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In This Short But Authoritative Book, Drs. Ray And Kauffman Succinctly Review All Important Studies On Complexes Of Biguanide And Its Derivatives Published Since Priyadaranjan Rays Classical Chemical Review Article By Giving Special Attention To Synthesis, Properties, Magnetism, Spectroscopy, Reactions, Kinetics, Structures And Applications. This Book Is The Only One Of Its Kind. The Structures Of The Ligands And Their Complexes As Revealed By Magnetic Moments, Electronic Spectra, Epr And X-Ray Crystallography Have Been Considered.The Books References Which Number More Than Four Hundred Should Give Practising Scientists Ready Access To The Crucial Details Needed For Research And Development On These Theoretically And Practically Significant Compounds. As Such, It Provides Data That Widely Scattered Is In Scientific Literatures In A Single Handy Source Book. This Book Is Heartily Recommend To Inorganic, Organic, Medical And Pharmaceutical Chemists, As Well As To Anyone Concerned With This Unique Class Of Ligands And Their Complexes With A Wide Variety Of Elements Of Varying Oxidation States And Coordination Numbers.
Reaction Mechanisms of Metal Complexes in Solution provides a comprehensive overview of an often-overlooked research area. Despite its importance and recent reshaping of the field, many inorganic chemists have lost an appreciation for the significance of stability constants and the thermodynamic aspects of complex formation. Ideal for newcomers and established researchers in the field this book is a complete treatment of the area covering advanced topics with relevance to biomedical applications, extraction metallurgy, food chemistry and a wealth of other industrial processes and research areas. The book will be of particular interest to postgraduates with an interest in coordination chemistry, catalysis, supramolecular chemistry, metallobiology and related aspects of biochemistry.
A comprehensive handbook valuable when doing routine analysis or developing new methods of chromatography of organic materials. Section I presents the principles, techniques, quantitative determi-nations and detection methods used in chromatographic analysis. In the major part of the book, Section II summarized data in volumi-nous tabular/graphic form on paper, thin layer, liquid and gas chro-matography. Section III lists important books on eletrophoreses, gel permeation chromatography, and ion exchange, in addition to the other forms of chromatography mentioned above
The present volume, "Manganese" D 5, continues the description of the manganese complexes. The arrangement of the complexes in these D volumes is based on the ligand type. The introduction, on p. 1, shows the classes of complexes, which have already been described in Chapters 1 to 21 in the Volumes D 1 (1979), D 2 (1980), D 3 (1982), and D 4 (1985). In Chapters 22 to 29 of this volume are treated complexes with amine-N-polycarboxylic acids, hydrazinecarboxylic acids, amides, hydrazides, derivatives of hydroxylamine (e.g., hydroxamic acids), oximes and nitroso compounds, azo compounds, and triazenes. A survey at the beginning of each of these sections gives information on the most characteristic features of the various complex types. Because of the complexometric relevance of the complexes with amine-N-polycarboxylic acids, there are many studies concerning the existence and the stability of the complexes in solution. Numerous X-ray investigations, reported for the complexes with urea or with amides and hydrazides of carboxylic acids, show the different structures of the compounds as a result of the varying bonding sites of the ligands. Complexes with hydrazides (e.g., with isonicotino hydrazide) are of special interest, due to their biological activity. Complexes with hydroxamic acids, oximes or azo compounds have been studied mostly in aqueous organic or pure organic solvents. The characteristic intense colors of many solutions are used for the analytical determination of manganese.
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