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A lithium-ion battery comprises essentially three components: two intercalation compounds as positive and negative electrodes, separated by an ionic-electronic electrolyte. Each component is discussed in sufficient detail to give the practising engineer an understanding of the subject, providing guidance on the selection of suitable materials in actual applications. Each topic covered is written by an expert, reflecting many years of experience in research and applications. Each topic is provided with an extensive list of references, allowing easy access to further information. Readership: Research students and engineers seeking an expert review. Graduate courses in electrical drives can also be designed around the book by selecting sections for discussion. The coverage and treatment make the book indispensable for the lithium battery community.
Recent advances in electrochemistry and materials science have opened the way to the evolution of entirely new types of energy storage systems: rechargeable lithium-ion batteries, electrochroms, hydrogen containers, etc., all of which have greatly improved electrical performance and other desirable characteristics. This book encompasses all the disciplines linked in the progress from fundamentals to applications, from description and modelling of different materials to technological use, from general diagnostics to methods related to technological control and operation of intercalation compounds. Designing devices with higher specific energy and power will require a more profound understanding of material properties and performance. This book covers the status of materials and advanced activities based on the development of new substances for energy storage.
The electrochemical energy storage is a means to conserve electrical energy in chemical form. This form of storage benefits from the fact that these two energies share the same vector, the electron. This advantage allows us to limit the losses related to the conversion of energy from one form to another. The RS2E focuses its research on rechargeable electrochemical devices (or electrochemical storage) batteries and supercapacitors. The materials used in the electrodes are key components of lithium-ion batteries. Their nature depend battery performance in terms of mass and volume capacity, energy density, power, durability, safety, etc. This book deals with current and future positive and negative electrode materials covering aspects related to research new and better materials for future applications (related to renewable energy storage and transportation in particular), bringing light on the mechanisms of operation, aging and failure.
Papers presented at the symposium held in Paris, France on April 30-May 2, 2003.
The discovery of fullerenes and nanotubes has greatly stimulated the interest of scientists and engineers in carbon materials, and has resulted in much scientific research. These materials have provided us with many interesting ideas and potential applications, some of them practical and some simply dreams for the future. In the early 1960s, carbon fibers, glass-like carbons and pyrolytic carbons were developed which were quite different from the carbon materials that had previously been used. Carbon fibers exhibited surprisingly good mechanical properties, glass-like carbons exhibited brittle fracture resulting in a conchoidal fracture surface similar to sodium glass, and giving no carbon dust, and pyrolytic carbons were produced by a new production process of chemical vapour deposition and showed very high anisotropy. These carbons materials made a great impact not only on the carbon community who had been working on carbon materials but also on people working in the fields of materials science and engineering. They were used to develop a variety of new applications in technological fields, such as semiconductors, microelectronics, aerospace and high temperature, etc. These newly developed carbon materials were called NEW CARBONS, in comparison with carbon materials such as artificial graphites represented by graphite electrodes, carbon blacks and activated carbons, which maybe thought of as CLASSICAL CARBONS. Later, other new carbons, such as activated carbons and those with novel functions, isotropic high-density graphites, intercalation compounds, various composites, etc., were developed. In 1994, Professor Michio Inagaki published a book entitled "New Carbon Materials — Structure and Functions" with his friend Professor Yoshihiro Hishiyama of Musashi Institute of Technology, published by Gihoudou Shuppan in Japanese. However, progress in the fields of these new carbons is so rapid that the previous book is already out of date. For this reason the author has decided to write an English text on New Carbons. The text focuses on New Carbons based on hexagonal networks of carbon-atoms, i.e. graphite-related materials. The fundamental concept underlying this book is that the structure and functions of these materials are principally governed by their texture. The aim is to give readers a comprehensive understanding of New Carbons through the description of their structure and texture, along with the properties that are largely dependent on them.
In recent years the Japanese have funded a comprehensive study of carbon materials which incorporate other elements including boron, nitrogen and fluorine, hence the title of the project "Carbon Alloys".Coined in 1992, the phrase "Carbon Alloys" can be applied to those materials mainly composed of carbon materials in multi-component systems. The carbon atoms of each component have a physical and/or chemical interactive relationship with other atoms or compounds. The carbon atoms of the components may have different hybrid bonding orbitals to create quite different carbon components.Eiichi Yasuda and his team consider the definition of Carbon Alloys, present the results of the Carbon Alloys projects, describe typical Carbon Alloys and their uses, discuss recent techniques for their characterization, and finally, illustrate potential applications and future developments for Carbon Alloy science. The book contains over thirty chapters on these studies from as many researchers.The most modern of techniques, particularly in the area of spectroscopy, were used as diagnostic tools, and many of these are applicable to pure carbons also. Porosity in carbons received considerable attention.
A one-stop resource for both researchers and development engineers, this comprehensive handbook serves as a daily reference, replacing heaps of individual papers. This second edition features twenty percent more content with new chapters on battery characterization, process technology, failure mechanisms and method development, plus updated information on classic batteries as well as entirely new results on advanced approaches. The authors, from such leading institutions as the US National Labs and from companies such as Panasonic and Sanyo, present a balanced view on battery research and large-scale applications. They follow a distinctly materials-oriented route through the entire field of battery research, thus allowing readers to quickly find the information on the particular materials system relevant to their research.
Conjugated polymers suoh as polyaoetylene (CH)x polyphenylene (C6H4)x' poly thiophene (C4H2S)x' etc., which are insulators in their pristine state, can be brought to the metallic state after "doping" with ohemioal speoies whioh oan be either eleotron donors or I aoceptors. . This doping prooess involves a oharge transfer between the dopant moleoule and the polymer ohain whioh are then supposed to be spatially olose to each other. It follows that the meohanism of doping must be oonsidered as an aotual interoalation process, which will greatly affeot the struotural oharacteristios of the starting material, as well as its morphology, as has been observed during the 2 intercalation of graphite and layered compounds . In parallel with these modifioations, the band struoture of the system changes yielding a new set of eleotronio properties. It is evident therefore that the struotural and eleotronio properties are intimately related, and must be studied simultaneously in the same system to give reliable information. A great number of studies have been devoted to the structural and electronic properties of conjugated polymers after a chemical or 2 electrochemical doping process . Most of these concern the properties of the system for a given dopant concentration. With this approach a universal pioture of the polymer/dopant system is very diffioult to obtain, as a comparison between different experiments is very hazardous. On the other hand, only a small number of measurements have been performed during the continuous electroohemioal doping of various polymers.
The quest for efficient and durable battery technologies is one of the key challenges for enabling the transition to renewable energy economies. Magnesium batteries, and in particular rechargeable non-aqueous systems, are an area of extensive opportunity and intense research. Rechargeable magnesium batteries hold numerous advantages over current lithium-ion batteries, namely the relative abundance of magnesium to lithium and the potential for magnesium batteries to greatly outperform their Li-ion counterparts. Magnesium Batteries comprehensively outlines the scientific and technical challenges in the field, covering anodes, cathodes, electrolytes and particularly promising systems such as the Mg–S cell. Edited by a leading figure in the field of electrochemical energy storage, with contributions from global experts, this book is a vital resource for students and researchers at all levels. Whether entering into the subject for the first time or extending their knowledge of battery materials across chemistry, physics, energy, engineering and materials science this book provides an ideal reference for anyone interested in the state-of-the-art and future of magnesium batteries.