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This title is a revision of Experimental Thermodynamics Volume II, published in 1975, reflecting the significant technological developments and new methods introduced into the study of measurement of thermodynamic quantities.The editors of this volume were assigned the task of assembling an international team of distinguished experimentalists, to describe the current state of development of the techniques of measurement of the thermodynamic quantities of single phases. The resulting volume admirably fulfils this brief and contains a valuable summary of a large variety of experimental techniques applicable over a wide range of thermodynamic states with an emphasis on the precision and accuracy of the results obtained. Those interested in the art of measurements, and in particular engaged in the measurement of thermodynamic properties, will find this material invaluable for the guidance it provides towards the development of new and more accurate techniques.·Provides detailed descriptions of experimental chemical thermodynamic methods·Strong practical bias and includes both detailed working equations and figures for the experimental methods·Most comprehensive text in this field since the publication of Experimental Thermodynamics II
This volume is another in the series of IUPAC sponsored monographs that summarize the state of knowledge with respect to experimental techniques in thermochemistry and thermodynamics. Following volume VI, Measurement of Thermodynamic Properties of Single Phases, VI, this book contains descriptions of recent developments in the techniques for measurement of thermodynamic quantities for multiple phases of pure fluids as well mixtures over a wide range of conditions. The precision and accuracy of results obtained from each method was regarded as an essential element in each description. Throughout the text, the quantities, units and symbols are those defined by IUPAC for use in the international community. Measurement of Thermodynamic Properties of Multiple Phases, Volume VII is an invaluable reference source to researchers and graduate students. - Describes the latest techniques for studying multiple phases of pure component systems, using quantities, units and symbols as defined by IUPAC for use in the international community - Illustrates the measurement techniques to obtain activity coefficients, interfacial tension and critical parameters - An invaluable reference source to researchers and graduate students
This title is a revision of Experimental Thermodynamics Volume II, published in 1975, reflecting the significant technological developments and new methods introduced into the study of measurement of thermodynamic quantities. The editors of this volume were assigned the task of assembling an international team of distinguished experimentalists, to describe the current state of development of the techniques of measurement of the thermodynamic quantities of single phases. The resulting volume admirably fulfils this brief and contains a valuable summary of a large variety of experimental techniques applicable over a wide range of thermodynamic states with an emphasis on the precision and accuracy of the results obtained. Those interested in the art of measurements, and in particular engaged in the measurement of thermodynamic properties, will find this material invaluable for the guidance it provides towards the development of new and more accurate techniques. · Provides detailed descriptions of experimental chemical thermodynamic methods · Strong practical bias and includes both detailed working equations and figures for the experimental methods · Most comprehensive text in this field since the publication of Experimental Thermodynamics II
1. Introduction. -- 2. Phase Changes in Pure Component Systems: Liquids and Gases. -- 3. Phase Changes in Pure Component Systems: Liquids and Solids. -- 4. Phase Changes in Pure Component Systems: Solid and Solid. -- 5. Vapour-Liquid Equilibrium at Low Pressure. -- 6. Vapour-Liquid Equilibrium at High Pressure. -- 7. Low Pressure Gas Solubility in Liquids. -- 8. Liquid-Liquid Equilibrium. -- 9. Condensed Phases of Organic Materials: Solid-Liquid and Solid-Solid Equilibrium. -- 10. Condensed Phases of Inorganic Materials: Metallic Systems. -- 11. Condensed Phases of Inorganic Materials: Ceramic Systems. -- 12. Condensed Phases of Inorganic Materials: Molten Salts. -- 13. Measurement of Limiting Activity Coefficients Using Non-Analytical Tools. -- 14. Measurement of Limiting Activity Coefficients Using Analytical Tools. -- 15. Measurement of Interfacial Tension. -- 16. Critical Parameters.
CRC Press is pleased to introduce the new edition of Commonly Asked Questions in Thermodynamics, an indispensable resource for those in modern science and engineering disciplines from molecular science, engineering and biotechnology to astrophysics. Fully updated throughout, this edition features two new chapters focused on energy utilization and biological systems. This edition begins by setting out the fundamentals of thermodynamics, including its basic laws and overarching principles. It provides explanations of those principles in an organized manner, using questions that arise frequently from undergraduates in the classroom as the stimulus. These early chapters explore the language of thermodynamics; the first and second laws; statistical mechanical theory; measurement of thermodynamic quantities and their relationships; phase behavior in single and multicomponent systems; electrochemistry; and chemical and biochemical reaction equilibria. The later chapters explore applications of these fundamentals to a diverse set of subjects including power generation (with and without fossil fuels) for transport, industrial and domestic use; heating; decarbonization technologies; energy storage; refrigeration; environmental pollution; and biotechnology. Data sources for the properties needed to complete thermodynamic evaluations of many processes are included. The text is designed for readers to dip into to find an answer to a specific question where thermodynamics can provide some, if not all, of the answers, whether in the context of an undergraduate course or not. Thus its readership extends beyond conventional technical undergraduates to practicing engineers and also to the interested lay person who seeks to understand the discourse that surrounds the choice of particular technological solutions to current and future energy and material production problems.
Phase diagrams are "maps" materials scientists often use to design new materials. They define what compounds and solutions are formed and their respective compositions and amounts when several elements are mixed together under a certain temperature and pressure. This monograph is the most comprehensive reference book on experimental methods for phase diagram determination. It covers a wide range of methods that have been used to determine phase diagrams of metals, ceramics, slags, and hydrides.* Extensive discussion on methodologies of experimental measurements and data assessments * Written by experts around the world, covering both traditional and combinatorial methodologies* A must-read for experimental measurements of phase diagrams
Volumetric properties play an important role in research at the interface of physical chemistry and chemical engineering, but keeping up with the latest developments in the field demands a broad view of the literature. Presenting a collection of concise, focused chapters, this book offers a comprehensive guide to the latest developments in the field and a starting point for more detailed research. The chapters are written by acknowledged experts, covering theory, experimental methods, techniques, and results on all types of liquids and vapours. The editors work at the forefront of thermodynamics in mixtures and solutions and have brought together contributions from all areas related to volume properties, offering a synergy of ideas across the field. Graduates, researchers and anyone working in the field of volumes will find this book to be their key reference.
“Ionic liquids will never find application in industry”, “I don’t understand this fad for ionic liquids” and “there is no widespread interest in these systems” are just three of quotes from the reports of referees for research proposals that I have received over the years. I wonder what these people think today. There are currently at least nine large-scale industrial uses of ionic liquids, including, we now rec- nise, the production of ?-Caprolactam (a monomer for the production of nylon-6) [1]. There has been a steady increase in the interest in ionic liquids for well over a decade and last year the number of papers and patents including ionic liquids was counted in the thousands. This remarkable achievement has been built on the hard work and enthusiasm, first of a small band of devotees, but now of huge numbers of scientists all over the world who do not see themselves as specialists in ionic liquids. The ionic liquids field continues to develop at an incredible rate. No sooner do I think that I am on top of the literature than it turns out that a whole new area of work has emerged without me noticing. Things that were once supposedly impos- 1 sible in ionic liquids, such as measuring the H NMR of solutes, are now widely applicable (see Chapter 8). Hence, collected volumes such as this are very w- come.
Magnesium and Its Alloys: Technology and Applications covers a wide scope of topics related to magnesium science and engineering, from manufacturing and production to finishing and applications. This handbook contains thirteen chapters, each contributed by experts in their respective fields, and presents a broad spectrum of new information on pure magnesium, magnesium alloys, and magnesium matrix MgMCs composites. It covers such topics as computational thermodynamics, modern Mg-alloys with enhanced creep or fatigue properties, cutting-edge approaches to melt treating (grain refinement, micro-alloying, and the resulting solidification and growth), coatings, surface engineering, environmental protection (recycling and green energy storage and production), as well as biomedical applications. Aimed at researchers, professionals, and graduate students, the book conveys comprehensive and cutting-edge knowledge on magnesium alloys. It is especially useful to those in the fields of materials engineering, mechanical engineering, manufacturing engineering, and metallurgy.