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This book provides an introduction to lattice models of polymers. This is an important topic both in the theory of critical phenomena and the modelling of polymers. The first two chapters introduce the basic theory of random, directed and self-avoiding walks. The next two chapters develop and expand this theory to explore the self-avoiding walk in both two and three dimensions. Following chapters describe polymers near a surface, dense polymers, self-interacting polymers and branched polymers. The book closes with discussions of some geometrical and topological properties of polymers, and of self-avoiding surfaces on a lattice. The volume combines results from rigorous analytical and numerical work to give a coherent picture of the properties of lattice models of polymers. This book will be valuable for graduate students and researchers working in statistical mechanics, theoretical physics and polymer physics. It will also be of interest to those working in applied mathematics and theoretical chemistry.
Integrating coverage of polymers and biological macromolecules into a single text, Physical Chemistry of Macromolecules is carefully structured to provide a clear and consistent resource for beginners and professionals alike. The basic knowledge of both biophysical and physical polymer chemistry is covered, along with important terms, basic structural properties and relationships. This book includes end of chapter problems and references, and also: Enables users to improve basic knowledge of biophysical chemistry and physical polymer chemistry. Explores fully the principles of macromolecular chemistry, methods for determining molecular weight and configuration of molecules, the structure of macromolecules, and their separations.
From the reviews: "...This book is a very useful addition to polymer literature, and it is a pleasure to recommend it to the polymer community." (J.E. Mark, University of Cincinnati, POLYMER NEWS)
This monograph gives a detailed introductory exposition of research results for various models, mostly two-dimensional, of directed walks, interfaces, wetting, surface adsorption (of polymers), stacks, compact clusters (lattice animals), etc. The unifying feature of these models is that in most cases they can be solved analytically. The methods used include transfer matrices, generating functions, recurrence relations, and difference equations, and in some cases involve utilization of less familiar mathematical techniques such as continued fractions and q-series. The authors emphasize an overall view of what can be learned generally of the statistical mechanics of anisotropic systems, including phenomena near surfaces, by studying the solvable models. Thus, the concept of scaling and, where known, finite-size scaling properties are elucidated. Scaling and statistical mechanics of anisoptropic systems in general are active research topics. The volume provides a comprehensive survey of exact model results in this field.
This book offers concise information on the properties of polymeric materials, particularly those most relevant to physical chemistry and chemical physics. Extensive updates and revisions to each chapter include eleven new chapters on novel polymeric structures, reinforcing phases in polymers, and experiments on single polymer chains. The study of complex materials is highly interdisciplinary, and new findings are scattered among a large selection of scientific and engineering journals. This book brings together data from experts in the different disciplines contributing to the rapidly growing area of polymers and complex materials.
Physics of Polymer Surfaces and Interfaces emphasizes current theoretical ideas and modern experimental tools for characterizing the physical properties of polymer surfaces and interfaces. Foremost are their important roles in polymer technology throughthe processes of wetting, adhesion, adsorption, and through their effect on the kinetics of phase separation and mechanical mixing of molten polymers. Each of the 14 chapters in this book stands as a 'mini-review' of a specific subject. This up-to-date compendium of the most significant theoretical and experimental works provides a scientific understanding of the physics of polymer interfaces and surfaces and will aid scientists in planning and interpreting new results.
The International Winter School on Electronic Properties of Polymers Orien tation and Dimensionality of Conjugated Systems, held March 9-16, 1991, in Kirchberg, ('lYrol) Austria, was a sequel to three meetings on similar subjects held there. The 1991 winter school was again organized in cooperation with the "Bundesministerium fUr Wissenschaft und Forschung" in Austria, and with the "Bundesministerium fUr Forschung und Technologie" in the Federal Republic of Germany. The basic idea of the meeting was to provide an opportunity for experienced scientists from universities and industry to discuss their most re cent results and for students and young scientists to become familiar with the present status of research and applications in the field. Like the previous winter schools on polymers, this one concentrated on the electronic structure and potential~ for application of polymers with conjugated double bonds. This time, however, special attention was paid to the effects of orientation and dimensionality. Anisotropy of the electric conductivity in stretch-oriented samples and whether the transport mechanisms are one-, two-, or three-dimensional or might even have a "fractal dimensionality" were there fore central topics. The problem of orientation was extended to systems such as Langmuir-Blodgett films and other layered structures. Accordingly, thin films were the focus of most of the application oriented contributions. Whereas in the previous winter schools discussions on applications dealt with "large volume applications" such as electromagnetic shielding and energy storage, this time "molecular materials for electronics" and prospects of "molecular electronics" were at the center of interest.