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It is a basic law of chemistry that pressure influences reactions. Thus, high-pressure reactions are no longer a rarity in chemistry today, but rather are indispensable tools - whether for innovative syntheses, new products or for explaining reaction mechanisms. The expert editors, Rudi van Eldik and Frank-Gerrit Klärner, provide a comprehensive overview of this fascinating field, ranging from the influence of high pressure on organic and inorganic reactions, via concrete applications in synthesis for metal catalytic and stereoselective processes right up to the use of supercritical liquids. Written by renowned experts, this volume contains a wealth of vital and practical information, for both newcomers to the field as well as experienced high-pressure chemists. Whether in academia or industry, this book belongs on the shelf of every chemist concerned with high-pressure chemistry either now or in the future.
High pressure chemistry is a widely used methodology in organic synthesis which helps to increase the rate and to improve the efficiency of chemical processes. The current publication outlines the impact of pressure on many types of chemical reactions important from synthetic point of view and gives practical considerations how to plan and perform synthetic experiments under high pressure in the lab.
Volume 41 of Reviews in Mineralogy and Geochemistry introduces to the field of high-temperature and high-pressure crystal chemistry, both as a guide to the dramatically improved techniques and as a summary of the voluminous crystal chemical literature on minerals at high temperature and pressure. The three parts of the book introduces crystal chemical considerations of special relevance to non-ambient crystallographic studies, reviews the temperature- and pressure-variation of structures in major mineral groups and presents experimental techniques for high-temperature and high-pressure studies of single crystals and polycrystalline samples as well as special considerations relating to diffractometry on samples at non-ambient conditions.
There is no paucity of books on high pressure. Beginning with P. W. Bridgman's The Physics of High Pressure, books of general interest include the two-volume Physics and Chemistry of High Pressure, edited by R. S. Bradley, and the series, Advances in High Pressure Research, as well as the report on the Lake George Conference in 1960. Solid state physics is well represented by Solids Under Pressure, edited by Paul and Warschauer, by Physics of Solids at High Pressure, edited by Tomizuka and Emrick, and by Properties Physiques des Solides sous Pression, edited by Bloch, as well as by chapters in Volumes 6, 13, 17, and 19 of Solid State Physics, edited by Seitz, Turnbull, and Ehrenreich. Chemistry in gases and liquids is covered in Weale's Chemical Reactions at High Pressure, and Hamann's Physico-chemical Effects of Pressure. In addition to the coverage of techniques and calibrations in the above volumes, Modern Very High Pressure Techniques, edited by Wentorf, High Pressure Methods in Solid State Research, by C. C. Bradley, The Accurate Characterization of the High Pressure Environment, edited by E. C. Lloyd, and a chapter in Volume 11 of Solid State Physics are devoted entirely to this facet of high pressure research. It is not our plan either to supersede or extend these approaches. It is our purpose here to discuss the effect of high pressure on the electronic properties of solids.
The application of high pressures to serve scientific ends is an ever-growing area of research. With sections on chemistry, food science, biochemistry and physics, this book contains a variety of original work.
An Introduction to High-Pressure Science and Technology provides you with an understanding of the connections between the different areas involved in the multidisciplinary science of high pressure. The book reflects the deep interdisciplinary nature of the field and its close relationship with industrial applications.Thirty-nine specialists in high
Exploring the range and utility of high-pressure solvent systems across a variety of different chemical applications, this book brings together recent advances in supercritical technology and other pressurised-solvent systems. It provides an in-depth overview of the latest advances and developments and discusses the limitations and drawbacks that need to be addressed. Wherever possible, the greenness and economic viability of the different solvent systems is highlighted. This book is ideal for researchers and industrialists working in environmental science, green chemistry and biorefineries.
High-Pressure Chemistry and Physics of Polymers is devoted to covering all areas of high-pressure polymer materials science. Topics addressed include the synthesis of polymers, changes in reactivity, structural transformations, molecular dynamics, relaxation processes, deformational properties, chemical modification, and the effect of shock waves and shear stresses. The authors' contributions reflect over 60 years of Soviet study in the field of physico-chemistry conducted at the major former Soviet Institutes of Chemical Physics, Organic Chemistry, Polymer Chemistry, and Physical Chemistry. Fundamental topics such as compressibility of polymers, polymerization under pressure, viscoelastic/deformational properties, and polymer modification are discussed with an eye toward materials development for improving physical models and methods of calculating the changing parameters of materials under pressure. The book is a valuable reference to data on mechanisms of physical and chemical processes, in addition to new experimental data for improving physical models and methods of calculating changes in material characteristics under compression loads. High-Pressure Chemistry and Physics of Polymers will be an important reference for graduate students and practicing professionals in polymer chemistry and polymeric materials.
Since the 1950s shock compression research contributed greatly to scientific knowledge and industrial technology. As a result, for example, our understanding of meteorite impacts has substantially improved, and shock processes have become standard industrial methods in materials synthesis and processing. Investigations of shock-compressed matter involve physics,electrical engineering, solid mechanics, metallurgy, geophysics and materials science. The description of shock-compressed matter presented here, which is derived from physical and chemical observations, differs significantly from the classical descriptions derived from strictly mechanical characteristics. This volume, with over 900 references, provides an introduction for scientists and engineers interested in the present state of shock compression science.
The International Association for the Properties of Water and Steam (IAPWS) has produced this book in order to provide an accessible, up-to-date overview of important aspects of the physical chemistry of aqueous systems at high temperatures and pressures. These systems are central to many areas of scientific study and industrial application, including electric power generation, industrial steam systems, hydrothermal processing of materials, geochemistry, and environmental applications. The authors' goal is to present the material at a level that serves both the graduate student seeking to learn the state of the art, and also the industrial engineer or chemist seeking to develop additional expertise or to find the data needed to solve a specific problem. The wide range of people for whom this topic is important provides a challenge. Advanced work in this area is distributed among physical chemists, chemical engineers, geochemists, and other specialists, who may not be aware of parallel work by those outside their own specialty. The particular aspects of high-temperature aqueous physical chemistry of interest to one industry may be irrelevant to another; yet another industry might need the same basic information but in a very different form. To serve all these constituencies, the book includes several chapters that cover the foundational thermophysical properties (such as gas solubility, phase behavior, thermodynamic properties of solutes, and transport properties) that are of interest across numerous applications. The presentation of these topics is intended to be accessible to readers from a variety of backgrounds. Other chapters address fundamental areas of more specialized interest, such as critical phenomena and molecular-level solution structure. Several chapters are more application-oriented, addressing areas such as power-cycle chemistry and hydrothermal synthesis. As befits the variety of interests addressed, some chapters provide more theoretical guidance while others, such as those on acid/base equilibria and the solubilities of metal oxides and hydroxides, emphasize experimental techniques and data analysis.- Covers both the theory and applications of all Hydrothermal solutions - Provides an accessible, up-to-date overview of important aspects of the physical chemistry of aqueous systems at high temperatures and pressures- The presentation of the book is understandable to readers from a variety of backgrounds