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In February 1999, the California Office of Environmental Health Hazard Assessment issued a Public Health Goal (PHG) for total chromium of 2.5 μg/L. The PHG, based on a 10^6 risk level for 0.2 μg/L hexavalent chromium [Cr(VI)], was 40 times less than the USEPA's contaminant MCL of 100 μg/L for total chromium [Cr(III) ] Cr(VI)]. The success of the movie Erin Brockovich, which popularized a groundwater chromium pollution lawsuit in Hinkley, California, sensitized the public to the health hazards of chromium in drinking water. In 2001, the California state legislature passed a bill requiring the California Department of Health Services to adopt an MCL for Cr(VI). All of these actions must be viewed from the perspective that, at the time, no technology had been demonstrated to be effective at treating chromium to concentrations consistent with the total chromium PHG or the Cr(VI) 10^6 risk level of 0.2 μg/L. The purpose of this report was to present the results of this partnership study, which included an analysis of chromium occurrence and co-occurrence, an evaluation of Cr(VI) removal technologies, and an examination of chromium oxidation and reduction chemistry. This study investigated nearly all of the potential methods of controlling Cr(VI) either through the use of technologies that remove Cr(VI) directly (adsorption, anion exchange, membrane filtration) or those that remove the reduced form of chromium, Cr(III) (precipitation with membranes or coagulation and precipitation with conventional or membrane filters). These technologies were investigated using laboratory-scale testing methods, including batch isotherm tests, bench membrane systems, flow-through mini-columns, and jar testing techniques. For most technologies, controlled water matrices were used to screen performance. Selected technologies were further assessed using natural groundwater matrices from the Los Angeles Department of Water and Power and the Glendale Water and Power groundwater facilities.
This toxicological profile is prepared in accordance with guidelines developed by the Agency for Toxic Substances and Disease Registry (ATSDR) and the Environmental Protection Agency (EPA). The original guidelines were published in the Federal Register on April 17, 1987. Each profile will be revised and republished as necessary. The ATSDR toxicological profile succinctly characterizes the toxicologic and adverse health effects information for the toxic substances each profile describes. Each peer-reviewed profile identifies and reviews the key literature that describes a substance's toxicologic properties. Other pertinent literature is also presented but is described in less detail than the key studies. The profile is not intended to be an exhaustive document; however, more comprehensive sources of specialty information are referenced. The profiles focus on health and toxicologic information; therefore, each toxicological profile begins with a public health statement that describes, in nontechnical language, a substance's relevant toxicological properties. Following the public health statement is information concerning levels of significant human exposure and, where known, significant health effects. A health effects summary describes the adequacy of information to determine a substance's health effects. ATSDR identifies data needs that are significant to protection of public health. Each profile: (A) Examines, summarizes, and interprets available toxicologic information and epidemiologic evaluations on a toxic substance to ascertain the levels of significant human exposure for the substance and the associated acute, subacute, and chronic health effects; (B) Determines whether adequate information on the health effects of each substance is available or being developed to determine levels of exposure that present a significant risk to human health of acute, subacute, and chronic health effects; and (C) Where appropriate, identifies toxicologic testing needed to identify the types or levels of exposure that may present significant risk of adverse health effects in humans.
Due to increasing demand for potable and irrigation water, water suppliers have to use alternative resources. They either have to regenerate wastewater or deal with contaminated surface water. This book brings together the experiences of various experts in preparing of innovative materials that are selective for arsenic and chromium removal, and in
An unmatched reference on electrochemical technologies for soil, sediment, and groundwater pollution remediation Electrochemical technologies are emerging as important approaches for effective and efficient pollution remediation, both on their own and in concert with other remediation techniques. Electrochemical Remediation Technologies for Polluted Soils, Sediments and Groundwater provides a systematic and clear explanation of fundamentals, field applications, as well as opportunities and challenges in developing and implementing electrochemical remediation technologies. Written by leading authorities in their various areas, the text summarizes the latest research and offers case studies that illustrate equipment, installation, and methods employed in real-world remediations. Divided into nine sections, the coverage includes: Introduction and fundamental principles Remediation of heavy metals and other inorganic pollutants Remediation of organic pollutants Remediation of mixed contaminants Electrokinetic barriers Integrated (coupled) technologies Mathematical modeling Economic and regulatory considerations Field applications and performance assessment Unique as a comprehensive reference on the subject, Electrochemical Remediation Technologies for Polluted Soils, Sediments and Groundwater will serve as a valuable resource to all environmental engineers, scientists, regulators, and policymakers.
Only limited information existed about the occurrence of boron and chromium in drinking water sources prior to this project. In addition, chromium speciation in drinking water sources was not well understood. In fact, due to analytical method deficiencies, previous field sampling experiences had resulted in total chromium concentrations less than corresponding hexavalent chromium concentrations. This project specifically addressed the following questions: . What are the analytical method challenges and sensitivities for reliable low-level detection of chromium species and boron in drinking water supplies? . What are the national occurrence patterns for chromium species and boron in drinking water sources? . What is the fate of these compounds through drinking water facilities and distribution systems? The project approach included . an investigation of analytical challenges for both chromium and boron analysis, . a review of existing occurrence data sources, . a design and an implementation of the national occurrence survey, . an analysis of the national occurrence results, and . an investigation of the fate of chromium and boron through drinking water facilities and distribution systems.
This book presents the select proceedings of the International Conference on Sustainable Practices and Innovations in Civil Engineering (SPICE 2019). The chapters discuss emerging and current research in sustainability in different areas of civil engineering, which aim to provide solutions to sustainable development. The contents are broadly divided into the following six categories: (i) structural systems, (ii) environment and water resource systems, (iii) construction technologies, (iv)geotechnical systems, (v) innovative building materials, and (vi) transportation. This book will be of potential interest for students, researchers, and practitioners working in sustainable civil engineering related fields.
This edited book brings together a diverse group of environmental science, sustainability, and health researchers to address the challenges posed by global mass poisoning caused by chromium contamination of soil and plants. In recent years, contamination of the environment by chromium has become a major concern. Chromium is a non-degradable, harmful, and toxic pollutant which negatively affects the environment. It is unique among the heavy metals found in industrial wastewater and sewage and sludge, as it may exist as a trivalent cation and as anion in the hexavalent state in the pH range of agricultural soils. It is used on a large scale in many different industries, including metallurgy, electroplating, production of paints and pigments, tanning, wood preservation, chemical production, and pulp and paper production. These industries are contributing larger amount of chromium, which can ultimately have significant adverse effects on biological and ecological activities of ecosystem. Chromium enters the food chain through consumption of plant material. A high concentration of chromium has been found to be harmful to vegetation. As the chromium concentration in plants increases, it adversely affects several biological parameters and eventually renders the soil barren. The book sheds light on this global environmental issue and proposes solutions to contamination through multi-disciplinary approaches and case studies from different parts of the world. This book is a valuable resource to students, academicians, researchers, and environmental professionals who are doing field work on chromium contamination throughout the world.
This new edition discusses chemical and engineering principles as they apply to the cleanup and removal of hazardous chemicals from soil and groundwater. There is emphasis on environmental chemistry, soil science, microbiology, and plant science. The first part of the book provides an overview of the recent history of environmental contamination and the formulation of relevant regulations for hazardous waste site remediation. This part also provides a background for several salient aspects of site remediation (e.g., soil science, the site assessment process). The second part of the book examines field remediation technologies, including phytoremediation, bioremediation, and several chemical and physical technologies. Theory of operation, practical considerations, and possible environmental impacts and other consequences of their use are discussed. Covers both metal- and hydrocarbon-based contamination and remediation Many competitors only address one industry, or source, of contamination—this title provides an overview of all of the sources. Presents both the assessment of contaminated sites and the technologies currently available for environmental cleanup Effective for use in field situations and for academic (i.e., university course) use. Two new chapters: (i) the use of nanomaterials for remediation of contaminated soil and water; and (ii) revegetation of severely disturbed sites.
This book describes the water sector as it is structured in Italy, presenting innovative engineering, financial and managerial solutions implemented by the Italian water sector, through the experiences of its major stakeholders. The main themes addressed include water regulation, financing infrastructures, economic performance of the leading companies, abstraction, potabilization, distribution, treatment and purification technologies, energy production, and organizational restructuring. The last part of the work presents company profiles with important financial indicators, as well as future strategic postures. Written by leading Italian experts, the book reflects the remarkable advances that have been made in the field of water governance and environmental management. The book is especially valuable for researchers, water professionals, utility managers, as well as policy makers and foreign investors looking for opportunities. This work has been prepared as part of the research activities of the Observatory on Sustainable Water Industry, one of Agici’s Research and Advisory units.