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This book presents a summary of high-pressure phase transitions of minerals and related inorganic compounds. The first part reviews the methods to investigate phase transitions by direct high-pressure and high-temperature experiments together with thermodynamic approaches that consist of calorimetric measurements and thermodynamic calculation. In the second part, phase relations and thermodynamic properties of olivine, pyroxene, garnet, spinel, perovskite, rutile, and related inorganic compounds with A2BO4, ABO3, AB2O4, and AO2 stoichiometries are described. Particular emphasis is placed on spinel- and perovskite-structured phases and their high-pressure polymorphs called post-spinel and post-perovskite phases. The last part of the book focuses on phase relations of mantle rocks and on natural high-pressure minerals from the Earth’s deep mantle and in shocked meteorites.
The ever-increasing importance of chemical reactions at high and superhigh temperatures in crystalline, amorphous, and semicrystalline SOlids, as well as the reactions of these solids with gases, prompted the authors of this book to examine critically the literature available in this field and to present a general review of the subject. In this monograph we discuss those chemical and physicochemical points which we consider to be most important for solving a series of problems in the preparation and use of new inorganic materials. We hope that this book will be of interest to the many specialists working on inorganic materials. N. A. Toropov PREFACE Modem technology demands ever more materials with high mechanical strength, heat and chemical re sistance, fire resistance, special electrical properties, particular behavior toward active radiations, etc. The search for such materials requires the study of various chemical compounds, metallic alloys, and other fused in organic systems, especially oxide systems. Materials based on oxides begin to assume increasing importance in many fields of the new technology. In this connection the investigation of oxides and systems consisting of two and more oxides is expanding greatly.
Silicate Glasses and Melts, Second Edition describes the structure-property-composition relationships for silicate glasses and melts from a geological and industrial perspective. Updated sections include (i) characterization of silicate melt and COHN fluid structure (with and without dissolved silicate components) with pressure, temperature, and redox conditions and responses of structural variables to chemical composition, (ii) determination of solubility and solution mechanisms of COHN volatiles in silicate melts and minerals and of solubility and solution mechanisms of silicate components in COHN fluids, and (iii) effects of very high pressure on structure and properties of melts and glasses. This new book is an essential resource for researchers in a number of fields, including geology, geophysics, geoscience, volcanology, material science, glass science, petrology and mineralogy. - Brings together multidisciplinary research scattered across the scientific literature into one reference, with a focus on silicate melts and their application to natural systems - Emphasizes linking melt properties to melt structure - Includes a discussion of the pros and cons of the use of glass as a proxy for melt structure and properties - Written by highly regarded experts in the field who, among other honors, were the 2006 recipients of the prestigious G.W. Morey award of the American Ceramic Society
High-Pressure Research: Applications in Geophysics contains the papers presented during a U.S.-Japan joint seminar held in Honolulu, Hawaii, 6-9 July 1976. The seminar brought together scientists engaged in high pressure-high temperature research to exchange ideas on the latest state-of-the-art developments, their experimental results, and their latest interpretations with regard to the significance of these results to the geophysical sciences in general. Four formal sessions were held. Of the forty-two papers presented at the seminar, thirty-nine appear as contributed papers and three as abstracts in this volume. The papers in Session I examine the geophysics and geochemistry of the crust and upper mantle. The contributions in Session II focus on phase transitions related to Earth's deep interior. Session III is devoted equations of state and shock wave experiments while Session IV covers instrumentation, pressure calibration, and standardization.
Since the beginning of civilization, the origins of the Earth and Moon have been the subjects of continuing interest, speculation, and enquiry. These are also among the most challenging of all scientific problems. They are, perhaps to a unique degree, interdisciplinary, having attracted the attention of philosophers, astronomers, mathematicians, geologists, chemists, and physicists. A large and diverse literature has developed, far beyond the capacity of individuals to assimilate adequately. Consequently, most of those who attempt to present review-syntheses in the area tend to reflect the perspectives of their own particular disciplines. The present author's approach is that of a geochemist, strongly influenced by the basic phil osophy of Harold Urey. Whereas most astronomical phenomena are controlled by gravitational and magnetic fields, and by nuclear interactions, Urey (1952) emphasized that the formation of the solar system occurred in a pressure-temperature regime wherein the chemical properties of matter were at least as important as those of gravitational and magnetic fields. This was the principal theme of his 1952 book, "The Planets," which revolutionized our approach to this subject. In many subsequent papers, Urey strongly emphasized the importance of meteorites in providing critical evidence of chemical conditions in the primordial solar nebula, and of the chemical fractionation processes which occurred during formation of the terrestrial planets. This approach has been followed by most subsequent geochemists and cosmochemists.