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This is the second edition of Melt Rheology and its Role in Plastics Processing, although the title has changed to reflect its broadened scope. Advances in the recent years in rheometer technology and polymer science have greatly enhanced the usefulness of rheology in the plastics industry. It is now possible to design polymers having specific molecular structures and to predict the flow properties of melts having those structures. In addition, rheological properties now provide more precise information about molecular structure. This book provides all the information that is needed for the intelligent application of rheology in the development of new polymers, the determination of molecular structure and the correlation of processability with laboratory test data. Theory and equations are limited to what is essential for the use of rheology in the characterization of polymers, the development of new plastics materials and the prediction of plastics processing behavior. The emphasis is on information that will be of direct use to practitioners. Extensive references are provided for those wishing to pursue certain issues in greater depth. While the primary audience is applied polymer scientists and plastics engineers, the book will also be of use to postgraduate students in polymer science and engineering and as a text for a graduate course.
This book is designed to fulfill a dual role. On the one hand it provides a description of the rheological behavior of molten poly mers. On the other, it presents the role of rheology in melt processing operations. The account of rheology emphasises the underlying principles and presents results, but not detailed deriva tions of equations. The processing operations are described qualita tively, and wherever possible the role of rheology is discussed quantitatively. Little emphasis is given to non-rheological aspects of processes, for example, the design of machinery. The audience for which the book is intended is also dual in It includes scientists and engineers whose work in the nature. plastics industry requires some knowledge of aspects of rheology. Examples are the polymer synthetic chemist who is concerned with how a change in molecular weight will affect the melt viscosity and the extrusion engineer who needs to know the effects of a change in molecular weight distribution that might result from thermal degra dation. The audience also includes post-graduate students in polymer science and engineering who wish to acquire a more extensive background in rheology and perhaps become specialists in this area. Especially for the latter audience, references are given to more detailed accounts of specialized topics, such as constitutive relations and process simulations. Thus, the book could serve as a textbook for a graduate level course in polymer rheology, and it has been used for this purpose.
Presents rheological data on a number of polymers, making use of the master curve approach to determine unified curves for each generic type of polymer. The text offers a step-by-step procedure for developing a speadsheet computer program to obtain accurate thermoplastic rheograms at any tempertature without using sophisticated rheometres. It inclu
This review encompasses fundamental principles and rheological equations of state, polymer melt rheology (shear and extensional flow, viscoelasticity, die swell and melt fracture) and rheological c094 techniques. It describes the main plastics processing techniques, and explains the influence of polymer melt rheology upon their operation. An additional indexed section containing several hundred abstracts from the Rapra Polymer Library database provides useful references for further reading.
Introduction to Fluoropolymers, Second Edition, provides a comprehensive overview of the history, principles, properties, processing and applications of fluoropolymers, supporting their development and utilization in high-performance applications, components, and products. This second edition has been updated and expanded to include new in-depth chapters on manufacturing and applications of PTFE and melt processible fluoropolymers. The book begins by demonstrating the role of fluoropolymers in everyday life, before introducing the history and basic principles of fluoropolymers. This is followed by detailed coverage of the main fluoropolymer types. Properties and applications are illustrated by real-world examples as diverse as waterproof clothing, vascular grafts and coatings for aircraft interiors. The different applications of fluoropolymers show the benefits of a group of materials that are highly water-repellant and flame-retardant, with unrivalled lubrication properties and a high level of biocompatibility. Health and safety and environmental aspects are also covered throughout the book, with a final chapter examining safety, disposal, and recycling in detail. This book is an essential resource for anyone looking to understand or use fluoropolymer materials in their products. This includes engineers, product designers, manufacturers, scientists, researchers, and other professionals, across industries such as automotive, aerospace, medical devices, food and beverages, high performance apparel, oil and gas, renewable energy, solar photovoltaics, electronics and semiconductors, pharmaceuticals, and chemical processing. This is also a valuable introductory guide for academic researchers and advanced students in plastics engineering, polymer science, and materials science. - Introduces and demystifies fluoropolymers for a wide audience of engineers, designers, professionals, and researchers, across industries and disciplines - Covers a broad range of materials, including polytetrafluoroethylene (PTFE), polyvinyl fluoride (PVF), vinylidene fluoride polymers, fluoroelastomers, and more - Focuses on properties, processing methods and advanced industrial applications of fluoropolymers
Fluoropolymer Applications in Chemical Processing Industries: The Definitive User's Guide and Handbook, Second Edition, contains the most extensive collection of data and information on fluoropolymer applications in chemical processing industries. Because of their superior properties, fluoropolymers have been rapidly replacing metal alloys for corrosion inhibition in chemical processing equipment. This book is a complete compendium of information about fluoropolymer lining materials and structural piping and tubing. Fluoropolymer surfaces preserve purity of processing streams in the chemical processing, plastics, food, pharmaceutical, semiconductor, and pulp and paper industries. Updated to reflect major changes since 2004, this book contains practical, problem-solving tools for professionals in those industries. Equipment manufacturers, plant operators, and product design and manufacturing engineers all will benefit from the in-depth knowledge provided. This new edition includes new fluoropolymer grades and new examples of the fluoropolymer role in preventing corrosion. New fabrication techniques have been added, and additional emphasis has been placed on adhesion and welding techniques. New sections have been added on inspection of new linings, and in-service inspection – including inspection frequency, acceptance criteria, fitness for service evaluation, and reparability. - Includes extensive guidelines for the selection of fluoropolymers for corrosion control - Features a detailed 'how-to' on processes that convert fluoropolymers into shapes and parts - Discusses fabrication techniques to finish the fluoropolymer components before exposure to harsh chemical environments - Includes laboratory techniques to determine the cause of part failure, and a modeling methodology to predict and analyze failure of fluoropolymer parts
As the complexity of the food supply system increases, the focus on processes used to convert raw food materials and ingredients into consumer food products becomes more important. The Handbook of Food Engineering, Third Edition, continues to provide students and food engineering professionals with the latest information needed to improve the efficiency of the food supply system. As with the previous editions, this book contains the latest information on the thermophysical properties of foods and kinetic constants needed to estimate changes in key components of foods during manufacturing and distribution. Illustrations are used to demonstrate the applications of the information to process design. Researchers should be able to use the information to pursue new directions in process development and design, and to identify future directions for research on the physical properties of foods and kinetics of changes in the food throughout the supply system. Features Covers basic concepts of transport and storage of liquids and solids, heating and cooling of foods, and food ingredients New chapter covers nanoscale science in food systems Includes chapters on mass transfer in foods and membrane processes for liquid concentration and other applications Discusses specific unit operations on freezing, concentration, dehydration, thermal processing, and extrusion The first four chapters of the Third Edition focus primarily on the properties of foods and food ingredients with a new chapter on nanoscale applications in foods. Each of the eleven chapters that follow has a focus on one of the more traditional unit operations used throughout the food supply system. Major revisions and/or updates have been incorporated into chapters on heating and cooling processes, membrane processes, extrusion processes, and cleaning operations.
The Science and Technology of Flexible Packaging: Multilayer Films from Resin and Process to End Use, Second Edition provides a comprehensive guide on plastic films in flexible packaging, covering scientific principles, materials properties, processes and end use considerations. Sections discuss the science of multilayer films in a concise and impactful way, presenting the fundamental understanding required to improve product design, material selection and processes. In addition, the book includes information on why one material is favored over another and how film or coating affects material properties. Descriptions and analysis of key properties of packaging films are provided from engineering and scientific perspectives. With essential scientific insights, best practice techniques, environmental sustainability information and key principles of structure design, this book provides information aids in material selection and processing, how to shorten development times and deliver stronger products, and ways to enable engineers and scientists to deliver superior products with reduced development time and cost. - Provides essential information on all aspects of multilayer films in flexible packaging, including processing, properties, materials and end use - Bridges the gap between scientific principles and practical challenges - Includes explanations to assist practitioners in overcoming challenges - Enables the reader to address new challenges, such as design for sustainability and eCommerce
This handbook provides an exhaustive description of polyethylene. The 50+ chapters are written by some of the most experienced and prominent authors in the field, providing a truly unique view of polyethylene. The book starts with a historical discussion on how low density polyethylene was discovered and how it provided unique opportunities in the early days. New catalysts are presented and show how they created an expansion in available products including linear low density polyethylene, high density polyethylene, copolymers, and polyethylene produced from metallocene catalysts. With these different catalysts systems a wide range of structures are possible with an equally wide range of physical properties. Numerous types of additives are presented that include additives for the protection of the resin from the environment and processing, fillers, processing aids, anti-fogging agents, pigments, and flame retardants. Common processing methods including extrusion, blown film, cast film, injection molding, and thermoforming are presented along with some of the more specialized processing techniques such as rotational molding, fiber processing, pipe extrusion, reactive extrusion, wire and cable, and foaming processes. The business of polyethylene including markets, world capacity, and future prospects are detailed. This handbook provides the most current and complete technology assessments and business practices for polyethylene resins.
Polymers are one of the most fascinating materials of the present era finding their applications in almost every aspects of life. Polymers are either directly available in nature or are chemically synthesized and used depending upon the targeted applications. Advances in polymer science and the introduction of new polymers have resulted in the significant development of polymers with unique properties. Different kinds of polymers have been and will be one of the key in several applications in many of the advanced pharmaceutical research being carried out over the globe. This 4-partset of books contains precisely referenced chapters, emphasizing different kinds of polymers with basic fundamentals and practicality for application in diverse pharmaceutical technologies. The volumes aim at explaining basics of polymers based materials from different resources and their chemistry along with practical applications which present a future direction in the pharmaceutical industry. Each volume offer deep insight into the subject being treated. Volume 1: Structure and Chemistry Volume 2: Processing and Applications Volume 3: Biodegradable Polymers Volume 4: Bioactive and Compatible Synthetic/Hybrid Polymers