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Advances in Spectroscopic Monitoring of the Atmosphere provides a comprehensive overview of cutting-edge technologies and monitoring applications. Concepts are illustrated by numerous examples with information on spectroscopic techniques and applications widely distributed throughout the text. This information is important for researchers to gain an overview of recent developments in the field and make informed selections among the most suitable techniques. This volume also provides information that will allow researchers to explore implementing and developing new diagnostic tools or new approaches for trace gas and aerosol sensing themselves. Advances in Spectroscopic Monitoring of the Atmosphere covers advanced and newly emerging spectroscopic techniques for optical metrology of gases and particles in the atmosphere. This book will be a valuable reference for atmospheric scientists, including those whose focus is applying the methods to atmospheric studies, and those who develop instrumentation. It will also serve as a useful introduction to researchers entering the field and provide relevant examples to researchers and students developing and applying optical sensors for a variety of other scientific, technical, and industrial uses. - Overview of new applications including remote sensing by UAV, laser heterodyne radiometry, dual comb spectroscopy, and more - Features in-situ observations and measurements for real-world data - Includes content on leading edge optical sensors
This book is devoted to the most efficient method of obtaining spectroscopic parameters characterising the absorption of microwave radiation by the Earth’s atmosphere. It explores why this field of science is interesting and important for humanity, and details the basics of gas phase molecular spectroscopy. The book also shows the advantages of the resonator spectroscopy technique for quantitative molecular analysis, and reviews the best-known investigations of diagnostic atmospheric lines and the continuum in the millimetre and submillimetre-wave range. It will appeal to a wide range of specialists in the fields of spectroscopy, atmospheric physics, and millimetre and submillimetre-wave techniques, and will be helpful for lecturers and students concerned with these specialised courses.
The field of optical and laser remote sensing has grown rapidly in recent years. This dynamic growth has been stimulated not only by technological advances in lasers, detectors, and optical system design, but also by the potential application of remote sensing systems to a wide variety of atmo spheric measurements. Optical and laser remote sensing can allow single ended measurement capability not offered by conventional point-detection techniques. While many past measurements have been associated with labo ratory research. practical systems have recently been developed which are capable of remotely detecting. measuring. and tracking a wide range of molecular and atomic species in the atmosphere with concentrations of parts per billion and at ranges over 100 km. This book is a compilation of papers which represent an overview of the present state of development of optical and laser remote sensing tech nology. The subjects covered include both passive and active remote sen sing techniques in the UV, visible, and IR spectral regions. related laser and detector technology, and atmospheric propagation and system analysis considerations. While the papers do not constitute an exhaustive treat ment of the excellent research being conducted in this field, they are representative of the wide diversity of present efforts. It is hoped that the reader will gain a general understanding of the current research in optical and laser remote sensing as well as an overview of current systems development.
Laser-initiated breakdown of N2, 02, and Ar has been investigated st sub-atmospheric pressures using a pulsed (10 ns) Nd:yttrium aluminum garnet (Nd:YAG) laser at 1.06 micrometers. Breakdown thresholds have been determined from 3 to 760 torr and spectral analysis of the plasma emission has been carried out over the range 300-600 nm. Sharp spectral features arising from highly excited singly and multiply charged ions are reported, as well as an underlying continuum at intermediate pressure. Time resolved measurements indicate a complex kinetic dynamic optical behavior. (Author).
Laser spectroscopy is a valuable tool for sensing and chemical analysis. Developments in lasers, detectors and mathematical analytical tools have led to improvements in the sensitivity and selectivity of spectroscopic techniques and extended their fields of application. Laser Spectroscopy for Sensing examines these advances and how laser spectroscopy can be used in a diverse range of industrial, medical, and environmental applications. Part one reviews basic concepts of atomic and molecular processes and presents the fundamentals of laser technology for controlling the spectral and temporal aspects of laser excitation. In addition, it explains the selectivity, sensitivity, and stability of the measurements, the construction of databases, and the automation of data analysis by machine learning. Part two explores laser spectroscopy techniques, including cavity-based absorption spectroscopy and the use of photo-acoustic spectroscopy to acquire absorption spectra of gases and condensed media. These chapters discuss imaging methods using laser-induced fluorescence and phosphorescence spectroscopies before focusing on light detection and ranging, photothermal spectroscopy and terahertz spectroscopy. Part three covers a variety of applications of these techniques, particularly the detection of chemical, biological, and explosive threats, as well as their use in medicine and forensic science. Finally, the book examines spectroscopic analysis of industrial materials and their applications in nuclear research and industry. The text provides readers with a broad overview of the techniques and applications of laser spectroscopy for sensing. It is of great interest to laser scientists and engineers, as well as professionals using lasers for medical applications, environmental applications, military applications, and material processing. - Presents the fundamentals of laser technology for controlling the spectral and temporal aspects of laser excitation - Explores laser spectroscopy techniques, including cavity-based absorption spectroscopy and the use of photo-acoustic spectroscopy to acquire absorption spectra of gases and condensed media - Considers spectroscopic analysis of industrial materials and their applications in nuclear research and industry
This work describes experimental techniques using laser spectroscopy and presents specific practical applications for this technology in many fields, including physics, engineering, chemistry, medicine and bioscience. The general spectroscopic features of molecules are delineated; transition metal and rare earth complexes are examined; and transition selection rules are explained.
Leading experts discuss the characteristics, advantages, limitations and future aspects of modern spectroscopic techniques for environmental analysis. Demonstrates how these methods can be applied to trace gas detection and assessment. Concentrates on the latest techniques--both laser and non-laser based--which offer advantages for air pollution and gas monitoring as opposed to more conventional methods. Numerous examples of applications illustrate the potential of the techniques backed up by cutting-edge information and representative data.
This book presents a comprehensive overview of the modern theory of spectral line broadening and shifting by pressure of atmospheric gases. It describes current semi-classical methods for calculating vibrotational line widths and shifts, including very recent modifications and new developments realised by the authors themselves. For most of the considered molecular systems, analytical formulae are also given, which enable the calculation of line broadening coefficients without the use of semi-classical methods. The results of calculations by various approaches are compared with experimental data available in the literature. Numerous appendices list theoretical expressions and parameters' values required for the writing of computer programs for calculation of line broadening and line shifting coefficients.The book is addressed to undergraduate and postgraduate students as well as to professional scientists and researchers working in the field of molecular physics, molecular spectroscopy, quantum chemistry and mathematical physics.
By now it has been nearly twenty years since the pioneering studies at the MIT-Lincoln Laboratories, Lexington, USA, demonstrated the unique capabilities of lead salt tunable diode lasers (TDL) for infrared absorption spectroscopy. The progress in the use of TDL instrumentation for a wide variety of scientific applications was described by a great number of papers since, however, comparatively few meetings were specifically devoted to this subject. In 1980 the conference on "High Resolution Infrared Spectroscopy Applications and Developments" at the National Bureau of Standards in Gaithersburg, USA, reviewed the state of the art of tunable diode lasers together with Fourier Transform Spectroscopy and other laser spectroscopic techniques. Three years later in 1983 the SPIE Conference in San Diego, USA, dedicated one meeting to "Tunable Diode Laser Development and Spectroscopy" Applications. It appeared appropriate after a further interval of three years to organize another meeting about this quickly advancing field. In November of 1986 an International Symposium on "Monitoring of Gaseous Pollutants by Tunable Diode Lasers" was organized by and held at the Fraunhofer-Insti tut fuer Physikalische Messtechnik in Freiburg, FRG. The main emphasis of this conference was put on the applications of TDL techniques to the solution of problems of environmental relevance : The measurement of atmospheric trace gases and the monitoring of exhaust gases from automobile and power plant stack emitters. The state of diode laser development and application of TDL instruments to scientific molecular spectroscopy were not directly subjects of the meeting.
Keeping abreast of the latest techniques and applications, this new edition of the standard reference and graduate text on laser spectroscopy has been completely revised and expanded. While the general concept is unchanged, the new edition features a broad array of new material. This new edition has been completely revised, especially the chapters on non linear spectroscopy, ion trapping, ultra short laser pulses and new developments. Fifty new figures illustrate the newest developments and results. The author is one of the most renowned experts in this area and no other book with this broad scope is available.