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The book is concerned with understanding the fundamental mechanisms of high temperature alloy oxidation. It uses this understanding to develop methods of predicting oxidation rates and the way they change with temperature, gas chemistry and alloy composition. The focus is on designing (or selecting) alloy compositions which provide optimal resistance to attack by corrosive gases. . Emphasises quantitative calculations for predicting reaction rates and the effects of temperature, oxidant activities and alloy compositions. . Uses phase diagrams and diffusion paths to analyse and interpret scale structures and internal precipitation distributions . Provides a detailed examination of corrosion in industrial gases (water vapour effects, carburisation and metal dusting, sulphidation) . Text is well supported by numerous micrographs, phase diagrams and tabulations of relevant thermodynamic and kinetic data . Combines physical chemistry and materials science methodologies.
High Temperature Coatings, Second Edition, demonstrates how to counteract the thermal effects of rapid corrosion and degradation of exposed materials and equipment that can occur under high operating temperatures. This is the first true practical guide on the use of thermally protective coatings for high-temperature applications, including the latest developments in materials used for protective coatings. It covers the make-up and behavior of such materials under thermal stress and the methods used for applying them to specific types of substrates, as well as invaluable advice on inspection and repair of existing thermal coatings. With his long experience in the aerospace gas turbine industry, the author has compiled the very latest in coating materials and coating technologies, as well as hard-to-find guidance on maintaining and repairing thermal coatings, including appropriate inspection protocols. The book is supplemented with the latest reference information and additional support to help readers find more application- and industry-type coatings specifications and uses. - Offers an overview of the underlying fundamental concepts of thermally-protective coatings, including thermodynamics, energy kinetics, crystallography and equilibrium phases - Covers essential chemistry and physics of underlying substrates, including steels, nickel-iron alloys, nickel-cobalt alloys and titanium alloys - Provides detailed guidance on a wide variety of coating types, including those used against high temperature corrosion and oxidative degradation and thermal barrier coatings
Reviews the science and engineering of high-temperature corrosion and provides guidelines for selecting the best materials for an array of system processes High-temperature corrosion (HTC) is a widespread problem in an array of industries, including power generation, aerospace, automotive, and mineral and chemical processing, to name a few. This book provides engineers, physicists, and chemists with a balanced presentation of all relevant basic science and engineering aspects of high-temperature corrosion. It covers most HTC types, including oxidation, sulfidation, nitridation, molten salts, fuel-ash corrosion, H2S/H2 corrosion, molten fluoride/HF corrosion, and carburization. It also provides corrosion data essential for making the appropriate choices of candidate materials for high-temperature service in process conditions. A form of corrosion that does not require the presence of liquids, high-temperature corrosion occurs due to the interaction at high temperatures of gases, liquids, or solids with materials. HTC is a subject is of increasing importance in many areas of science and engineering, and students, researchers, and engineers need to be aware of the nature of the processes that occur in high-temperature materials and equipment in common use today, especially in the chemical, gas, petroleum, electric power, metal manufacturing, automotive, and nuclear industries. Provides engineers and scientists with the essential data needed to make the most informed decisions on materials selection Includes up-to-date information accompanied by more than 1,000 references, 80% of which from within the past fifteen years Includes details on systems of critical engineering importance, especially the corrosion induced by low-energy radionuclides Includes practical guidelines for testing and research in HTC, along with both the European and International Standards for high-temperature corrosion engineering Offering balanced, in-depth coverage of the fundamental science behind and engineering of HTC, High Temperature Corrosion: Fundamentals and Engineering is a valuable resource for academic researchers, students, and professionals in the material sciences, solid state physics, solid state chemistry, electrochemistry, metallurgy, and mechanical, chemical, and structural engineers.
A straightforward treatment describing the oxidation processes of metals and alloys at elevated temperatures. This 2006 second edition retains the fundamental theory but incorporates advances made in understanding degradation phenomena. The first half provides an authoritative introduction to the basic principles, covering thermodynamics and mechanisms of high temperature corrosion of metals and alloys. The latter half extends the discussion to oxidation processes in complex systems, from reactions in mixed environments to protective techniques, including coatings and atmosphere control. The authors provide a logical and expert treatment of the subject, producing a revised edition that will be a comprehensive guide to material scientists and engineers requiring an understanding of this elementary process.
This book assesses the state of the art of coatings materials and processes for gas-turbine blades and vanes, determines potential applications of coatings in high-temperature environments, identifies needs for improved coatings in terms of performance enhancements, design considerations, and fabrication processes, assesses durability of advanced coating systems in expected service environments, and discusses the required inspection, repair, and maintenance methods. The promising areas for research and development of materials and processes for improved coating systems and the approaches to increased coating standardization are identified, with an emphasis on materials and processes with the potential for improved performance, quality, reproducibility, or manufacturing cost reduction.
This four-volume reference work builds upon the success of past editions of Elsevier’s Corrosion title (by Shreir, Jarman, and Burstein), covering the range of innovations and applications that have emerged in the years since its publication. Developed in partnership with experts from the Corrosion and Protection Centre at the University of Manchester, Shreir’s Corrosion meets the research and productivity needs of engineers, consultants, and researchers alike. Incorporates coverage of all aspects of the corrosion phenomenon, from the science behind corrosion of metallic and non-metallic materials in liquids and gases to the management of corrosion in specific industries and applications Features cutting-edge topics such as medical applications, metal matrix composites, and corrosion modeling Covers the benefits and limitations of techniques from scanning probes to electrochemical noise and impedance spectroscopy
The classic book on corrosion science and engineering—now in a valuable new edition The ability to prevent failures by managing corrosion is one of the main global challengesof the twenty-first century. However, most practicing engineers and technologists have only a basic understanding of how they can actively participate in this urgent economic and environmental issue. Now, students and professionals can turn to this newly revised edition of the trusted Corrosion and Corrosion Control for coverage of the latest developments in the field, including advances in knowledge, new alloys for corrosion control, and industry developments in response to public demand. This Fourth Edition presents an updated overview of the essential aspects of corrosion science and engineering that underpin the tools and technologies used for managing corrosion, enhancing reliability, and preventing failures. Although the basic organization of the book remains unchanged from the previous edition, this new update includes: An introduction to new topics, including the element of risk management in corrosion engineering and new advanced alloys for controlling corrosion Expanded discussions on electrochemical polarization, predicting corrosion using thermodynamics, steel reinforcements in concrete, and applications of corrosion control technologies in automotive, nuclear, and other industries A stronger emphasis on environmental concerns and regulations in the context of their impact on corrosion engineering A discussion of the challenge of reliability in nuclear reactors; stainless steels; the concept of critical pitting temperature; and information on critical pitting potential (CPP) Complemented with numerous examples to help illustrate important points, Corrosion and Corrosion Control, Fourth Edition enables readers to fully understand corrosion and its control and, in turn, help reduce massive economic and environmental loss. It is a must-read for advanced undergraduates and graduate students in engineering and materials science courses, as well as for engineers, technologists, researchers, and other professionals who need information on this timely topic.
This book serves as a reference for engineers, scientists, and students concerned with the use of materials in applications where reliability and resistance to corrosion are important. It updates the coverage of its predecessor, including coverage of: corrosion rates of steel in major river systems and atmospheric corrosion rates, the corrosion behavior of materials such as weathering steels and newer stainless alloys, and the corrosion behavior and engineering approaches to corrosion control for nonmetallic materials. New chapters include: high-temperature oxidation of metals and alloys, nanomaterials, and dental materials, anodic protection. Also featured are chapters dealing with standards for corrosion testing, microbiological corrosion, and electrochemical noise.