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As laboratories replace heavy hydraulic presses and bulky high-pressure chambers with miniature diamond anvils, traditional heaters with laser heating, and continue to improve methods of shock compression, there has been considerable new data obtained from the high-pressure, high-temperature modification of pure elements. The dense metallic modification of elements shows the potential for achieving superconductivity akin to theoretical predictions. Phase Transformations of Elements Under High Pressure contains the latest theoretical and experimental information on nearly 100 elements, including first-and second-phase transitions, melting lines, crystal structures of stable and metastable phases, stability of polymorphic modifications, and other useful properties and data. It emphasizes features such as changes in the liquid state, amorphization, and metallization, and provides temperature-pressure diagrams for every element. The book also describes the transitions of polymeric forms of fullerene, crystal modifications of elements stable under high pressures, and provides data that confirms their superconducting and magnetic properties. This handbook will be a lasting reference for scientists in a broad range of disciplines, including solid-state physics, chemistry, crystallography, mineralogy, and materials science.
The use of high-pressure techniques has become popular for studying the nature of substances and phenomena occurring in them, especially as a means of obtaining new materials (synthesis under high pressure) and processing known materials (hydroextrusion). A product of many years of research by the authors and their colleagues, Phase Transitions in Solids under High Pressure discusses the relationships of phase transformations in solids under high pressure, the mechanism of these transformations, crystal geometry, the effect of deformation, the conditions of formation, and preservation of the high-pressure phases under normal pressure. The book begins with an introduction that describes the relationship of the thermodynamics of phase transformations and the kinetics of the transformations. This is followed by a chapter explaining the equipment and mostly original procedures for investigating phase transformation in solids under high hydrostatic and quasi-hydrostatic pressures. The book covers phase transformations under high pressure in a wide temperature range in the elements carbon, silicon, germanium, titanium, zirconium, iron, gallium, and cerium as well as in titanium- and iron-based alloys and AIBVII, AIIBVI, and AIIIBV compounds. In addition, the book examines the kinetics of phase transformations in iron-based alloys in isobaric–isothermal conditions. The authors present results for phase transformations in deformation under high pressure, describe several non-trivial effects associated with phase transformations under high pressure, and analyze the kinetics and hysteresis of high-temperature and low-temperature phase transformations. They conclude by describing the role of investigations under high pressure for determining general relationships governing phase transformations in solids.
A comprehensive handbook comprising two volumes, High Pressure Phase Transformations classifies and systemizes data on phase transformations of 2,263 elements and compounds under high pressure (at least 0.1 GPa). Each compound has a separate paragraph and bibliography that includes information on the behavior of the material under normal pressure. A critical analysis is made of experimental data on melting, first- and second-order phase transitions, crystal stuctures and phase diagrams, and data on new materials and compounds synthesized under high pressure are presented and discussed.
For all kinds of materials, phase transformations show common phenomena and mechanisms, and often turn a material, for example metals, multiphase alloys, ceramics or composites, into its technological useful form. The physics and thermodynamics of a transformation from the solid to liquid state or from one crystal form to another are therefore essential for creating high-performance materials. This handbook covers phase transformations, a general phenomenon central to understanding the behavior of materials and for creating high-performance materials. It will be an essential reference for all materials scientists, physicists and engineers involved in the research and development of new high performance materials. It is the revised and enhanced edition of the renowned book edited by the late P. Haasen in 1990 (Vol. 5, Materials Science and Technology).
The use of high-pressure techniques has become popular for studying the nature of substances and phenomena occurring in them, especially as a means of obtaining new materials (synthesis under high pressure) and processing known materials (hydroextrusion). A product of many years of research by the authors and their colleagues, Phase Transitions in
In many instances of mechanical interaction between two materials, the physical contact affects only the outermost surface layer, with little discernible influence on the bulk of the material. The resultant high pressures in these localised regimes can induce surface structural changes such as deformation, phase transformation and amorphization.
Phase transitions are involved in phenomena ranging from the initial stages of the creation of the Universe to the existence of biological objects. It is natural to as whether any phenomena analogous to phase transitions are possible in disordered substances like liquids and glasses. The possibility of such transitions is still very much a matter of debate. Neither the nature nor the features of transformations in liquids and glasses are yet clear, nor is the nature of the order parameters. Investigations in recent years have shown that transformations in liquids and glasses lead to a drastic change of their physical properties and short-range order structure. The papers collected here contribute to a better understanding of the physics of disordered systems and phase transformations in them. An unambiguous identification of transitions in liquids and glasses requires further high-precision experimental study of the thermodynamic and structural properties in the vicinity of transitions in order to test existing theoretical models and develop new, more accurate ones.
This collection is organized around the central theme of “Martensite by Design.” Contributions include design, microstructure, properties, advanced processing and manufacturing, performance, phase transformations, and characterization.