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There remains a lack of understanding of environmental isotopes and their use; students and practitioners typically find the concepts of isotope concentrations and partitioning to be more complicated than for geochemistry. However, this need not be so, if the basics are presented together with geochemistry, using case studies and examples to make the point. This new book presents the basics of environmental isotopes and geochemistry together, with case studies and simple examples that build a real understanding of their use in natural and contaminated groundwater.
To understand hydrochemistry and to analyze natural as well as man-made impacts on aquatic systems, hydrogeochemical models have been used since the 1960’s and more frequently in recent times. Numerical groundwater flow, transport, and geochemical models are important tools besides classical deterministic and analytical approaches. Solving complex linear or non-linear systems of equations, commonly with hundreds of unknown parameters, is a routine task for a PC. Modeling hydrogeochemical processes requires a detailed and accurate water analysis, as well as thermodynamic and kinetic data as input. Thermodynamic data, such as complex formation constants and solubility-products, are often provided as databases within the respective programs. However, the description of surface-controlled reactions (sorption, cation exchange, surface complexation) and kinetically controlled reactions requires additional input data. Unlike groundwater flow and transport models, thermodynamic models, in principal, do not need any calibration. However, considering surface-controlled or kinetically controlled reaction models might be subject to calibration. Typical problems for the application of geochemical models are: • speciation • determination of saturation indices • adjustment of equilibria/disequilibria for minerals or gases • mixing of different waters • modeling the effects of temperature • stoichiometric reactions (e.g. titration) • reactions with solids, fluids, and gaseous phases (in open and closed systems) • sorption (cation exchange, surface complexation) • inverse modeling • kinetically controlled reactions • reactive transport Hydrogeochemical models depend on the quality of the chemical analysis, the boundary conditions presumed by the program, theoretical concepts (e.g.
In Europe, ca. 1900 "mineral water" brandsare officially registered and bottled for drinking. Bottled waters isgroundwater and is in large parts of the continent rapidly developing into themain supply of drinking water for the general population.This book is the first state of the art overview of the chemistry ofgroundwaters from 40 European countries from Portugal to Russia, measured on1785 bottled water samples, equivalent to 1189 distinct bottled water brandsfrom 1247 wells in 884 locations plus an additional 500 tap water samplesacquired in 2008 by the network of EuroGeoSurveys experts all across Europe.In contrast to previously available compilations, all chemical data (containedon the enclosed CD) were measured in a single laboratory, under strict qualitycontrol with high internal and external reproducibility, affording a singlehigh quality, internally consistent dataset. More than 70 parameters weredetermined on every sample using state of the art analytical techniques withultra low detection limits (ICPMS, ICPOES, IC) at a single hydrochemical labfacility. Because of the wide geographical distributionof the water sources across 40 European countries, the bottled mineral,drinking and tap waters characterized herein may be used for obtaining a firstestimate of "ground- water geochemistry" at the scale of the EuropeanContinent, previously unavailable in this completeness, quality and coverage.The data published here allow for the first time to present a comprehensiveinternally consistent, overview of the natural distribution and variation ofthe determined chemical elements and additional state parameters of groundwaterat the European scale. Most elements show a very widerange, usually 3 to 4 but up to 7 orders of magnitude, of natural variation of their concentration. Data are interpreted in terms of their origin, considering hydrochemical parameters, such as the influence of soil, vegetation cover and mixing with deep waters, as well as other factors (bottling effects, leaching from bottles). A chapter is devoted to comparing the results from the bottled waters with those of European tap waters and previously published datasets. The authors also provide an overview of the legal framework, that any bottled water sold in the European Union must comply with. It provides a comprehensive compilation of current drinking water action levels in European countries, limiting values of the European Drinking/Mineral/Natural Mineral Water directives (1998/83/EC, 2003/40/EC, 2009/54/EC) and legislation in effect in 26 individual European Countries, and for comparison those of the FAO and in effect in the US (EPA, maximum contaminant levels [MCA]). The accompanying CD contains the extensive data sets, sample data (of 1189 different brands) and two previously published European water chemistry data sets.
This book is a result of the Priority Programme 546 run by the Deutsche Forschungsgemeinschaft. It presents the various ideas, concepts and conclusions that resulted from this Programme on the subject of geochemical processes with long-term effects in anthropogenically influenced drainage and ground water.
Offers a comprehensive volume discussing groundwater problems in coastal areas, spanning fundamental science to practical water management.
Geochemical Techniques for Identifying Sources of Ground-Water Salinization offers a comprehensive look at the threat to the United States' freshwater resources due to salinization and outlines techniques that can be used to study the problem. The book reviews the seven major salt-water sources that commonly mix and deteriorate our fresh ground water (natural saline ground water, halite solution, sea-water intrusion, oil- and gas-field brines, agriculture effluents, saline seep, and road salting). Other topics covered are the characteristics of saltwater sources, geochemical parameters, and basic graphical and statistical methods that are frequently used in saltwater studies. The book also provides geographical charts showing the distribution of the major salt-water sources, illustrating which ones are potential sources in any given area in the United States.Geochemical Techniques for Identifying Sources of Ground-Water Salinization describes the individual geochemical parameters used in identifying salinization and the information on how and where to obtain them. This is an informative book for anyone interested in the present and future quality of our fresh-water supply.
Groundwater Science, 2E, covers groundwater's role in the hydrologic cycle and in water supply, contamination, and construction issues. It is a valuable resource for students and instructors in the geosciences (with focuses in hydrology, hydrogeology, and environmental science), and as a reference work for professional researchers. This interdisciplinary text weaves important methods and applications from the disciplines of physics, chemistry, mathematics, geology, biology, and environmental science, introducing you to the mathematical modeling and contaminant flow of groundwater. New to the Second Edition:. New chapter on subsurface heat flow and geothermal systems. Expanded content on well construction and design, surface water hydrology, groundwater/ surface water interaction, slug tests, pumping tests, and mounding analysis.. Updated discussions of groundwater modeling, calibration, parameter estimation, and uncertainty. Free software tools for slug test analysis, pumping test analysis, and aquifer modeling. Lists of key terms and chapter contents at the start of each chapter. Expanded end-of-chapter problems, including more conceptual questions. Two-color figures. Homework problems at the end of each chapter and worked examples throughout. Companion website with videos of field exploration and contaminant migration experiments, PDF files of USGS reports, and data files for homework problems. PowerPoint slides and solution manual for adopting faculty.
This book contains both practical and theoretical aspects of groundwater resources relating to geochemistry. Focusing on recent research in groundwater resources, this book helps readers to understand the hydrogeochemistry of groundwater resources. Dealing primarily with the sources of ions in groundwater, the book describes geogenic and anthropogenic input of ions into water. Different organic, inorganic and emerging contamination and salinity problems are described, along with pollution-related issues affecting groundwater. New trends in groundwater contamination remediation measures are included, which will be particularly useful to researchers working in the field of water conservation. The book also contains diverse groundwater modelling examples, enabling a better understanding of water-related issues and their management. Groundwater Geochemistry: Pollution and Remediation offers the reader: An understanding of the quantitative and qualitative challenges of groundwater resources An introduction to the environmental geochemistry of groundwater resources A survey of groundwater pollution-related issues Recent trends in groundwater conservation and remediation Mathematical and statistical modeling related to groundwater resources Students, lecturers and researchers working in the fields of hydrogeochemistry, water pollution and groundwater will find Groundwater Geochemistry an essential companion.