction mechanisms and the advantage of heterogeneous catalysis - simplicity and ease of recovery of catalysts could both be obtained. Indeed the polymer matrix itself often enhanced the selectivity of the catalyst. The first symposium on Organometallic Polymers, held at the National Meeting of the American Chemical Society in September 1977, attracted a large number of scientists interested in this field, both established investigators and newcomers. Subsequent symposia in 1977, 1979, 1983, and 1987 have seen the field mature. Hundreds of papers and patents have been published.