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Many areas of physics research depend upon a good physical understanding of charged particle transport processes in gases, a statement which is as true now as it was in the early part of the last century, when modern physics was taking shape. Gas lasers, multi-wire drift chambers used in high energy particle detectors, muon-catalysed fusion in hydrogen and its isotopes and low-temperature plasma processing technology are just a few examples of experiments and processes in which electrons, ions or muons play a key role. The macroscopic properties of these non-equilibrium systems can best be found by averaging microscopic collision properties over a velocity distribution function, calculated from solution of Boltzmann's kinetic equation, using recently developed techniques. This is the realm of the modern kinetic theory of gases, and is the theme of this book.
Many areas of physics research depend upon a good physical understanding of charged particle transport processes in gases, a statement which is as true now as it was in the early part of the last century, when modern physics was taking shape. Gas lasers, multi-wire drift chambers used in high energy particle detectors, muon-catalysed fusion in hydrogen and its isotopes and low-temperature plasma processing technology are just a few examples of experiments and processes in which electrons, ions or muons play a key role. The macroscopic properties of these non-equilibrium systems can best be found by averaging microscopic collision properties over a velocity distribution function, calculated from solution of Boltzmann's kinetic equation, using recently developed techniques. This is the realm of the modern kinetic theory of gases, and is the theme of this book.
This book offers a comprehensive and cohesive overview of transport processes associated with all kinds of charged particles, including electrons, ions, positrons, and muons, in both gases and condensed matter. The emphasis is on fundamental physics, linking experiment, theory and applications. In particular, the authors discuss: The kinetic theory of gases, from the traditional Boltzmann equation to modern generalizations A complementary approach: Maxwell’s equations of change and fluid modeling Calculation of ion-atom scattering cross sections Extension to soft condensed matter, amorphous materials Applications: drift tube experiments, including the Franck-Hertz experiment, modeling plasma processing devices, muon catalysed fusion, positron emission tomography, gaseous radiation detectors Straightforward, physically-based arguments are used wherever possible to complement mathematical rigor. Robert Robson has held professorial positions in Japan, the USA and Australia, and was an Alexander von Humboldt Fellow at several universities in Germany. He is a Fellow of the American Physical Society. Ronald White is Professor of Physics and Head of Physical Sciences at James Cook University, Australia. Malte Hildebrandt is Head of the Detector Group in the Laboratory of Particle Physics at the Paul Scherrer Institut, Switzerland.
This book is about the drift, diffusion, and reaction of ions moving through gases under the influence of an external electric field, the gas temperature, and the number density. While this field was established late in the 19th century, experimental and theoretical studies of ion and electron swarms continue to be important in such varied fields as atomic and molecular physics, aeronomy and atmospheric chemistry, gaseous electronics, plasma processing, and laser physics. This book follows in the rigorous tradition of well-known older books on the subject, while at the same time providing a much-needed overview of modern developments with a focus on theory. Graduate students and researchers new to this field will find this book an indispensable guide, particularly those involved with ion mobility spectrometry and the use of ion transport coefficients to test and improve ab initio ion-neutral interaction potentials. Established researchers and academics will find in this book a modern companion to the classic references.
Over the last decade, scientific and engineering interests have been shifting from conventional ion mobility spectrometry (IMS) to field asymmetric waveform ion mobility spectrometry (FAIMS). Differential Ion Mobility Spectrometry: Nonlinear Ion Transport and Fundamentals of FAIMS explores this new analytical technology that separates and characterizes ions by the difference between their mobility in gases at high and low electric fields. It also covers the novel topics of higher-order differential IMS and IMS with alignment of dipole direction. The book relates the fundamentals of FAIMS and other nonlinear IMS methods to the physics of gas-phase ion transport. It begins with the basics of ion diffusion and mobility in gases, covering the main attributes of conventional IMS that are relevant to all IMS approaches. Building on this foundation, the author reviews diverse high-field transport phenomena that underlie differential IMS. He discusses the conceptual implementation and first-principles optimization of FAIMS as a filtering technique, emphasizing the dependence of FAIMS performance metrics on instrumental parameters and properties of ion species. He also explores ion reactions in FAIMS caused by field heating and the effects of inhomogeneous electric field in curved FAIMS gaps. Written by an accomplished scientist in the field, this state-of-the-art book supplies the foundation to understand the new technology of nonlinear IMS methods.
Since the discovery of X-rays and radioactivity, ionizing radiations have been widely applied in medicine both for diagnostic and therapeutic purposes. The risks associated with radiation exposure and handling led to the parallel development of the field of radiation protection. Pioneering experiments done by Sanche and co-workers in 2000 showed that low-energy secondary electrons, which are abundantly generated along radiation tracks, are primarily responsible for radiation damage through successive interactions with the molecular constituents of the medium. Apart from ionizing processes, which are usually related to radiation damage, below the ionization level low-energy electrons can induce molecular fragmentation via dissociative processes such as internal excitation and electron attachment. This prompted collaborative projects between different research groups from European countries together with other specialists from Canada, the USA and Australia. This book summarizes the advances achieved by these research groups after more than ten years of studies on radiation damage in biomolecular systems. An extensive Part I deals with recent experimental and theoretical findings on radiation induced damage at the molecular level. It includes many contributions on electron and positron collisions with biologically relevant molecules. X-ray and ion interactions are also covered. Part II addresses different approaches to radiation damage modelling. In Part III biomedical aspects of radiation effects are treated on different scales. After the physics-oriented focus of the previous parts, there is a gradual transition to biology and medicine with the increasing size of the object studied. Finally, Part IV is dedicated to current trends and novel techniques in radiation reserach and the applications hence arising. It includes new developments in radiotherapy and related cancer therapies, as well as technical optimizations of accelerators and totally new equipment designs, giving a glimpse of the near future of radiation-based medical treatments.
Describes the fundamentals and applications of gaseous radiation detection, ideal for researchers and experimentalists in nuclear and particle physics.
Progress in International Research on Thermodynamic and Transport Properties covers the proceedings of the 1962 Second Symposium by the same title, held at Purdue University and the Thermophysical Properties Research Center. This symposium brings together theoretical and experimental research works on the thermodynamic and transport properties of gases, liquids, and solids. This text is organized into nine parts encompassing 68 chapters that cover topics from thixotropy to molecular orbital calculations. The first three parts review papers on theoretical, experimental, and computational studies of the various aspects of thermodynamic properties. These parts discuss the principles of phase equilibria, throttling, volume heat capacity, steam, volumetric behavior, enthalpy, and density. The subsequent part highlights the theoretical evaluations of transport properties, such as viscosity, diffusion, and conductivity, as well as the transport processes. These topics are followed by surveys of the theories in intermolecular forces and their applications. Other parts consider the measurement of thermal conductivity, viscosity, and radiation. The final parts examine the properties of ionized gases and non-Newtonian fluids. This book will prove useful to mechanical and chemical engineers.