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Proceedings of the NATO Advanced Study Institute, Erice, Sicily, Italy, June 19-29, 1995
With the central importance of electric polarizability and hyperpolarizability for a wide spectrum of activities, this book charts the trends in the accurate theoretical determination of these properties in specialized fields. The contributions include reviews and original papers that extend from methodology to applications in specific areas of primary importance such as cluster science and organic synthesis of molecules with specific properties.
Clusters of Atoms and Molecules I is devoted to theoretical concepts and experimental techniques important in the rapidly expanding field of cluster science. Cluster properties are dicussed for clusters composed of alkali metals, semiconductors, transition metals, carbon, oxides and halides of alkali metals, rare gases, and neutral molecules. The book contains several well-integrated treatments, all prepared by experts. Each contribution starts out as simple as possible and ends with the latest results, so that the book can serve as a text for a course, an introduction into the field, or as a reference book for the expert.
Atomic clusters are aggregates of atoms containing a few to several thousand atoms. Due to the small size of these pieces of matter, the properties of atomic clusters in general are different from those of the corresponding material in the macroscopic bulk phase. This monograph presents the main developments of atomic clusters and the current status of the field. The book treats different types of clusters with very different properties: clusters in which the atoms or molecules are tied by weak van der Waals interactions, metallic clusters, clusters of ionic materials, and network clusters made of typical covalent elements. It includes methods of experimental cluster synthesis as well as the structural, electronic, thermodynamic and magnetic properties of clusters, covering both experiments and the theoretical work that has led to our present understanding of the different properties of clusters. The question of assembling nanoclusters to form solids with new properties is also considered. Having an adequate knowledge of the properties of clusters can be of great help to any scientist working with objects of nanometric size. On the other hand, nanoclusters are themselves potentially important in fields like catalysis and nanomedicine.
This book provides an introduction to many-body methods for applications in quantum chemistry. These methods, originating in field-theory, offer an alternative to conventional quantum-chemical approaches to the treatment of the many-electron problem in molecules. Starting with a general introduction to the atomic and molecular many-electron problem, the book then develops a stringent formalism of field-theoretical many-body theory, culminating in the diagrammatic perturbation expansions of many-body Green's functions or propagators in terms of Feynman diagrams. It also introduces and analyzes practical computational methods, such as the field-tested algebraic-diagrammatic construction (ADC) schemes. The ADC concept can also be established via a wave-function based procedure, referred to as intermediate state representation (ISR), which bridges the gap between propagator and wave-function formulations. Based on the current rapid increase in computer power and the development of efficient computational methods, quantum chemistry has emerged as a potent theoretical tool for treating ever-larger molecules and problems of chemical and physical interest. Offering an introduction to many-body methods, this book appeals to advanced students interested in an alternative approach to the many-electron problem in molecules, and is suitable for any courses dealing with computational methods in quantum chemistry.
This book completes the physical foundations and experimental techniques described in volume 1 with an updated review of the accessory equipment indispensable in molecular beam experiments. It extends the subject to cluster beams and beams of hyperthermal and subthermal energies. As in volume 1, a special effort is made to outline the physical foundations of the various experimental techniques. Hence this book is intended not only as a reference standard for researchers in the field, but also to bring the flavor of current molecular beam research to advanced undergraduates and graduate students and to enable them to gain a solid background in the field and its technique.
A consistent, up-to-date description of the extremely manifold and varied experimental techniques which nowadays enable work with neutral particles. Th book lays the physical foundations of the various experimental techniques, which utilize methods from most fields in physics.
Find out all about atoms, what they are and where they come from - and how these tiny particles combine to make up EVERYTHING in the universe (including you). Packed with intriguing facts, this is an entertaining and accessible introduction to key scientific ideas. Part of Usborne's bestselling "See Inside" lift-the-flap non-fiction series, which includes over 40 titles. With beautiful full-colour illustrations and fascinating details to discover on every page. Written in consultation with an expert chemist.
This book provides a comprehensive survey of modern molecular astrophysics. It includes an introduction to molecular spectroscopy and then addresses the main areas of current molecular astrophysics, including galaxy formation, star forming regions, mass loss from young as well as highlyevolved stars and supernovae, starburst galaxies plus the tori and discs near the central engines of active galactic nuclei. All chapters have been written by invited authors who are acknowledged experts in their fields. The thorough editorial process has ensured a uniformly high standard ofexposition and a coherent style. The book is unique in giving a detailed view of its wide-ranging subject. It will provide the standard introduction for research students in molecular astrophysics. The book will be read by research astronomers and astrophysicists who wish to broaden the basis oftheir knowledge or are moving their activities into this burgeoning field. It will enable chemists to learn the astrophysics most related to chemistry as well as instruct physicists about the molecular processes most important in astronomy.