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Combining the two topics for the first time, this book begins with an introduction to the recent challenges in energy conversion devices from a materials preparation perspective and how they can be overcome by using atomic layer deposition (ALD). By bridging these subjects it helps ALD specialists to understand the requirements within the energy conversion field, and researchers in energy conversion to become acquainted with the opportunities offered by ALD. With its main focus on applications of ALD for photovoltaics, electrochemical energy storage, and photo- and electrochemical devices, this is important reading for materials scientists, surface chemists, electrochemists, electrotechnicians, physicists, and those working in the semiconductor industry.
The world of today must face up to two contradictory energy problems: on the one hand, there is the sharply growing consumer demand in countries such as China and India. On the other hand, natural resources are dwindling. Moreover, many of those countries which still possess substantial gas and oil supplies are politically unstable. As a result, renewable natural energy sources have received great attention. Among these, solar-cell technology is one of the most promising candidates. However, there still remains the problem of the manufacturing costs of such cells. Many attempts have been made to reduce the production costs of “conventional” solar cells (manufactured from monocrystalline silicon using diffusion methods) by instead using cheaper grades of silicon, and simpler pn-junction fabrication. That is the ‘hero’ of this book; the heterojunction solar cell.
The early chapters comprehensively review the optical and transport properties of silicon. Light trapping is described in detail. Limits on the efficiency of silicon cells are discussed as well as material requirements necessary to approach these limits. The status of current approaches to passifying surfaces, contacts and bulk regions is reviewed. The final section of the book describes the most practical approaches to the fabrication of high-efficiency cells capable of meeting the efficiency targets for both concentrated and non-concentrated sunlight, including a discussion of design and processing approaches for non-crystalline silicon.
Today’s solar cell multi-GW market is dominated by crystalline silicon (c-Si) wafer technology, however new cell concepts are entering the market. One very promising solar cell design to answer these needs is the silicon hetero-junction solar cell, of which the emitter and back surface field are basically produced by a low temperature growth of ultra-thin layers of amorphous silicon. In this design, amorphous silicon (a-Si:H) constitutes both „emitter“ and „base-contact/back surface field“ on both sides of a thin crystalline silicon wafer-base (c-Si) where the electrons and holes are photogenerated; at the same time, a-Si:H passivates the c-Si surface. Recently, cell efficiencies above 23% have been demonstrated for such solar cells. In this book, the editors present an overview of the state-of-the-art in physics and technology of amorphous-crystalline heterostructure silicon solar cells. The heterojunction concept is introduced, processes and resulting properties of the materials used in the cell and their heterointerfaces are discussed and characterization techniques and simulation tools are presented.
Amorphous Silicon/Crystalline Silicon Solar Cells deals with some typical properties of heterojunction solar cells, such as their history, the properties and the challenges of the cells, some important measurement tools, some simulation programs and a brief survey of the state of the art, aiming to provide an initial framework in this field and serve as a ready reference for all those interested in the subject. This book helps to “fill in the blanks” on heterojunction solar cells. Readers will receive a comprehensive overview of the principles, structures, processing techniques and the current developmental states of the devices. Prof. Dr. Wolfgang R. Fahrner is a professor at the University of Hagen, Germany and Nanchang University, China.
Nanostructured solar cells are very important in renewable energy sector as well as in environmental aspects, because it is environment friendly. The nano-grating structures (such as triangular or conical shaped) have a gradual change in refractive index which acts as a multilayer antireflective coating that is leading to reduced light reflection losses over broadband ranges of wavelength and angle of incidence. There are different types of losses in solar cells that always reduce the conversion efficiency, but the light reflection loss is the most important factor that decreases the conversion efficiency of solar cells significantly. The antireflective coating is an optical coating which is applied to the surface of lenses or any optical devices to reduce the light reflection losses. This coating assists for the light trapping capturing capacity or improves the efficiency of optical devices, such as lenses or solar cells. Hence, the multilayer antireflective coatings can reduce the light reflection losses and increases the conversion efficiency of nanostructured solar cells.
Solar cells are semiconductor devices that convert light photons into electricity in photovoltaic energy conversion and can help to overcome the global energy crisis. Solar cells have many applications including remote area power systems, earth-orbiting satellites, wristwatches, water pumping, photodetectors and remote radiotelephones. Solar cell technology is economically feasible for commercial-scale power generation. While commercial solar cells exhibit good performance and stability, still researchers are looking at many ways to improve the performance and cost of solar cells via modulating the fundamental properties of semiconductors. Solar cell technology is the key to a clean energy future. Solar cells directly harvest energy from the sun’s light radiation into electricity are in an ever-growing demand for future global energy production. Solar cell-based energy harvesting has attracted worldwide attention for their notable features, such as cheap renewable technology, scalable, lightweight, flexibility, versatility, no greenhouse gas emission, environment, and economy friendly and operational costs are quite low compared to other forms of power generation. Thus, solar cell technology is at the forefront of renewable energy technologies which are used in telecommunications, power plants, small devices to satellites. Aiming at large-scale implementation can be manipulated by various types used in solar cell design and exploration of new materials towards improving performance and reducing cost. Therefore, in-depth knowledge about solar cell design is fundamental for those who wish to apply this knowledge and understanding in industries and academics. This book provides a comprehensive overview on solar cells and explores the history to evolution and present scenarios of solar cell design, classification, properties, various semiconductor materials, thin films, wafer-scale, transparent solar cells, and so on. It also includes solar cells’ characterization analytical tools, theoretical modeling, practices to enhance conversion efficiencies, applications and patents.
The most comprehensive, authoritative and widely cited reference on photovoltaic solar energy Fully revised and updated, the Handbook of Photovoltaic Science and Engineering, Second Edition incorporates the substantial technological advances and research developments in photovoltaics since its previous release. All topics relating to the photovoltaic (PV) industry are discussed with contributions by distinguished international experts in the field. Significant new coverage includes: three completely new chapters and six chapters with new authors device structures, processing, and manufacturing options for the three major thin film PV technologies high performance approaches for multijunction, concentrator, and space applications new types of organic polymer and dye-sensitized solar cells economic analysis of various policy options to stimulate PV growth including effect of public and private investment Detailed treatment covers: scientific basis of the photovoltaic effect and solar cell operation the production of solar silicon and of silicon-based solar cells and modules how choice of semiconductor materials and their production influence costs and performance making measurements on solar cells and modules and how to relate results under standardised test conditions to real outdoor performance photovoltaic system installation and operation of components such as inverters and batteries. architectural applications of building-integrated PV Each chapter is structured to be partially accessible to beginners while providing detailed information of the physics and technology for experts. Encompassing a review of past work and the fundamentals in solar electric science, this is a leading reference and invaluable resource for all practitioners, consultants, researchers and students in the PV industry.
Enormous leaps forward in the efficiency and the economy of solar cells are being made at a furious pace. New materials and manufacturing processes have opened up new realms of possibility for the application of solar cells. Crystalline silicon cells are increasingly making way for thin film cells, which are spawning experimentation with third-generation high-efficiency multijunction cells, carbon-nanotube based cells, UV light for voltage enhancement, and the use of the infrared spectrum for night-time operation, to name only a few recent advances. This thoroughly updated new edition of Markvart and Castaner's Solar Cells, extracted from their industry standard Practical Handbook of Photovoltaics, is the definitive reference covering the science and operation, materials and manufacture of solar cells. It is essential reading for engineers, installers, designers, and policy-makers who need to understand the science behind the solar cells of today, and tomorrow, in order to take solar energy to the next level. A thorough update to the definitive reference to solar cells, created by a cast of international experts from industry and academia to ensure the highest quality information from multiple perspectives Covers the whole spectrum of solar cell information, from basic scientific background, to the latest advances in materials, to manufacturing issues, to testing and calibration. Case studies, practical examples and reports on the latest advances take the new edition of this amazing resource beyond a simple amalgamation of a vast amount of knowledge, into the realm of real world applications