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This report presents a cost analysis of Itaconic Acid production from dimethyl succinate (DMS) and formaldehyde. The process examined is based on a catalytic condensation. In this process, succinic acid is generated as by-product. This report was developed based essentially on the following reference(s): US Patent 6664417, issued to Board of Trustees of Michigan State University in 2003 Keywords: Methylenesuccinic Acid, Succinic Acid Methyl Ester, Succinic Anhydride, Formalin, Citraconate, Citraconic Anhydride
This report presents a cost analysis of Itaconic Acid production from dimethyl succinate (DMS) and formaldehyde The process examined is based on a catalytic condensation. In this process, succinic acid is generated as by-product. This report was developed based essentially on the following reference(s): US Patent 6664417, issued to Board of Trustees of Michigan State University in 2003 Keywords: Methylenesuccinic Acid, Succinic Acid Methyl Ester, Succinic Anhydride, Formalin, Citraconate, Citraconic Anhydride
This report presents a cost analysis of Sebacic Acid production from castor oil and sodium hydroxide. The process examined is a typical caustic oxidation process. This report was developed based essentially on the following reference(s): Keywords: Decanedioic Acid, Dicarboxylic Acid, 1,8-Octanedicarboxylic Acid
This report presents a cost analysis of polymer grade (PG) Ethylene production starting from an ethane/propane mixture at a volume ratio of 4:1. A typical steam cracking process with front-end demethanization is employed. In this process, a mix of 80 vol% ethane and 20 vol% propane is thermally cracked in pyrolysis furnaces. In addition to polymer grade Ethylene, the process also generates polymer grade propylene and hydrogen-rich gas. This report was developed based essentially on the following reference(s): "Ethylene", Ullmann's Encyclopedia of Industrial Chemistry, 7th edition Keywords: Ethene, Propene, Hydrocarbon Pyrolysis, Cracking Furnace, Lummus, KBR, Technip, Linde, S&W
This report presents a cost analysis of Acetic Acid production from acetaldehyde and oxygen The process examined is a typical liquid-phase oxidation process. In this process, the oxidation occurs with manganous acetate as catalyst. Unreacted acetaldehyde is condensed and recycled back to the reactor. The liquid product is sent to a set of distillation columns to recover the Acetic Acid. This report was developed based essentially on the following reference(s): Keywords: Ethanoic Acid, Ethanal, Oxidation Reaction, Liquid-Phase Oxidation, Air
This report presents a cost analysis of Polyacrylonitrile (PAN) Precursor production. In this process, acrylonitrile is polymerized with methyl acrylate comonomer via aqueous dispersion polymerization and the polymer formed is subsequently converted to fiber through wet spinning. This report was developed based essentially on the following reference(s): (1) "Acrylic Fibers," Encyclopedia of Polymer Science and Technology (2) Morgan, P., Carbon Fibers and Their Composites, 2005 Keywords: Polyacrylonitrile, Carbon Fiber, Acrylic Fiber, Suspension Polymerization, Acrylonitrile, Wet Spinning
This report presents a cost analysis of 11-Aminoundecanoic Acid production from castor oil. The process examined is similar to the one owned by Arkema. This report was developed based essentially on the following reference(s): Keywords: Nylon-11, Polyamide 11, PA11, Rilsan, Arkema, Atochem
This report presents a cost analysis of Salicylic Acid production from phenol, sodium hydroxide, carbon dioxide, and sulfuric acid. In the process, sodium phenolate is prepared by reacting phenol and aqueous sodium hydroxide. The solution is heated, evaporated, and then reacted with carbon dioxide, producing sodium salicylate, which is further acidified with sulfuric acid producing Salicylic Acid. This report was developed based essentially on the following reference(s): Keywords: SA, 2-Hydroxybenzoic Acid, Monohydroxybenzoic Acid
This book is a compilation of selected papers from the 3rd International Petroleum and Petrochemical Technology Conference (IPPTC 2019). The work focuses on petroleum & petrochemical technologies and practical challenges in the field. It creates a platform to bridge the knowledge gap between China and the world. The conference not only provides a platform to exchanges experience but also promotes the development of scientific research in petroleum & petrochemical technologies. The book will benefit a broad readership, including industry experts, researchers, educators, senior engineers and managers.
This booklet is designed to bridge the gap between handbooks and technical literature and aims at graduate students or experienced readers. Commercial flow sheeting simulation software is increasingly available and is used in the early steps of process design in industry. As to this, more sophisticated and precise models based on activities instead of concentrations should be used. After an introductory chapter there is in Chapter 2 an intensive discussion of reactive phase equilibria of ionic and non-ionic solutes based on chemical potentials. Chapter 3 introduces to multicomponent diffusion and mass transfer. However, the main focus is on the reactive mass transfer on rigid and mobile surfaces where the interfacial reaction, molecular diffusion and adsorption layers are decisive. The respective extraction of zinc with a cation exchanger and of acetic acid with an anion exchanger is discussed as case studies. Since adsorption layers and surfactants have a major impact on liquid-liquid extraction efficiency, the final chapter reviews several tech niques which make use of polymeric species in an extractive process. A short review is also given on extraction apparatus and the hydrodynamics (hydraulic design, droplet populance balances) of columns. Much of the booklet is based on the PhD works of C. Czapla (2000), G. Modes (2000), H. Klocker (1996), T. Kronberger (1995), M. Marters (2000), M. Roos (2000), M. Traving (2000) and B. Wachter (1996) who I wish to thank for their fruitful contributions.