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Improved Oil Recovery by Surfactant and Polymer Flooding contains papers presented at the 1976 AIChE Symposium on Improved Oil Recovery by Surfactant and Polymer Flooding held in Kansas City. Organized into 18 chapters, the book includes papers that introduce petroleum reservoirs and discuss interfacial tension; molecular forces; molecular aspects of ultralow interfacial tension; the structure, formation, and phase inversion of microemulsions; and thermodynamics of micellization and related phenomena. Papers on adsorption phenomena at solid/liquid interfaces and reservoir rocks, as well as on flow through porous media studies on polymer solutions, microemulsions, and soluble oils are also provided. Significant topics on molecular, microscopic, and macroscopic aspects of oil displacement in porous media by surfactant and polymer solutions and related phenomena are also discussed. The literature cited in this book forms a comprehensive list of references in relation to improved oil recovery by surfactant and polymer flooding. This book will be useful to experts and non-experts in this field of research.
Polymeric Surfactants covers the structure and stability origins of these highly useful surfactants. Adsorption and solution properties in emulsions are discussed based on their underlying thermodynamics and kinetics. Research scientists and Ph.D. students investigating chemistry, chemical engineering and colloidal science will benefit from this text on polymeric surfactants and their value in preparation and stabilization of disperse systems.
This book aims at presenting, describing, and summarizing the latest advances in polymer flooding regarding the chemical synthesis of the EOR agents and the numerical simulation of compositional models in porous media, including a description of the possible applications of nanotechnology acting as a booster of traditional chemical EOR processes. A large part of the world economy depends nowadays on non-renewable energy sources, most of them of fossil origin. Though the search for and the development of newer, greener, and more sustainable sources have been going on for the last decades, humanity is still fossil-fuel dependent. Primary and secondary oil recovery techniques merely produce up to a half of the Original Oil In Place. Enhanced Oil Recovery (EOR) processes are aimed at further increasing this value. Among these, chemical EOR techniques (including polymer flooding) present a great potential in low- and medium-viscosity oilfields. • Describes recent advances in chemical enhanced oil recovery. • Contains detailed description of polymer flooding and nanotechnology as promising boosting tools for EOR. • Includes both experimental and theoretical studies. About the Authors Patrizio Raffa is Assistant Professor at the University of Groningen. He focuses on design and synthesis of new polymeric materials optimized for industrial applications such as EOR, coatings and smart materials. He (co)authored about 40 articles in peer reviewed journals. Pablo Druetta works as lecturer at the University of Groningen (RUG) and as engineering consultant. He received his Ph.D. from RUG in 2018 and has been teaching at a graduate level for 15 years. His research focus lies on computational fluid dynamics (CFD).
The importance of oil in the world economy cannot be overstated, and methods for recovering oil will be the subject of much scientific and engineering research for many years to come. Even after the application of primary depletion and secondary recovery processes (usually waterflooding), much oil usually remains in a reservoir, and indeed in some heterogeneous reservoir systems as much as 70% of the original oil may remain. Thus, there is an enormous incentive for the development of improved or enhanced methods of oil recovery, aimed at recovering some portion of this remainil)g oil. The techniques used range from 'improved' secondary flooding methods (including polymer and certain gas injection processes) through to 'enhanced' or 'tertiary' methods such as chemical (surfactant, caustic, foam), gas miscible (carbon dioxide, gas reinjection) and thermal (steam soak and drive, in-situ combustion). The distinction between the classification ofthe methods usually refers to the target oil that the process seeks to recover. That is, in 'improved' recovery we are usually aiming to increase the oil sweep efficiency, whereas in 'tertiary' recovery we aim to mobilise and recover residual or capillary trapped oil. There are a few books and collections of articles which give general overviews of improved and enhanced oil recovery methods. However, for each recovery method, there is such a wide range of interconnected issues concerning the chemistry, physics and fluid mechanics of flow in porous media, that rarely are these adequately reviewed.
This book aims at presenting, describing, and summarizing the latest advances in polymer flooding regarding the chemical synthesis of the EOR agents and the numerical simulation of compositional models in porous media, including a description of the possible applications of nanotechnology acting as a booster of traditional chemical EOR processes. A large part of the world economy depends nowadays on non-renewable energy sources, most of them of fossil origin. Though the search for and the development of newer, greener, and more sustainable sources have been going on for the last decades, humanity is still fossil-fuel dependent. Primary and secondary oil recovery techniques merely produce up to a half of the Original Oil In Place. Enhanced Oil Recovery (EOR) processes are aimed at further increasing this value. Among these, chemical EOR techniques (including polymer flooding) present a great potential in low- and medium-viscosity oilfields. • Describes recent advances in chemical enhanced oil recovery. • Contains detailed description of polymer flooding and nanotechnology as promising boosting tools for EOR. • Includes both experimental and theoretical studies. About the Authors Patrizio Raffa is Assistant Professor at the University of Groningen. He focuses on design and synthesis of new polymeric materials optimized for industrial applications such as EOR, coatings and smart materials. He (co)authored about 40 articles in peer reviewed journals. Pablo Druetta works as lecturer at the University of Groningen (RUG) and as engineering consultant. He received his Ph.D. from RUG in 2018 and has been teaching at a graduate level for 15 years. His research focus lies on computational fluid dynamics (CFD).
This book provides a concise treatise on the use of surfactants in enhanced oil recovery (EOR), including information on key types of surfactants and their respective applications in the wider petroleum industry. The authors discuss carbon dioxide EOR, alkaline-surfactant-polymer flooding strategies, and the use of surfactants as a means of reducing interfacial tension, while also paying special attention to the challenges involved in using surfactants for enhanced oil recovery, such as the difficult issue of surfactant adsorption on reservoir rock. All chapters highlight and are based on the authors’ own laboratory-scale case studies. Given its content, the book offers a valuable asset for graduate students of petroleum and chemical engineering, as well as researchers in the field of chemical enhanced oil recovery. It will also be of interest to professionals involved in enhanced industrial oil recovery.
In this chapter, the fundamentals of surfactant flooding are covered, which include microemulsion properties, phase behavior, interfacial tension, capillary desaturation, surfactant adsorption and retention, and relative permeabilities. The surfactant–polymer interactions are discussed. The mechanisms and screening criteria are briefly discussed. The field cases presented include low-tension waterflooding (Loma Novia, Wichita County Regular field), sequential micellar/polymer flooding (El Dorado, Sloss), micellar/polymer flooding (Torchlight and Delaware-Childers), and Minas SP project preparation and SP flooding (Gudong).
This book covers all aspects of polymer flooding, an enhanced oil recovery method using water soluble polymers to increase the viscosity of flood water, for the displacement of crude oil from porous reservoir rocks. Although this method is becoming increasingly important, there is very little literature available for the engineer wishing to embark on such a project. In the past, polymer flooding was mainly the subject of research. The results of this research are spread over a vast number of single publications, making it difficult for someone who has not kept up-to-date with developments during the last 10 to 15 years to judge the suitability of polymer flooding to a particular field case. This book tries to fill that gap. The basic mechanisms of the process are described and criteria given where it may be employed. Basic elements of the chemistry of EOR-polymers are provided. The fundamentals of polymer physics, such as rheology, flow in porous media and adsorption, are derived. Practical hints on mixing and testing of polymers in the laboratory are given, as well as instructions for their application in the oil field. Polymer flooding is illustrated by some case histories and the economics of the methods are examined. For the essential subjects, example calculations are added. An indispensable book for reservoir engineers, production engineers and laboratory technicians within the petroleum industry.