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Membrane Reactors for Hydrogen Production Processes deals with technological and economic aspects of hydrogen selective membranes application in hydrogen production chemical processes. Membrane Reactors for Hydrogen Production Processes starts with an overview of membrane integration in the chemical reaction environment, formulating the thermodynamics and kinetics of membrane reactors and assessing the performance of different process architectures. Then, the state of the art of hydrogen selective membranes, membrane manufacturing processes and the mathematical modeling of membrane reactors are discussed. A review of the most useful applications from an industrial point of view is given. These applications include: natural gas steam reforming, autothermal reforming, water gas shift reaction, decomposition of hydrogen sulphide, and alkanes dehydrogenation. The final part is dedicated to the description of a pilot plant where the novel configuration was implemented at a semi-industrial scale. Plant engineers, researchers and postgraduate students will find Membrane Reactors for Hydrogen Production Processes a comprehensive guide to the state of the art of membrane reactor technology.
Membrane reactors are increasingly replacing conventional separation, process and conversion technologies across a wide range of applications. Exploiting advanced membrane materials, they offer enhanced efficiency, are very adaptable and have great economic potential. There has therefore been increasing interest in membrane reactors from both the scientific and industrial communities, stimulating research and development. The two volumes of the Handbook of membrane reactors draw on this research to provide an authoritative review of this important field.Volume 2 reviews reactor types and industrial applications, beginning in part one with a discussion of selected types of membrane reactor and integration of the technology with industrial processes. Part two goes on to explore the use of membrane reactors in chemical and large-scale hydrogen production from fossil fuels. Electrochemical devices and transport applications of membrane reactors are the focus of part three, before part four considers the use of membrane reactors in environmental engineering, biotechnology and medicine. Finally, the book concludes with a discussion of the economic aspects of membrane reactors.With its distinguished editor and international team of expert contributors, the two volumes of the Handbook of membrane reactors provide an authoritative guide for membrane reactor researchers and materials scientists, chemical and biochemical manufacturers, industrial separations and process engineers, and academics in this field. - Discusses integration of membrane technology with industrial processes - Explores the use of membrane reactors in chemical and large-scale hydrogen production from fossil fuels - Considers electrochemical devices and transport applications of membrane reactors
In the last decade, the attention paid to the environmental protection has generated a considerable interest towards the development of new energy carriers and green energy production methods. Hydrogen as an energy carrier becomes a potential important source of energy due to its neutral environmental impact. However, its production, transformation and purification, presents a challenge in the so called hydrogen economy. Current Trends and Future Developments on (Bio-) Membranes gives a comprehensive review on the present state of the art of the hydrogen production and purification using new and alternative technologies stressing green processes and environment protection. The book covers green processes, renewable feedstocks utilization and membrane reactor technology for hydrogen production in line with new process intensification strategy. The book is divided in four sections, ie fundamentals of hydrogen generation, its impact on environmental issue, new applications involving hydrogen and its storage and distribution. The main scope of this book is to offer a new horizon on hydrogen generation and utilization. It stresses the role of new technologies for hydrogen generation, including the "micro-reactors technology for portable applications”, their combination with high temperature fuel cells, the role of gas-separation for both hydrogen purification and CO2 sequestration, the exploitation of renewable sources (biogas, bioethanol and other renewables feedstocks) in reforming processes useful to generate hydrogen, membrane and membrane reactor technology as well as membrane bio-reactors etc.
Provides a comprehensive practical review of the new technologies used to obtain hydrogen more efficiently via catalytic, electrochemical, bio- and photohydrogen production. Hydrogen has been gaining more attention in both transportation and stationary power applications. Fuel cell-powered cars are on the roads and the automotive industry is demanding feasible and efficient technologies to produce hydrogen. The principles and methods described herein lead to reasonable mitigation of the great majority of problems associated with hydrogen production technologies. The chapters in this book are written by distinguished authors who have extensive experience in their fields, and readers will have a chance to compare the fundamental production techniques and learn about the pros and cons of these technologies. The book is organized into three parts. Part I shows the catalytic and electrochemical principles involved in hydrogen production technologies. Part II addresses hydrogen production from electrochemically active bacteria (EAB) by decomposing organic compound into hydrogen in microbial electrolysis cells (MECs). The final part of the book is concerned with photohydrogen generation. Recent developments in the area of semiconductor-based nanomaterials, specifically semiconductor oxides, nitrides and metal free semiconductor-based nanomaterials for photocatalytic hydrogen production are extensively discussed.
Thanks to their outstanding hydrogen selectivity, palladium membranes have attracted extensive R&D interest. They are a potential breakthrough technology for hydrogen production and also have promising applications in the areas of thermochemical biorefining. This book summarises key research in palladium membrane technologies, with particular focus on the scale-up challenges. After an introductory chapter, Part one reviews the fabrication of palladium membranes. Part two then focuses on palladium membrane module and reactor design. The final part of the book reviews the operation of palladium membranes for synthesis gas/hydrogen production, carbon capture and other applications. - Review of manufacture and design issues for palladium membranes - Discussion of the applications of palladium membrane technology, including solar steam reforming, IGCC plants, NGCC plants, CHP plants and hydrogen production - Examples of the technology in operation
Membrane reactors are increasingly replacing conventional separation, process and conversion technologies across a wide range of applications. Exploiting advanced membrane materials, they offer enhanced efficiency, are very adaptable and have great economic potential. There has therefore been increasing interest in membrane reactors from both the scientific and industrial communities, stimulating research and development. The two volumes of the Handbook of membrane reactors draw on this research to provide an authoritative review of this important field.Volume 1 explores fundamental materials science, design and optimisation, beginning with a review of polymeric, dense metallic and composite membranes for membrane reactors in part one. Polymeric and nanocomposite membranes for membrane reactors, inorganic membrane reactors for hydrogen production, palladium-based composite membranes and alternatives to palladium-based membranes for hydrogen separation in membrane reactors are all discussed. Part two goes on to investigate zeolite, ceramic and carbon membranes and catalysts for membrane reactors in more depth. Finally, part three explores membrane reactor modelling, simulation and optimisation, including the use of mathematical modelling, computational fluid dynamics, artificial neural networks and non-equilibrium thermodynamics to analyse varied aspects of membrane reactor design and production enhancement.With its distinguished editor and international team of expert contributors, the two volumes of the Handbook of membrane reactors provide an authoritative guide for membrane reactor researchers and materials scientists, chemical and biochemical manufacturers, industrial separations and process engineers, and academics in this field. - Considers polymeric, dense metallic and composite membranes for membrane reactors - Discusses cereamic and carbon for membrane reactors in detail - Reactor modelling, simulation and optimisation is also discussed
Hydrogen is one of the most promising next-generation fuels. It has the highest energy content per unit weight of any known fuel and in comparison to the other known natural gases it is environmentally safe - in fact, its combustion results only in water vapour and energy. This book provides an overview of worldwide research in the use of hydrogen in energy development, its most innovative methods of production and the various steps necessary for the optimization of this product.
Catalytic Reactors presents several key aspects of reactor design in Chemical and Process Engineering. Starting with the fundamental science across a broad interdisciplinary field, this graduate level textbook offers a concise overview on reactor and process design for students, scientists and practitioners new to the field. This book aims to collate into a comprehensive and well-informed work of leading researchers from north America, western Europe and south-east Asia. The editor and international experts discuss state-of-the-art applications of multifunctional reactors, biocatalytic membrane reactors, micro-flow reactors, industrial catalytic reactors, micro trickle bed reactors and multiphase catalytic reactors. The use of catalytic reactor technology is essential for the economic viability of the chemical manufacturing industry. The importance of Chemical and Process Engineering and efficient design of reactors are another focus of the book. Especially the combination of advantages from both catalysis and chemical reaction technology for optimization and intensification as essential factors in the future development of reactors and processes are discussed. Furthermore, options that can drastically influence reaction processes, e.g. choice of catalysts, alternative reaction pathways, mass and heat transfer effects, flow regimes and inherent design of catalytic reactors are reviewed in detail. Focuses on the state-of-the-art applications of catalytic reactors and optimization in the design and operation of industrial catalytic reactors Insights into transfer of knowledge from laboratory science to industry For students and researchers in Chemical and Mechanical Engineering, Chemistry, Industrial Catalysis and practising Engineers
Palladium (Pd)-based membranes have received a great deal of attention from both academia and industry thanks to their ability to selectively separate hydrogen from gas streams. The integration of such membranes with appropriate catalysts in membrane reactors allows for hydrogen production with CO2 capture that can be applied in smaller bioenergy or combined heat and power (CHP) plants, as well as in large-scale power plants. Pd-based membranes are therefore regarded as a Key Enabling Technology (KET) to facilitate the transition towards a knowledge-based, low-carbon, and resource-efficient economy. This Special Issue of the journal Membranes on “Pd-based Membranes: Overview and Perspectives” contains nine peer-reviewed articles. Topics include manufacturing techniques, understanding of material phenomena, module and reactor design, novel applications, and demonstration efforts and industrial exploitation.
Covers the timely topic of fuel cells and hydrogen-based energy from its fundamentals to practical applications Serves as a resource for practicing researchers and as a text in graduate-level programs Tackles crucial aspects in light of the new directions in the energy industry, in particular how to integrate fuel processing into contemporary systems like nuclear and gas power plants Includes homework-style problems