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In the present chapter, results of our recent investigations on the role of gallium (Ga) on the aluminum (Al) site in Zr69.5Al7.5-xGaxCu12Ni11 metallic glass (MG) composition have been discussed. The material tailoring and cooling rate effects on the mechanical behavior of Zr-based metallic glasses and their nanocomposites have been studied. The substitution of Ga on the Al site in Zr-Al-Cu-Ni alloy affects the nucleation and growth characteristics of quasicrystals (QCs) and consequently changes the morphology of nanoquasicrystals. The Zr69.5Al7.5-xGaxCu12Ni11 system displayed metallic glass formation in the range of x = 0-7.5. In this process, we have come out with a new glass composition; Zr-Ga-Cu-Ni with glass transition temperature (Tg)-614 K. The effect of cooling rate on the glass forming ability (GFA) and mechanical properties for this new metallic glass composition has been discussed and compared with some other Zr-based metallic glasses. The various indentation parameters such as microhardness, yield strength, strain hardening constant, nature of shear band formation, and so on for the alloys have been analyzed. The study is focused on investigations of these materials to understand the structure (microstructure) property correlations.
Metallic Glass-Based Nanocomposites: Molecular Dynamics Study of Properties provides readers with an overview of the most commonly used tools for MD simulation of metallic glass composites and provides all the basic steps necessary for simulating any material on Materials Studio. After reading this book, readers will be able to model their own problems on this tool for predicting the properties of metallic glass composites. This book provides an introduction to metallic glasses with definitions and classifications, provides detailed explanations of various types of composites, reinforcements and matrices, and explores the basic mechanisms of reinforcement-MG interaction during mechanical loading. It explains various models for calculating the thermal conductivity of metallic glass composites and provides examples of molecular dynamics simulations. Aimed at students and researchers, this book caters to the needs of those working in the field of molecular dynamics (MD) simulation of metallic glass composites.
Bulk metallic glasses are a new emerging field of materials with many desirable and unique properties. These amorphous materials have many diverse applications from structural applications to biomedical implants. This book provides a complete overview of bulk metallic glasses. It covers the principles of alloy design, glass formation, processing, atomistic modeling, computer simulations, mechanical properties and microstructures.
Metallic glasses are very promising engineering and functional materials due to their unique mechanical, chemical, and physical properties, attracting increasing attention from both scientific and industrial communities. However, their practical applications are greatly hindered due to three main problems: dimensional limit, poor tension plasticity, and difficulty in machining and shaping. Therefore, further investigation of these issues is urgently required. This book provides readers with recent achievements and developments in the properties and processing of metallic glasses, including mainly thermoplastic forming of metallic glasses (Chapter 2), atomic-level simulation of mechanical deformation of metallic glasses (Chapter 3), metallic glass matrix composites (Chapter 4), and tribo-electrochemical applications of metallic glasses (Chapters 5 and 6).
Metallic glasses and their crystal/glass composites find ever more applications in such fields as mini transformers, microelectromechanical devices, pressure sensors, precision surgical instruments, biological implants and sportive goods (springs, diaphragms, membranes, knife blades, electromagnetic wave shields, optical mirrors, power inductors, Coriolis flow meters, etc.). The book reviews recent research and suggests future developments, e.g. in the area of dual-phase composite/hybrid materials. Keywords: Metallic Glasses, Crystal/Glass Composites, Dual-phase Composite/Hybrid Materials, Supercooled Liquid, Devitrification, Magnetic Materials, Microelectromechanical Devices, Pressure Sensors, Orthopedic Screws, Precision Instruments, Biological Implants, Electromagnetic Wave Shields, Optical Mirrors, Power Inductors, Coriolis Flow Meters.
In spite of the large amount of research activity in this subfield of materials science and engineering, there is no single book available that provides background information, methods of synthesis, characterization procedures, properties, and potential and existing applications.of bulk metallic glasses. Written in an easy-to-understand style by pioneering researchers in this field, Bulk Metallic Glasses is one of the first books to coherently discuss the synthesis, processing, properties, and applications of these unique materials. The book explores the differences between nanocrystalline, glassy, and amorphous solids as well as the thermodynamics and kinetics and various processing methods of glass formation. It critically compares the different criteria for glass formation, describes the advantages and limitations of experimental methods for synthesizing bulk metallic glasses in assorted sizes and shapes, and examines the kinetics of crystallization/devitrification and the mechanisms of transformations. It also covers the density, diffusivity, thermal expansion, electrical resistivity, specific heat, viscosity, corrosion resistance, mechanical behavior, and magnetic properties of bulk metallic glasses. After presenting a wide array of applications, the book concludes with a discussion on the future of these materials. The adoption of bulk metallic glasses into existing systems is besieged by many obstacles but due to their interesting combination of properties, future applications may be unlimited. A one-stop resource on all aspects of bulk metallic glasses, this book demonstrates the immense potential of these novel materials. It clearly elucidates the background, detailed methods of synthesis and characterization, structure, and properties of bulk metallic glasses.
Metallic glasses and amorphous materials have attracted much more attention in the last two decades. A noncrystalline solid produced by continuous cooling from the liquid state is known as a glass. From the other point of view, a noncrystalline material, obtained by any other process, for example, vapor deposition or solid-state processing methods such as mechanical alloying, but not directly from the liquid state, is referred to as an amorphous material. At this moment, bulk metallic glasses (BMG) are appearing as a new class of metallic materials with unique physical and mechanical properties for structural and functional usage. Extreme values of strength, fracture toughness, magnetic properties, corrosion resistance, and other properties have been registered in BMG materials.
The formation of metallic glasses and dual-phase composite/hybrid materials is reviewed, as well as the glass transition process and the resulting structural phenomena. These materials exhibit high strength, extreme hardness, good wear resistance and large elastic deformation. Due to their excellent structural, functional, magnetic, chemical and biological properties metallic glasses are suitable for a great many applications, including in such areas as microelectromechanical devices, pressure sensors, orthopaedic screws and precision surgical instruments. Metallic Glasses, Metallic Glass Composites, Crystal/Glass Transition, Nano-Crystallization, Phase Separations, Supercooled Liquids, Glassy Nanocomposites, Nanoscale Quasicrystals, Mechanical Properties, Nanoscale Wear Resistance, Bauschinger Effect, Cryogenic Temperature, Porous Glasses, Nanocomposite Alloys, Soft Magnetic Alloys, Hard Magnetic Alloys, Magnetocaloric Effect, Corrosion Resistant Alloys, Surface Oxides, Catalysts
Metallic Glasses and Their Oxidation provides a comprehensive review of the structures, properties, preparations, processing and applications of metallic glasses. Special attention is paid to the oxidation behaviors and related mechanisms of metallic glasses that occur during their preparation, processing and application. The book's authors introduce basic knowledge of metallic glasses, including their structures, properties, processing techniques and applications. Then, the theories and techniques commonly used in oxidation investigation are highlighted, including thermal oxidation, native oxidation, stressed oxidation, powder oxidation and oxidation simulation. The book closes with the influence of oxidation on the structures and performances of metallic glasses, proposes measures to control oxidation, and discusses how to take advantage of oxidation to reinforce materials or create new materials. - Introduces the latest knowledge on the structures, properties, preparation, processing and application of metallic glasses - Reviews the fundamental concepts surrounding metal oxidation, including techniques, devices and methods frequently used in oxidation research - Discusses measures to control oxidation and the possibilities of using oxidation to reinforce metallic glasses or create new types of materials