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Authored by many of the world's leading experts on high-Tc superconductivity, this volume presents a panorama of ongoing research in the field, as well as insights into related multifunctional materials. The contributions cover many different and complementary aspects of the physics and materials challenges, with an emphasis on superconducting materials that have emerged since the discovery of the cuprate superconductors, for example pnictides, MgB2, H2S and other hydrides. Special attention is also paid to interface superconductivity. In addition to superconductors, the volume also addresses materials related to polar and multifunctional ground states, another class of materials that owes its discovery to Prof. Müller's ground-breaking research on SrTiO3.
The recent discovery of high-temperature superconductivity in copper based oxides is an event of major importance not only with respect to the physical phenomenon itself but also because it definitely shows that solid state chemistry, and especially the crystal chemistry of oxides, has a crucial place in the synthesis and understanding of new materials for future appli cations. The numerous papers published in the field of high Tc supercon ductors in the last five years demonstrate that the great complexity of these materials necessitates a close collaboration between physicists and solid state chemists. This book is based to a large extent on our experience of the crystal chemistry of copper oxides, which we have been studying in the laboratory for more than twelve years, but it also summarizes the main results which have been obtained for these compounds in the last five years relating to their spectacular superconducting properties. We have focused on the struc ture, chemical bonding and nonstoichiometry of these materials, bearing in mind that redox reactions are the key to the optimization of their supercon ducting properties, owing to the importance of the mixed valence of copper and its Jahn-Teller effect. We have also drawn on studies of extended defects by high-resolution electron microscopy and on their creation by ir radiation effects.
This book provides an introduction to the basic principles of neutron scattering and its application to current problems in condensed matter science and technology. Experiments on novel materials are particularly emphasized.
This book provides an introduction to the basic principles of neutron scattering and its application to current problems in condensed matter science and technology. Experiments on novel materials are particularly emphasized.
Since the publication of Physical Properties of High Temperature Superconductors I, research in the field of high temperature superconductivity has continued at a rapid pace. Volume II will contain chapters on some of the major areas of activity which were not covered extensively in Volume I: structure, microstructure, thermodynamics, oxygen stoichiometry effects, nuclear magnetic and quadrupole resonance, Hall effect, electronic structure, and the pairing state. Like Volume I, it will present authoritative and comprehensive reviews written by recognized experts in the field. This book should be useful to all students, scientists, and engineers who desire to know more about high temperature superconductivity.
A Festschrift in honor of Professor Marvin L. Cohen This volume is a Festschrift in honor of Professor Marvin L. Cohen. The articles, contributed by leading researchers in condensed matter physics, high-light recent advances in the use of quantum theory to explain and predict properties of real materials. The invention of quantum mechanics in the 1920's provided detailed descriptions of the electronic structure of atoms. However, a similar understanding of solids has been achieved only in the past 30 years, owing to the complex electron-ion and electron electron interactions in these systems. Professor Cohen is a central figure in this achievement. His development of the pseudopotential and total energy methods provided an alternate route using computers for the exploration of solids and new materials even when they have not yet been synthesized. Professor Cohen's contributions to materials theory have been both fundamental and encompassing. The corpus of his work consists of over 500 papers and a textbook. His band structures for semiconductors are used worldwide by researchers in solid state physics and chemistry and by device engineers. Professor Cohen's own use of his theories has resulted in the determination of the electronic structure, optical properties, structural and vibrational properties, and superconducting properties of numerous condensed matter systems including semiconductors, metals, surfaces, interfaces, defects in solids, clusters, and novel materials such as the fullerides and nanotubes.
Providing proven strategies for solutions to research, development, and production dilemmas, this reference details the instrumentation and underlying principles for utilization of electron microscopy in the manufacturing, automotive, semiconductor, photographic film, pharmaceutical, chemical, mineral, forensic, glass, and pulp and paper industries. The book covers safety, calibration, and troubleshooting techniques, as well as methods in sample preparation and image collection, interpretation, and analysis. It includes contributions from microscopy experts based at major corporations and scientists from universities and major research centers.
Prof. Heike Kamerlingh Onnes discovered superconductivity while measuring resistivity of mercury. Surprisingly the resistivity of mercury ceased at 4.2 K and this phenomenon was known as superconductivity. He realized the importance of this discovery in producing large magnetic fieldspl. delateIt was realized that superconductivity is in a new thermodynamic state with peculiar electric and magnetic properties. This paved the way to discover more superconductors. Simple elements such as Tin, Indium or lead showed the highest critical temperature (Tc) 7.2 K. They were called as Type 1 superconductors. Niobium-nitride was found to superconduct at 16 K at 1941 and Vanadium-silicon showed superconductive properties at 17.5 K at 1953. Nb alloys and binary or more complex compounds such as Nb3Sn (Tc – 18 K), Nb-Ti (Tc -9 K), Ga, V with Tc,23 K became type II superconductors. Thereafter, there was not much improvement in the development of superconductor although wonderful applications were expected from superconductors. After three decades, Fullerenes, like ceramic superconductors, are discovered. A decade ago MgB2 was discovered with Tc = 39 K. These superconductors were routinely produced into formof wires for producing larger magnetic fields. In all these cases cooling was effectively done by liquid Helium. A comprehensive microscopic theory of superconductivity in metals was proposed in 1957 by John Bardeen, Leon Cooper and Robert Schrieffer (the so-called “BCS” theory) for which they received the Nobel Prize in Physics. In a major breakthrough, George Bednorz and Karl Mueller discovered a brittle ceramic superconductivity in the family of cuprates at 30 K in 1986 and a new era began. Inspired by the work of Bednorz and Mueller on high temperature superconductivity (HTS), Paul Chu and his associates at the University of Houston discovered in 1987, 123 compounds. That is, YBCO (Yttrium1- Barium2-Copper3- Oxygen7) and iso-structural RBCO (Rare-earth1-Barium2-Copper3-Oxygen7) have a Tc of 93 K. Prior to 1987, all superconducting materials had lower critical temperatures (Tc’s) and therefore functioned only at temperatures near the boiling point of liquid helium (4.2 K) or liquid hydrogen (20.28 K), with the highest being Nb3Ge at 23 K. They were known as low temperature superconductors. YBCO was the first material to become superconducting above 77 K, (boiling point of liquid nitrogen) and subsequently a series of high temperature superconducting materials were discovered. These superconducting materials are widely known as High temperature superconductors as these Tc’s exceeded the limit prescribed by BCS theory. HTSCs are potentially valuable as liquid nitrogen is cheaper than liquid helium. YBCO possesses superior superconducting and physical properties. YBCO receiver coils in NMR-spectrometers have improved the resolution NMR spectrometers by a factor of 3 compared to that achievable with conventional coils. Paul Chu’s group holds the current Tc-record of 164 K in the mercury barium based cuprate superconductor under pressure. Their work led to a rapid succession of new high temperature superconducting materials, ushering in a new era in material science, chemistry and technology. Added to this the structure of Bi2Sr2Ca2Cu2O10(BiSCCO) high temperature superconductive compound having T= 110 K was reported. In 1993, mercuric-cuprates, perovskite ceramic superconductors with the transition temperatures Tc =138 K was also reported.
The field of superconductivity has tremendous potential for growth and further development in industrial applications. The subject continues to occupy physicists, chemists, and engineers interested in both the phenomena itself and possible financially viable industrial devices utilizing the physical concepts. For the past five years, within the publications of the American Physical Society, for example, 40%-60% of all articles submitted to major journals in the area of Solid State Physics have been on the subject of superconductivity, including the newer, extremely important subfield of high temperature superconductivity (high Tc).The present volume is the first handbook to address this field. It covers both "classic" superconductivity-related topics and high Tc. Numerous properties, including thermal, electrical, magnetic, mechanical, phase diagrams, and spectroscopic crystallographic structures are presented for many types of superconductors. Critical fields, critical currents, coherence lengths, penetration depths, and transition temperatures are tabulated. - First handbook on Superconductivity - Coherence lengths and depths are tabulated - Crystallographic structures of over 100 superconductor types - Main results of several theories are submitted - Phase diagrams for synthesizing new superconductors are included