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This report presents a cost analysis of Hydrogen Cyanide production via a direct synthesis method involving the reaction of ammonia, methane (natural gas), and air. The process examined is similar to Andrussow process. This report was developed based essentially on the following reference(s): (1) "Cyanides," Kirk-Othmer Encyclopedia of Chemical Technology, 5th edition (2) "Hydrogen Cyanide," McKetta, J., Inorganic Chemicals Handbook. Vol. 2 Keywords: Prussic Acid, DuPont, Reactor Waste-Heat Boiler, Air, Methane, Combustion
This report presents a cost analysis of DL-Methionine production from methional and hydrogen cyanide (HCN). The process examined is a typical carbonate process. This process is a multi-step process including: hydantoin intermediate production; reaction of hydantoin with potassium carbonate to produce potassium methioninate; and methioninate conversion to DL-Methionine. This report was developed based essentially on the following reference(s): US Patent 20130231501, issued to Evonik in 2013 Keywords: DLM, 3-Methylmercapto Propionaldehyde, MMP, Methional, Essential Amino Acid, Degussa
This report presents a cost analysis of Adiponitrile production from butadiene and hydrogen cyanide. In the process examined, adiponitrile is generated by the two-stage hydrocyanation of butadiene. The reaction product is treated for catalyst reovery and subsequently distilled for obtaining high-purity adiponitrile, suitable for hexamethylenediamine production. This report was developed based essentially on the following reference(s): Keywords: HMDA, DuPont, Hydrocyanation
This report presents a cost analysis of Hexamethylenediamine (HMDA) production from butadiene and hydrogen cyanide In the process examined, butadiene reacts with hydrogen cyanide to produce adiponitrile as an intermediate. Subsequently, the adiponitrile is hydrogenated to produce HMDA. This report was developed based essentially on the following reference(s): (1) WO Patent 2015009847, issued to Invista Technologies in 2015 (2) US Patent 4395573, issued to Monsanto in 1981 Keywords: HMDA, Rhône-Poulenc, DuPont, Hydrocyanation
This report presents a cost analysis of Isophorone Diisocyanate (IPDI) production from isophorone and chlorine. The process examined is a typical phosgenation process. In this process, isophorone diamine (IPDA) intermediate is initially obtained from isophorone. Then, IPDA reacts with phosgene to produce IPDI. The phosgene used is generated from chlorine and carbon monoxide in an on-site unit. Hydrogen chloride (HCl) is generated as by-product. This report was developed based essentially on the following reference(s): (1) US Patent 9187412 B2, issued to Evonik Degussa in 2015 (2) US Patent 8884063 B2, issued to BASF SE in 2014 (3) US Patent 8563768, issued to Covestro (fromer Bayer MaterialScience) in 2013 Keywords: Isophorone Diisocyanate, IPDI, Isophorone Diamine, IPDA, Phosgenation
This report presents a cost analysis of Acrylonitrile production from chemical grade (CG) propylene. The process examined is a fluidized bed propylene ammoxidation process. In this process, propylene and ammonia react to produce Acrylonitrile. Acetonitrile and hydrogen cyanide are generated as by-products. This report was developed based essentially on the following reference(s): "Acrylonitrile", Kirk-Othmer Encyclopedia of Chemical Technology, 5th edition Keywords: Propene, Propenenitrile, INEOS, Sohio, Fluidized Bed Reactor
This report presents a cost analysis of DL-Methionine production from methional and hydrogen cyanide (HCN) The process examined is a typical carbonate process. This process is a multi-step process including: hydantoin intermediate production; reaction of hydantoin with potassium carbonate to produce potassium methioninate; and methioninate conversion to DL-Methionine. This report was developed based essentially on the following reference(s): US Patent 20130231501, issued to Evonik in 2013 Keywords: DLM, 3-Methylmercapto Propionaldehyde, MMP, Methional, Essential Amino Acid, Degussa
This monograph consists of manuscripts submitted by invited speakers who participated in the symposium "Industrial Environmental Chemistry: Waste Minimization in Industrial Processes and Remediation of Hazardous Waste," held March 24-26, 1992, at Texas A&M University. This meeting was the tenth annual international symposium sponsored by the Texas A&M Industry-University Cooperative Chemistry Program (IUCCP). The program was developed by an academic-industrial steering committee consisting of the co-chairmen, Professors Donald T. Sawyer and Arthur E. Martell of the Texas A&M University Chemistry Department, and members appointed by the sponsoring companies: Bernie A. Allen, Jr., Dow Chemical USA; Kirk W. Brown, Texas A&M University; Abraham Clearfield, Texas A&M University; Greg Leyes, Monsanto Company; Jay Warner, Hoechst-Celanese Corporation; Paul M. Zakriski, BF Goodrich Company; and Emile A. Schweikert, Texas A&M University (IUCCP Coordinator). The subject of this conference reflects the interest that has developed in academic institutions and industry for technological solutions to environmental contamination by industrial wastes. Progress is most likely with strategies that minimize waste production from industrial processes. Clearly the key to the protection and preservation of the environment will be through R&D that optimizes chemical processes to minimize or eliminate waste streams. Eleven of the papers are directed to waste minimization. An additional ten papers discuss chemical and biological remediation strategies for hazardous wastes that contaminate soils, sludges, and water.
As concerns increase over the scarcity of water resources and the role of anthropogenic activities, water quality is evermore important. Activities ranging from agriculture to mining have had a bearing on the quality of water that they impact. Several studies assessing such impacts have been conducted at local and global scales over the years. This book, consisting of contributions by authors in various water-related fields, delves into some approaches that are used to understand and/or to improve water quality, and these include assessment of water chemistry, biomonitoring, modelling and water treatment. This book will be useful to environmental scientists, water professionals, researchers, academics and students.
The study of comets is a field that has seen tremendous advances in recent years, far surpassing the knowledge reflected in the original Comets volume published as part of the Space Science Series in 1982. This new volume, with more than seventy contributing authors, represents the first complete overview of comet science in more than a decade and contains the most extensive collection of knowledge yet assembled in the field. Comets II situates comet science in the global context of astrophysics for the first time by beginning with a series of chapters that describe the connection between stars and planets. It continues with a presentation of the formation and evolution of planetary systems, enabling the reader to clearly see the key role played in our own solar system by the icy planetesimals that were the seeds of the giant planets and transneptunian objects. The book presents the key results obtained during the 1990s, in particular those collected during the apparition of the exceptional comets C/Hyakutake and C/Hale-Bopp in 1996-1997. The latest results obtained from the in situ exploration of comets P/Borrelly and P/Wild 2 are also discussed in detail. Each topic of is designed to be accessible to students or young researchers looking for basic, yet detailed, complete and accurate, information on comet science. With its emphasis on the origin of theories and the future of research, Comets II will enable scientists to make connections across disciplinary boundaries and will set the stage for discovery and new understanding in the coming years.