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Over the years, the uses and applications of various non-conventional solvents such as ionic liquids, deep eutectic solvents, crown ethers, fluorinated solvents, glycols, glycerol etc diversified in various fields. This book consists of nine chapters, which present recent advances and outlook on various non-conventional solvents in organic transformations. Comparison between traditional solvents and non-conventional solvents are also highlighted in this book.
This introductory textbook on supramolecular chemistry is a thoroughly revised and expanded version of the 1st edition, originally published in 2020. All chapters have been brought up to date and now include "Further Reading" sections that highlight relevant developments. In addition, a new chapter on supramolecular polymers has been added. With these changes, this book provides an even more comprehensive introduction to the exciting field of supramolecular chemistry than before. Readers will learn what forces hold supramolecular architectures together, how supramolecular systems are created and characterized, how molecular switches, motors, transporters, catalysts, chemosensors, and other functional systems work, and where supramolecular chemistry can play or already plays a role in our lives. In 2022 the first edition of this book won the Literature Prize of the German Chemical Industry Association VCI. For the full press release (in German): https://www.vci.de/fonds/presse-und-infos/pressemitteilungen/preisgeld-fuer-supramolekuele.jsp
Over the years, applications of various non-conventional solvents diversified in various fields such as organic synthesis, natural products, drug design, pharmaceuticals, dyes and agrochemical industries. This book consists of nine chapters, which present recent advances and applications of various non-conventional solvents in organic transformations, drug design and bioremediation. Environmental impacts of non-conventional solvents and comparison between traditional solvents and non-conventional solvents are also discussed in this book.
A useful guide to the fundamentals and applications of deep eutectic solvents Deep Eutectic Solvents contains a comprehensive review of the use of deep eutectic solvents (DESs) as an environmentally benign alternative reaction media for chemical transformations and processes. The contributors cover a range of topics including synthesis, structure, properties, toxicity and biodegradability of DESs. The book also explores myriad applications in various disciplines, such as organic synthesis and (bio)catalysis, electrochemistry, extraction, analytical chemistry, polymerizations, (nano)materials preparation, biomass processing, and gas adsorption. The book is aimed at organic chemists, catalytic chemists, pharmaceutical chemists, biochemists, electrochemists, and others involved in the design of eco-friendly reactions and processes. This important book: -Explores the promise of DESs as an environmentally benign alternative to hazardous organic solvents -Covers the synthesis, structure, properties (incl. toxicity) as well as a wide range of applications -Offers a springboard for stimulating critical discussion and encouraging further advances in the field Deep Eutectic Solvents is an interdisciplinary resource for researchers in academia and industry interested in the many uses of DESs as an environmentally benign alternative reaction media.
This book summarizes the latest knowledge in the science and technology of ionic liquids and polymers in different areas. Ionic liquids (IL) are actively being investigated in polymer science and technology for a number of different applications. In the first part of the book the authors present the particular properties of ionic liquids as speciality solvents. The state-of-the art in the use of ionic liquids in polymer synthesis and modification reactions including polymer recycling is outlined. The second part focuses on the use of ionic liquids as speciality additives such as plasticizers or antistatic agents. The third part examines the use of ionic liquids in the design of functional polymers (usually called polymeric ionic liquids (PIL) or poly(ionic liquids)). Many important applications in diverse scientific and industrial areas rely on these polymers, like polymer electrolytes in electrochemical devices, building blocks in materials science, nanocomposites, gas membranes, innovative anion sensitive materials, smart surfaces, and a countless set range of emerging applications in different fields such as energy, optoelectronics, analytical chemistry, biotechnology, nanomedicine or catalysis.
This set of two books dedicated to presenting the latest novel and advanced research from around the world in this exciting area. These books highlight the important properties of electrochemistry in ionic liquids – as opposed to the more commonly used aqueous and organic environments – and the many applications. Readers will find 20 chapters gathered in two books: The first volume critically discusses electrode-electrolyte interfacial processes, reference electrodes, ultramicroelectrode voltammetry and scanning electrochemical microscopy, semi-integral and convolution voltammetry, and small-angle X-ray scattering coupled with voltammetry. The structure and properties of protic ionic liquids, deep-eutectic solvents, task-specific ionic liquids, polymeric ion gels, and lithium-ion solvation, useful for electrochemical application is also critically discussed The second volumes major topics covered in this book include electrodeposition and electroless deposition, voltammetry of adhered microparticles, electrochemistry of organic and organometallic compounds, electrocatalytic reactions, oxygen reduction reaction, ionic liquids in surface protection and lubrication, current industrial application of ionic liquids, and challenges, issues and recycling methods of ionic liquids in industrial developments.
This volume describes the most recent findings on the structure of ILs interpreted through cutting-edge experimental and theoretical methods. Research in the field of ionic liquids (ILs) keeps a fast and steady pace. Since these new-generation molten salts first appeared in the chemistry and physics landscape, a large number of new compounds has been synthesized. Most of them display unexpected behaviour and possess stunning properties. The coverage in this book ranges from the mesoscopic structure of ILs to their interaction with proteins. The reader will learn how diffraction techniques (small and large angle X-Ray and neutron scattering, powder methods), X-Ray absorption spectroscopies (EXAFS/XANES), optical methods (IR, RAMAN), NMR and calorimetric methods can help the study of ILs, both as neat liquids and in mixtures with other compounds. It will enable the reader to choose the best method to suit their experimental needs. A detailed survey of theoretical methods, both quantum-chemical and classical, and of their predictive power will accompany the exposition of experimental ones. This book is a must read for postgraduate students, for post-docs, and for researchers who are interested in understanding the structural properties of ILs.
The conventional solvents used in chemical, pharmaceutical, biomedical and separation processes represent a great challenge to green chemistry because of their toxicity and flammability. Since the beginning of “the 12 Principles of Green Chemistry” in 1998, a general effort has been made to replace conventional solvents with environmentally benign substitutes. Water has been the most popular choice so far, followed by ionic liquids, surfactant, supercritical fluids, fluorous solvents, liquid polymers, bio-solvents and switchable solvent systems. Green Solvents Volume I and II provides a throughout overview of the different types of solvents and discusses their extensive applications in fields such as extraction, organic synthesis, biocatalytic processes, production of fine chemicals, removal of hydrogen sulphide, biochemical transformations, composite material, energy storage devices and polymers. These volumes are written by leading international experts and cover all possible aspects of green solvents’ properties and applications available in today’s literature. Green Solvents Volume I and II is an invaluable guide to scientists, R&D industrial specialists, researchers, upper-level undergraduates and graduate students, Ph.D. scholars, college and university professors working in the field of chemistry and biochemistry.
Annotation FollowingIonic Liquids: Industrial Applications to Green Chemistry, SS #818, by the same editors, this book focuses on exciting new developments in ionic liquids.