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The efficacy of isocyanide reactions in the synthesis of natural or naturallike products has resulted in a renaissance of isocyanide chemistry. Now isocyanides are widely used in different branches of organic, inorganic, coordination, combinatorial and medicinal chemistry. This invaluable reference is the only book to cover the topic in such depth, presenting all aspects of synthetic isonitrile chemistry. The highly experienced and internationally renowned editor has brought together an equally distinguished team of authors who cover multicomponent reactions, isonitriles in total synthesis, isonitriles in polymer chemistry and much more.
The section devoted to iron in this volume reflects the tremendous progress in the area. Specifically cluster chemistry, ligand transformations and detailed structural results are more prominent in COMC II. The organic chemistry of ruthenium and osmium is an area which has burgeoned during the period since the publication of COMC. This is especially true for the cluster chemistry of these elements, which have provided most of the advances in this important field. Consequently, this volume will include an update (1981-1993) of the chemistry of mono- and bi-nuclear complexes of ruthenium and osmium, with a rather more extensive treatment of tri- and tetra-nuclear complexes. This is because many of the early results in ruthenium and osmium cluster chemistry described in COMC are now much better understood and can thus be placed in a more general context. In the case of complexes containing clusters with five or more metal atoms, the coverage is essentially complete, again because this chemistry has developed during the 1980s.
The Chemistry of Ruthenium, Rhodium, Palladium, Osmium, Iridium and Platinum
Organic Chemistry, Volume 20: Isonitrile Chemistry discusses the fundamental aspects of the chemistry of isonitriles. This book provides an introduction to as well as a thorough coverage of isonitrile chemistry. Organized into 10 chapters, this volume begins with an overview of the general properties and structure of isonitriles. This text then examines the quantitative study of the kinetics of isonitrile rearrangement as well as the principal resonance structure of the isonitrile molecule. Other chapters consider the experimental and theoretical findings on the fall-off behavior of the unimolecular rate constants of different isonitriles with pressure. This book discusses as well the behavior of isonitriles toward a center of low electron density, which is particularly manifested in the reactivity of alkyl and aryl isonitriles toward diborane and alkyl or arylboranes. The final chapter deals with the inorganic coordination chemistry of isonitriles. This book is a valuable resource for organic chemists.
In this comprehensive book, one of the leading experts, Shun-Ichi Murahashi, presents all the important facets of modern synthetic chemistry using Ruthenium, ranging from hydrogenation to metathesis. In 14 contributions, written by an international authorship, readers will find all the information they need about this fascinating and extraordinary chemistry. The result is a high quality information source and a indispensable reading for everyone working in organometallic chemistry. From the contents: Introduction (S.-I. Murahashi) Hydrogenation and Transfer Hydrogenation (M. Kitamura and R. Noyori) Oxidations (S.-I. Murahashi and N. Komiya) Carbon-Carbon Bond Formations via Ruthenacycle Intermediates (K. Itoh) Carbon-Carbon Bond Formation via pi-Allylruthenium Intermediates (T. Mitsudo) Olefin Metathesis (R. H. Grubbs) Cyclopropanation (H. Nishiyama) Nucleophilic Addition to Alkynes and Reactions via Vinylidene Intermediates (P. Dixneuf) Reactions via C-H Activation (N. Chatani) Lewis Acid Reactions (E. P. Kundig) Reactions with CO and CO2 (T. Mitsudo) Isomerization of Organic Substrates Catalyzed by Ruthenium Complexes (H. Suzuki) Radical Reactions (H. Nagashima) Bond Cleavage Reactions (S. Komiya)
Advances in Organometallic Chemistry
This workshop comprises part of the four-year (1985-1988) non-nuclear energy R & D programme for the development of renewable energy sources which is being implemented by the Commission of the European Communities. The aim of the workshop was to present work by the contracting laboratories in addition to work by numerous other research laboratories in 11 European countries. Extensive discussions were also held on the present state of this basic, directed research in photochemistry, photoelectrochemistry and photobiology, and where the future emphasis may usefully lie. Thus the book presents the proceedings of all the papers presented and summarizes the recommendations made by the participants as to where future research support may be most effectively placed. It was emphasized in these recommendations that the interdisciplinary collaboration between photochemistry and photobiology had been quite successfully achieved in this European programme. There were both high quality basic research and practical benefits accruing from the work, and these are described in the report on proposed areas for future research. This book contains work reported by 30 leading researchers and laboratories in Europe. The contents parallels and overlaps research in photovoltaics and semiconductors and therefore provides a unique link and basis of information across the field of photovoltaics, semiconductors and photosynthesis.
Annual Reports in Inorganic and General Syntheses–1975 presents an annual review of synthetically useful information that would prove beneficial to nearly all organic chemists, both specialist and nonspecialist in synthesis. It should help relieve some of the information storage burden of the specialist and should aid the nonspecialist who is seeking help with a specific problem to become rapidly aware of recent synthetic advances. This is the fourth volume of "ARIGS" and is organized along the lines used for the last volume. The authors were encouraged to use synthetic aspects as their primary guideline for the arrangement and preservation of the information; however, an occasional deviation to include structural or mechanistic features seemed to be justified in order to reflect the particular features of a given element's chemistry. Complex hydrides were dealt with under the particular elements. As a consequence there is no chapter on simple and complex metal hydrides of main groups I, II, and III in the present volume. As in previous issues of ARIGS, this volume presents an article of a timely subject of special interest. This year's special feature is the "Synthesis of Radiopharmaceuticals by the Reduction of 99m TcO4-."